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Imaging of the phase output of a lock-in amplifier in mid-infrared photothermal vibrational microscopy is demonstrated for the first time in combination with nonlinear demodulation. In general, thermal blurring and heat transport phenomena contribute to the resolution and sensitivity of mid-infrared photothermal imaging. For heterogeneous samples with multiple absorbing features, if imaged in a spectral regime of comparable absorption with their embedding medium, it is demonstrated that differentiation with high contrast is achieved in complementary imaging of the phase signal obtained from a lock-in amplifier compared to standard imaging of the photothermal amplitude signal. Specifically, by investigating the relative contribution of the out-of-phase lock-in signal, information based on changes in the rate of heat transport can be extracted, and inhomogeneities in the thermal diffusion properties across the sample plane can be mapped with high sensitivity and sub-diffraction limited resolution. Under these imaging conditions, wavenumber regimes can be identified in which the thermal diffusion contributions are minimized and an enhancement of the spatial resolution beyond the diffraction limited spot size of the probe beam in the corresponding phase images is achieved. By combining relative diffusive phase imaging with nonlinear demodulation at the second harmonic, it is demonstrated that 1-μm-size melamine beads embedded in a thin layer of 4-octyl-4'-cyanobiphenyl (8CB) liquid crystal can be detected with a 1.3-μm spatial full-width at half-maximum (FWHM) resolution. Thus, imaging with a resolving power that exceeds the probe diffraction limited spot size by a factor of 2.5 is presented, which paves the route towards super-resolution, label-free imaging in the mid-infrared.