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The amorphous glasses containing PbO, ZnO, MgO, and B2O3have been fabricated using the melt quenching technique. The structural properties have been analysed using the Fourier-transform infrared (FTIR) and Raman spectroscopy. Derivative of Absorption Spectra Fitting (DASF) method have been used to estimate the band gap energy from the UV–Vis absorption data which decreases from 3.02 eV to 2.66 eV with increasing the concentration of the PbO.The four glass samples 0.284 and 0.826 MeV showed unique variations in terms of gamma attenuation ability. LZMB4 glass sample proved to be the mist effective in terms of shielding of gamma radiation as it requires little distance compared to LZMB3, LZMB2 and LZMB1 to attenuate. RPE revealed a raise with increase in the thickness of the material and reduces as the energy raises. TF is superior in LZMB1 compared to LZMB2, LZMB3 and LZMB4, confirming that, LZMB4 will attenuate better. The ZEffof the materials was seen falling as the energy increases, confirming that the linear attenuation coefficient of the glass materials decreases when the energy is increased. The results confirmed that, glass material LZMB4 is the best option especially for gamma radiation shielding applications compared to LZMB3, followed by LZMB2, then LZMB1.

This research focuses on the preparation of a new glass system designed specifically for applications in radiation shielding materials. These glasses are based on the general formula (56-x)B2O3-10TiO2-8BaO-27ZnO-(x-1)Nd2O3, where x takes the values of 2, 4, 6 and 8 mol%. For the examination of the designed glasses' radiation attenuation performance, Phy-X software was used, which is a useful approach for predicting the linear attenuation coefficient (LAC), the half value layer (HVL), and effective atomic number. The LAC decreases from 1.489 cm-1to 0.551 cm-1for the glass with x=1 mol%, while the glass with 7 mol% Nd2O3saw a decrease in the LAC from 2.483 cm-1to 0.718 cm-1. Introducing Nd2O3increases the glasses' LAC, suggesting enhanced radiation shielding performance. Also, Nd2O3addition influences the HVL within the glasses, with higher content reducing the HVL. At 0.122 MeV, the HVL and tenth value layer (TVL) are 0.456 and 1.546 cm, respectively. At 0.245 MeV, the TVL is about 3.32 times higher than the HVL. The lowest mean free path (MFP) is found at 0.122 MeV, which varies between 0.672 cm for Nd1 and 0.403 cm for Nd4.