Search

Your search keyword '"Matthew D. Whealon"' showing total 2 results
Start Over Author "Matthew D. Whealon" Journal organic process research & development
2 results on '"Matthew D. Whealon"'

1. Continuous Organic Synthesis in a Spinning Tube-in-Tube Reactor: TEMPO-Catalyzed Oxidation of Alcohols by Hypochlorite

Author

Rick Boydson, Lisa M. Roberts, Philip D. Hampton, Andrew A. Yaeger, and Matthew D. Whealon

Subjects
chemistry.chemical_compound, Aqueous solution, chemistry, Bleach, Reagent, Sodium hypochlorite, Alcohol oxidation, Organic Chemistry, Inorganic chemistry, Hypochlorite, Physical and Theoretical Chemistry, Primary alcohol, Toluene
Abstract

Continuous production of aldehydes in high yields (≥90%) can be accomplished by feeding aqueous (sodium hypochlorite/sodium bicarbonate, pH 8.5) and organic (TEMPO/tetrabutylammonium bromide/primary alcohol/toluene or CH2Cl2) solutions through the inlets of a spinning tube-in-tube reactor (STT reactor manufactured by Kreido Biofuels [STT is a registered trademark of Kreido Biofuels]) at rotor speeds of 4000−6000 RPM with residence times as short as 1−2 min. This approach eliminates the need for slow addition of the bleach reagent to control this exothermic reaction.

Published
2008
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results