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We report broadband supercontinuum (SC) spectra generated from low-loss single-mode fibers (SMF) based on novel Ge–As–S–Se (GASS) chalcogenide (ChGs) glasses. The step-index fibers (SIF) possess an ultra-low background loss of 0.27 dB/m at wavelength of 2.5 ∼ 7. 5 μ m were fabricated by an optimized peeled-off extrusion method. SC generation was studied by pumping the fiber with 15 cm and 100 cm at same condition (5 μ m, ∼ 150 fs, 1 kHz, 25 mW), respectively. Output SC covering 1.46 ∼ 9. 32 μ m was obtained in this 15-cm fiber, while a relatively wide output SC spanning from 1.68 to 8. 28 μ m was observed in 100-cm fiber. Due to simulated numerical model does not account for higher-order modes at shorter wavelengths, cladding modes, polarization effects etc. Experimental SC spectral profile in the short and long S/Se fibers is slightly different with the simulation analysis. To the best of our knowledge, this is the first report on the performance of GASS fiber. • The fiber with an ultra-low background loss of 0.27 dB/m in 2.5 ∼ 7. 5 μ m. • SC spectrum covering 1.46–9.32 μ m was obtained in a 15 cm fiber, 1.68–8.28 μ m for 100 cm. • This fiber was better than As 2 S 3 fiber in operating window and higher damage than As 2 Se 3. [ABSTRACT FROM AUTHOR]

The influence of extrusion on the properties of chalcogenide glasses and fibers was investigated systematically via measuring and analyzing their structural and physical properties of Ge 10 As 22 Se 68 and As 2 S 3. The experimental results showed that the extrusion processing has an insignificant effect on the glass network, crystallization, and compositions, but does have an influence on the glass transmission rate, refractive index and density. Meanwhile, the fiber loss after extrusion processing was greatly improved with 57.65% or 71.43%, corresponding to Ge 10 As 22 Se 68 or As 2 S 3 fiber, respectively. [ABSTRACT FROM AUTHOR]