Search

Your search keyword '"Wen, Wen"' showing total 1 results
1 results on '"Wen, Wen"'

1. Enantioselective Synthesis of gem-Diaryl Benzofuran-3(2H)-ones via One-Pot Asymmetric Rhodium/Palladium Relay Catalysis.

Author

Zong-Feng Zhang, Dong-Xing Zhu, Wen-Wen Chen, Bin Xu, and Ming-Hua Xu

Subjects
*ENANTIOSELECTIVE catalysis, *PALLADIUM catalysts, *BENZOFURAN, *RHODIUM catalysts, *SULFUR, *ALKENES
Abstract

An asymmetric dual-metal relay catalysis strategy that combines Rh/chiral sulfur-olefin-catalyzed enantioselective 1,2-addition with a Pd-catalyzed intramolecular C--O coupling has been developed. The method allows rapid and efficient synthesis of quaternary carbon-containing gem-diaryl benzofuran-3(2H)-ones in good yields in a highly enantioselective manner (up to 99% ee) through a simple one-pot cascade reaction. [ABSTRACT FROM AUTHOR]

Published
2017
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results