1. Highly heterogeneous epitaxy of flexoelectric BaTiO3-δ membrane on Ge
- Author
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Dai, Liyan, Zhao, Jinyan, Li, Jingrui, Chen, Bohan, Zhai, Shijie, Xue, Zhongying, Di, Zengfeng, Feng, Boyuan, Sun, Yanxiao, Luo, Yunyun, Ma, Ming, Zhang, Jie, Ding, Sunan, Zhao, Libo, Jiang, Zhuangde, Luo, Wenbo, Quan, Yi, Schwarzkopf, Jutta, Schroeder, Thomas, Ye, Zuo-Guang, Xie, Ya-Hong, Ren, Wei, and Niu, Gang
- Subjects
Engineering ,Materials Engineering ,Physical Sciences ,Condensed Matter Physics - Abstract
The integration of complex oxides with a wide spectrum of functionalities on Si, Ge and flexible substrates is highly demanded for functional devices in information technology. We demonstrate the remote epitaxy of BaTiO3 (BTO) on Ge using a graphene intermediate layer, which forms a prototype of highly heterogeneous epitaxial systems. The Ge surface orientation dictates the outcome of remote epitaxy. Single crystalline epitaxial BTO3-δ films were grown on graphene/Ge (011), whereas graphene/Ge (001) led to textured films. The graphene plays an important role in surface passivation. The remote epitaxial deposition of BTO3-δ follows the Volmer-Weber growth mode, with the strain being partially relaxed at the very beginning of the growth. Such BTO3-δ films can be easily exfoliated and transferred to arbitrary substrates like Si and flexible polyimide. The transferred BTO3-δ films possess enhanced flexoelectric properties with a gauge factor of as high as 1127. These results not only expand the understanding of heteroepitaxy, but also open a pathway for the applications of devices based on complex oxides.
- Published
- 2022