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Abstract: An X-cut and a Z-cut Li-deficient, non-congruent LiNbO3 crystal were prepared by carrying out Li-poor vapor transport equilibration (VTE) treatment on one mm thick congruent plates at 1100°C for 170h. From the measured optical absorption edges (OAE), the Li2O content is evaluated to be 47.74±0.13mol% in the X-cut plate and 47.61±0.13mol% in the Z-cut VTE crystal. The composition homogeneity is verified by measuring the OAE as a function of the crystal thickness. The visible optical absorption and powder X-ray diffraction studies allow to conclude that both VTE crystals retain still the LiNbO3 phase. OH− absorption characteristics of the two VTE crystals were investigated in comparison with those of the as-grown crystals. The results show that the Li-poor VTE treatment only slightly modifies the area, spectral width, spectral shape and background absorption of the OH− band. Comparison shows that the Li-poor VTE effects on the OH− absorption have large differences from the Li-rich VTE effects in bandwidth and areas of three component peaks at 3466, 3481 and 3488cm−1. These spectral differences are explained on the basis of the H+ site occupation and crystal defect models taking into account the VTE effect on crystal defect concentration. The Li-poor VTE effects are attributed to the VTE inducing the redistribution of OH− ions in different sites. [Copyright &y& Elsevier]

Abstract: Influence of thermal reduction on intrinsic (bipolarons), extrinsic (Er3+) defects and OH− groups in Er:LiNbO3 crystals, which were as-grown and VTE-treated (VTE: vapor transport equilibration) before being reduced, was studied by measuring the polarised or unpolarised optical absorption in visible and near infrared regions. A wide and strong band extending from the optical absorption edge up to the infrared region and peaking around 500nm (∼2.5eV), resulting from the absorption of reduction-induced bipolarons, is observed. Meanwhile, the thermal reduction also induces an additional, relatively much narrow absorption band around 370nm in a crystal whether it is Er-doped or undoped and whether it is congruent or originally VTE-treated. Both the 500nm and the 370nm bands show similar polarisation dependence. The thermal reduction treatment hardly influences Er3+ spectroscopic properties such as absorption amplitude, linewidth, peaking position and polarisation dependence. The original VTE effects on the spectroscopic properties of Er:LiNbO3 crystal are essentially retained still. The thermal reduction has a similar effect on the OH− absorption to a strong VTE treatment: the removal of the OH− groups contained in the crystal. [Copyright &y& Elsevier]