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1. Redox-mediated mechanisms and biological responses of copper-catalyzed reduction of the nitrite ion in vitro.

Author

Opländer, Christian, Rösner, Julian, Gombert, Alexander, Brodski, Alexander, Suvorava, Tatsiana, Grotheer, Vera, van Faassen, Ernst E., Kröncke, Klaus-Dietrich, Kojda, Georg, Windolf, Joachim, and Suschek, Christoph V.

Subjects
*COPPER catalysts, *OXIDATION-reduction reaction, *CHEMICAL reduction, *COPPER ions, *NITRITES, *NITRIC oxide
Abstract

Highlights: [•] In ischemia copper dissociates from its carrier proteins, i.e., albumin. [•] Free Cu2+ ions are reduced to Cu1+ by ascorbate, Fe2+ and/or GSH. [•] Copper-catalyzed NO formation from nitrite exerts biological activity. [•] Cu1+-catalyzed NO formation represents a new protective principle to ischemic stress. [Copyright &y& Elsevier]

Published
2013
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