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Abstract: Yb3+-doped (Lu0.5Y0.5)3Al5O12 (Yb:LuYAG) single crystal has been grown by the Czochralski method. The segregation coefficient of Yb3+ was studied by the inductively coupled plasma atomic emission spectrometry (ICP-AES) method. The crystal structure has been determined by X-ray diffraction analysis. The absorption and emission spectra and fluorescence lifetime of Yb:LuYAG crystal were measured at room temperature. The spectroscopic parameters of Yb:LuYAG crystal were compared with those of Yb:YAG and Yb:LuAG crystals with the same doping level. The results indicate that Yb:LuYAG crystals are potential candidates for high-power ultrashort pulse lasers. [ABSTRACT FROM AUTHOR]

Abstract: Yb:Y3Al5O12 (Yb:YAG) single crystals with Yb doping concentration 0.5at.%, 5at.%, 15at.%, 25at.%, 50at.%, 100at.% and Yb:YAlO3 (Yb:YAP) single crystals with Yb doping concentration 0.5at.%, 5at.%, 15at.%, 30at.% were grown by the Czochralski process. The fluorescence spectra of these crystals and the effects of self-absorption on the shape of the fluorescence spectra were studied. Through comparing the fluorescence spectra of Yb:YAG and Yb:YAP, all results indicate that the effects of self-absorption on the fluorescence spectra of Yb:YAP are remarkably stronger than that of Yb:YAG at the same Yb concentration. [Copyright &y& Elsevier]

Ho3+, Pr3+ co-doped CaGdAlO 4 (Ho,Pr:CGA) crystal fibers were successfully grown by the micro-pulling-down (μ -PD) technique for the first time. Detailed investigations were conducted on the polarized absorption spectra, fluorescence spectra, and lifetime decay curves. The 2 at.% Ho, 0.4 at.% Pr:CGA crystal fiber exhibits a broad absorption band at 1147 nm with full width at half maximum (FWHM) of 25.5 nm and 64.5 nm for σ and π polarization, respectively. Increasing the concentration of Pr3+ led to a decrease in emission intensity at 2001 nm and an increase in emission intensity at 2861 nm. The FWHMs of the crystal fiber containing 2 at.% Ho and 0.4 at.% Pr:CGA at 2861 nm were 44.5 nm for σ polarization and 24.3 nm for π polarization. Additionally, the lifetime ratio (5I 7 /5I 6) decreases from 25.18 to 2.85 in the crystal fibers containing 2 at.% Ho:CGA and 2 at.% Ho, 0.4 at.% Pr:CGA, respectively. These findings suggest that the presence of deactivated Pr3+ ions can significantly reduce the lifetime gap between the 5I 6 and 5I 7 energy levels, potentially mitigating the self-termination phenomenon on the ∼3 μm emission. • Ho3+, Pr3+ co-doped CaGdAlO 4 single crystal fiber were grown by the micro-pulling-down (μ -PD) technique. • The crystal structure, polarized absorption and emission spectra were investigated. • The deactivating effect of different concentration of Pr3+ were analyzed. [ABSTRACT FROM AUTHOR]

Ho,Pr:CaYAlO 4 (Ho,Pr:CYA) crystal doped with 1 at.% Ho3+ and 0.1 at.% Pr3+ was successfully grown using the Czochralski method. Polarized absorption spectra, emission spectra, and fluorescence lifetime measurements were performed. The impact of Pr3+ co-doping on the ∼3 μm emission of Ho3+ ions was analyzed. The energy transfer efficiency from Ho3+:5I 7 to Pr3+:3F 2 energy level was calculated to be 60.66 %, indicating that Pr3+ effectively mitigated the self-termination effect in Ho,Pr:CYA crystals. The absorption cross-section at 645 nm was found to be 1.53 × 10−20 cm2 for σ polarization and 2.62 × 10−20 cm2 for π polarization. The emission cross-section at 2842 nm was calculated to be 0.86 × 10−20 cm2 for σ polarization and 1.33 × 10−20 cm2 for π polarization at 2908 nm, with a full width at half maximum (FWHM) of 139 nm and 88 nm, respectively. The fluorescence lifetimes of the 5I 6 and 5I 7 levels were measured to be 0.17 ms and 2.01 ms, respectively. These results collectively suggest that Ho,Pr:CYA crystals hold great potential as a candidate for 2.8 μm laser applications. • Ho3+,Pr3+ co-doped CaYAlO 4 crystal was grown by the Czochralski method. • The crystal structure, polarized absorption and emission spectra were investigated. • The intensity parameters were obtained using J-O theory. [ABSTRACT FROM AUTHOR]

Abstract We report on the growth, spectroscopic properties and visible laser operation of Pr3+-doped LaMgAl 11 O 19 (LMA) crystal. The absorption and emission spectra were recorded in visible wavelength range and the decay time of 3P 0 manifold was measured to be about 34.5 μs at room temperature. Using an InGaN laser diode as pump source, continuous-wave laser operation of Pr:LMA crystal have also been demonstrated in red at about 645 nm and deep red at about 725 nm, which provide new linearly polarized sources for various potential applications. Highlights • A Pr:LMA crystal was successfully gown by using the Czochralski method. • Spectral parameters of Pr:LMA crystal were obtained. • Using a blue laser diode as pump source, red and deep red laser were demonstrated from Pr:LMA crystal. [ABSTRACT FROM AUTHOR]

Abstract We report on diode-pumped continuous-wave and passively Q-switched c-cut Nd:LMA lasers. For continuous-wave operation, the maximum output power reaches 3.10 W with slope efficiency of about 48.9% at 1055 nm and 2.63 W with slope efficiency of 43.1% at 1082 nm. For passively Q switched operation, using a Cr:YAG as saturable absorber, the achieved maximum average output power is 1.49 W at 1055 nm with pulse width of 18.4 ns. Moreover, we have also realized simultaneous dual-wavelength laser operation at 1055 and 1082 nm with a maximum average output power of 1.22 W and a pulse width of 19.4 ns. Furthermore, inserting an etalon for suppressing the 1055 nm line, we have operated single wavelength laser at 1082 nm with output power of 0.31 W and pulse width of 20.8 ns. This work has verified the potential of Nd:LMA crystal as a laser gain medium. Highlights • Absorption and emission spectra of a c -cut Nd: LaMgAl 11 O 19 crystal are reported. • Efficiently continuous-wave operation at 1055 and 1082 nm have been realized for the first time to our knowledge. • Efficiently passively Q-switched operation at 1055 and 1082 nm have also been realized. [ABSTRACT FROM AUTHOR]

Tm3+ doped and Tm3+, Pr3+ co-doped Lu 3 Al 5 O 12 (LuAG) garnet single crystals have been successfully grown by the micro-pulling-down (μ-PD) method. The absorption spectra, fluorescence spectra and lifetimes were investigated at room temperature. In the absorption spectra, the transition centered at 782 nm matches well with the GaAlAs LDs laser pumping. The incorporation of Pr3+ into Tm3+-doped LuAG crystals enhanced the intensity of 1.5 μm emission and decreased the fluorescence lifetime of the lower energy level for 1.5 μm emission from 10.427 ms to 2.603 ms. The results indicate that Tm,Pr:LuAG crystal can be promising candidate for near infrared 1.5 μm laser materials. • Tm:LuAG and Tm,Pr:LuAG crystals have been successfully grown by the micro-pulling-down (μ-PD) method. • Spectral parameters of Tm:LuAG and Tm,Pr:LuAG crystals were obtained and compared. • The fluorescence mechanism of Tm,Pr:LuAG crystal has been studied for the first time. [ABSTRACT FROM AUTHOR]

Yb,Ho:Y 2 O 3 ceramics have been fabricated by Spark Plasma Sintering method (SPS). The microstructure and transmittance of the ceramics sintered from 1623 K to 1673 K were analyzed. The highest in-line transmittance of Yb,Ho:Y 2 O 3 ceramic sintered at 1673 K reached almost 83% at 750 nm with the thickness of 1 mm. The absorption spectra, fluorescence spectra and fluorescence decay curve were recorded at room temperature. The Judd-Ofelt parameters Ω 2 , Ω 4 and Ω 6 were calculated to be 8.33 × 10−20 cm2, 1.81 × 10−20 cm2, and 0.82 × 10−20 cm2, respectively. The intense emission cross section of Yb,Ho:Y 2 O 3 ceramic was 3.43 × 10−20 cm2 at 2057 nm with full width at half maximum (FWHM) of 208 nm. The results indicate that Yb,Ho:Y 2 O 3 transparent ceramic can be a promising laser gain medium for laser operation around 2 μm. Image 1 • The highest in-line transmittance of Yb,Ho:Y 2 O 3 ceramic sintered at 1673 K reached almost 83% at 750 nm with the thickness of 1 mm. • The spectral characteristics were intensively investigated through Judd-Ofelt theory. [ABSTRACT FROM AUTHOR]

We report on the comparative growth and spectroscopy of Eu3+-doped Y 3 Al 5 O 12 (YAG) and Y 3 ScAl 4 O 12 crystals grown by the micro-pulling-down (μ-PD) method. The structure of the as-grown crystals was determined by X-ray diffraction (XRD) and Raman spectroscopy. The absorption spectra of the crystals are dominated by a strong line centered at 395 nm, matching well with the emission of commercial ultraviolet laser diodes. The Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals exhibit strongest red emission centered at 710 nm and the full width at half maximum (FWHM) was calculated to be 2.03 and 3.19 nm, respectively. The fluorescence decay curves of 5D 0 levels were measured and discussed. All the results indicate that the Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals are promising candidates for red luminescent/laser materials. • Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals were successfully grown by the micro-pulling-down technique for the first time. • The structure parameters of Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals were investigated by XRD. • Spectral parameters of Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals were obtained and compared. [ABSTRACT FROM AUTHOR]

High quality of Tb3+-single doped and Tb3+/Pr3+ co-doped CaF 2 crystals were grown by the temperature gradient technique (TGT). Pr3+ ions were used as sensitizing ions of Tb3+. Optical properties including absorption spectrum, emission spectrum, and fluorescence decay curve were recorded. Through co-doping sensitizing ions of Pr3+, the absorption cross section around 480 nm increased from 0.007 × 10−20 cm2 to 0.3 × 10−20 cm2, the large value is beneficial for the absorption of LD pump source. Judd-Ofelt theory was used to analyze the spectroscopic parameters. Fluorescence branch ratio, transition probability, radiative and fluorescence lifetimes, and quantum efficiency were determined as well. The emission cross section of Tb,Pr:CaF 2 for the green emission at 544 nm and yellow emission at 587 nm corresponding to the transition of 5D 4 →7F 5 and 5D 4 →7F 4 were calculated to be 5.56 × 10−22 cm2 and 8.78 × 10−23 cm2, respectively, which is comparable to the Tb3+ doped CaF 2 crystal. • Tb:CaF 2 crystal and Tb/Pr co-doped CaF 2 crystal were grown by TGT method. • Pr3+ ions were used to improve the absorption cross section of Tb3+ ions. • Judd-Ofelt theory was used to analyze the spectroscopic parameters. • Tb,Pr:CaF 2 crystal is a potential laser material for green and yellow oscillation. [ABSTRACT FROM AUTHOR]