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1. Tetra-ortho-substituted biaryls through palladium-catalyzed Suzuki-Miyaura couplings with a diaminochlorophosphine ligand

Author

Andreas Althammer, Harish K. Potukuchi, Lutz Ackermann, Peter Mayer, and Robert Born

Subjects
Steric effects, biology, Scope (project management), Stereochemistry, Ligand, Organic Chemistry, chemistry.chemical_element, biology.organism_classification, Biochemistry, Combinatorial chemistry, Catalysis, chemistry, Tetra, Physical and Theoretical Chemistry, Palladium
Abstract

A palladium complex derived from a sterically hindered diaminochlorophosphine allowed for Suzuki-Miyaura cross-couplings of chloroarenes with ample scope and provided access to tetra-ortho-substituted bi(hetero)aryls.

Published
2010

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