98 results on '"Akita, Munetaka"'
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2. Preparation and photochemical behavior of organoruthenium derivatives of photochromic dithienylethene (DTE): DTE-(RRuLm)(n) (RRuLm = (eta(6)-C6H5)Ru(eta(5)-C5Me5), (eta(6)-C6H5)RuCl2(PPh3), (eta(5)-C5Me4)Ru(CO)(2); n = 1, 2)
3. Synthesis of a Library of Ir-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(m-BL)M'L']BF4, 2. Preparation, Basic Coordination Properties and Reactivity of the Carbonyl Complexes
4. Synthesis of a Library of Ir-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(m-BL)M'L']BF4, 1. Specific Synthesis of Isomeric Heterodinuclear Complexes with Switched Metal Arrangements
5. Synthesis of a Series of Diiron Complexes Based on Tetraethynylethene Skeleton and Related C6-Endiyne Spacers, (dppe)Cp*Fe-C∫C-C(R)=C(R)-C∫C-FeCp*(dppe): Tunable Molecular Wires
6. Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand: Dynamic and Diverse M--M Interactions in [(m-X)Rh2(PNNP)(CO)2]n+ and [(m4-X)Rh4(PNNP)2(CO)4]n+ [X= H, O, CｺC-R, R-CｺC-R, CｺC, CH=CH2, SMe2; n= 0, 1: PNNP= 3,5-bis(diphenylphosphinomethyl)pyrazolato]
7. Polynuclear rhodium complexes with dinucleating PNNP ligand: Dynamic and diverse M center dot center dot center dot M interactions in [(mu-X)Rh-2(PNNP)(CO)(2)](n+) and [(mu(4)-X)Rh-4(PNNP)(2)(CO)(4)](n+) [X = H, O, C C-R, R-C C-R, C C, CH=CH2, SMe2; n=0, 1 : PNNP=3,5-bis(diphenylphosphinomethyl)pyrazolato]
8. Synthesis and Characterization of Coordinatively Unsaturated Alkynyl- and Aryl-cobalt Complexes with 15 Valence Electrons, Tp^iPr2^Co-R, Bearing Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (Tp^iPr2^)
9. Synthesis and characterization of coordinatively unsaturated alkynyl- and aryl-cobalt complexes with 15 valence electrons, Tp(iPr2)Co-R, bearing the hydrotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(iPr2))
10. N/O- and C-bound (enolato)palladium complexes with hydrotris(pyrazolyl)borato ligands (Tp(R): R = iPr(2), Me-2) obtained via dehydrative condensation between the hydroxo complexes Tp(R)Pd(Py)OH and active methylene compounds: Factors determining the isomer distribution and dimerization of cyano compounds
11. Synthesis and characterisation of Fe,Co-mixed metal polynuclear complexes with C4H and C-4 ligands derived from butadiynyl (X = H) and butadiynediyl iron complexes (X = Fp*), Fp*-C C-C C-X [Fp* = (eta(5)-C5Me5)Fe(CO)(2)]: Transformation of the C-4(H) cluster frameworks via valence isomerization and 1,2-H shift of the carbon linkages
12. Synthesis of a series of rhodium complexes, Tp(iPr)Rh(I)L(2) and Tp(iPr)Rh(III)(X)(Y)(MeCN), with the hydridotris(3,5-diisopropylpyrazolyl)borato ligand (Tp(iPr)) from a versatile precursor, (kappa(3)-Tp(iPr))Rh(coe)(MeCN), and dependence of kappa(2)-kappa(3) interconversion rate of the Tp(iPr) ligand on the chelate ring size
13. Synthesis and structure determination of the linear conjugated polyynyl and polyynediyl iron complexes Fp*-(C C)(n)-X (X = H) (n = 1, 2); X = Fp* (n = 1, 2, 4); Fp* = (eta(5)-C5Me5)Fe(CO)(2))
14. Synthesis and structure determination of Rh-diene complexes with the hydridotris(3,5-diisopropylpyrazolyl)borate ligand, Tp(iPr)Rh(diene) (diene = cod, nbd): Dependence of the nu(B-H) values on the hapticity of the Tp(iPr) ligand (kappa(2) vs kappa(3))(1)
15. Synthesis and reactivity of labile MeCN adducts of diruthenium bis(mu-methylene) species, Cp2Ru2(mu-CH2)(2)(CO)(n)(MeCN)(2-n) (n = 1, 2): Reaction with H sources, H-X (X = SiR3, SnR3, H), and C-C coupling with alkynes and diazoalkanes
16. Synthesis of diiron bridging allenylidene complexes Cp*Fe-2(2)(mu-C=C=CR1R2)(mu-CO)(CO)(2) (Cp*=eta(5)-C5Me5) via nucleophilic addition to the diiron ethynediyl complex (mu-C C)[FeCp*(CO)(2)](2) and their conversion to cationic mu-vinylcarbyne and mu-vinylidene complexes
17. Conversion of a diruthenium mu-methylene complex, Cp(2)Ru(2)(mu-CH2)(mu-CO)(CO)(2), into methane through reduction with hydrosilane: Reactivity of silyl-mu-methylene intermediates Cp(2)Ru(2)(mu-CH2)(SiR(3))(X)(CO)(2) (X=H, SiR(3)) relevant to catalytic CO hydrogenation and activation of Si-H, C-H, and C-Si bonds
18. Tetranuclear complexes based on a dvnamic metal-metal linkage, [(mu 4-X)Rh-4(CO)(4)(PNNP)(2)](n+) (X/n = RC equivalent to C/1 (acetylide), C-2/0 (dicarbide))
19. REACTION OF THE METAL-SUBSTITUTED VINYLIDENE COMPLEX CP'(CO)2MN =C=(H)-FP-ASTERISK WITH EXCESS BULI, GIVING ACYLATED DINUCLEAR BRIDGING ALKENYL COMPLEXES, CP'MNCP-ASTERISK-FE MU-CH=C(E)-C(=O)-BU (MU-CO)(CO)2 (E=H, ME) - CONFIRMATION OF THE INTRAMOLECULAR 1,2-H SHIFT MECHANISM PROPOSED FOR THE FLUXIONAL PROCESS OF THE CATIONIC DIIRON MU-ETHYNYL COMPLEXES ((ETA(5)-C5R5)FE(CO)2)2(MU-C-EQUIVALENT-TO-C-H) BF4
20. TRANSFORMATION OF THE C2H LIGAND IN FP-ASTERISK-C-EQUIVALENT-TO-CH (FP-ASTERISK=(ETA-5-C5ME5)FE(CO)2) INTO VARIOUS C-2 FUNCTIONAL-GROUPS VIA AN IRON-SUBSTITUTED MANGANESE VINYLIDENE COMPLEX, (ETA-5-C5H4ME)MN(CO)2 =C=C(H)FP-ASTERISK - ITS AMPHOTERIC REACTIVITIES, STRUCTURAL COMPARISONS RELEVANT TO 1-ALKYNE-TO-VINYLIDENE REARRANGEMENTS, AND ELECTRONIC INFLUENCES ON STRUCTURES OF HETEROBIMETALLIC BRIDGING ALKYNYL COMPLEXES (ETA-5-C5R5)M(CO)2 2(MU-C2R)
21. Rational Synthesis and Reversible Metal-metal Bond Scission of Heterobimetallic Xenophilic Complexes Containing an Unsupported, Polar Metal-metal Bond, Tp^iPr2^M-Co(CO)_3_L (M= Ni, Co, Fe, Mn; L= CO, PPh_3_)
22. Rational synthesis and reversible metal-metal bond scission of heterobimetallic xenophilic complexes containing an unsupported, polar metal-metal bond, Tp(iPr2)M-CO(CO)(3)L (M = Ni, Co, Fe, Mn; L = CO, PPh3)
23. C–C Bond Forming Reductive Elimination from Diarylplatinum Complexes Driven by Visible-Light-Mediated Photoredox Reactions
24. INTERACTION OF ETHYNYLIRON (FP-C-EQUIVALENT-TO-C-H AND FP-ASTERISK-C-EQUIVALENT-TO-C-H) AND ETHYNEDIYLDIIRON COMPLEXES (FP-ASTERISK-C-EQUIVALENT-TO-C-FP-ASTERISK) WITH CO2(CO)8 - FORMATION OF A CLUSTER COMPOUND WHICH IS FLUXIONAL VIA A METAL METAL BOND SCISSION AND RECOMBINATION PROCESS
25. OXYMETHYLATION OF ALKYLIRON COMPLEX CPFE(CO)2-R WITH HYDROSTANNANE AND HYDROSILANE, LEADING TO R-CH2OH DERIVATIVES - RELATED REACTIONS OF CPFE(CO)(L)-R AND CPFE(CO)(L)-C(O)R TYPE ORGANOIRON COMPLEXES AND THE MOLECULAR-STRUCTURE OF TRANS-CPFE(H)(CO)(SNPH3)2
26. PREPARATION, STRUCTURE, AND DIVERGENT FLUXIONAL BEHAVIOR OF CATIONIC DINUCLEAR IRON ACETYLIDES [FPSTAR2(C=C-H)]BF4, [FPSTAR2(C=C-PH)]BF4
27. Preparation and Photochemical Behavior of Organoruthenium Derivatives of Photochromic Dithienylethene (DTE): DTE-(RMLm)n (RMLm= (h6-C6H5)Ru(h5-C5Me5), (h6-C6H5)RuCl2(PPh3), (h5-C5Me4)Ru(CO)2; n= 1, 2)
28. C-C Coupling of Permetallated Ethene, (m4-C=C)Ru2(FeCp*)2(CO)10, with Alkynes, and Isolation of Labile MeCN Adduct, (m4-C=C)Ru2(FeCp*)2(CO)8(NCMe)2
29. Tetranuclear Complexes Based on Dynamic Metal-metal Linkage, [(μ_4_-X)Rh_4_(CO)_4_(PNNP)_2_] ^n+ ^ [X / n= R-CC / 1 (Acetylide), C_2_ / 0 (Dicarbide)]
30. Nucleophilic Addition to the η^2^-Alkyne Ligand in [CpFe(CO)_2_(η^2^-R-C≡C-R)]^+^. Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile
31. C- and N/O-bound Enolatopalladium Complexes with Hydrotrispyrazolylborato Ligands (Tp^R^: R= iPr2 and Me2) Obtained via Dehydrative Condensation Between the Hydroxo Complexes, Tp^R^Pd(py)-OH, and Active Methylene Compounds: Factors Determining the Isomer Distribution and Dimerization of Cyano Compounds
32. Higher Nuclearity Fe,Ru-Mixed Metal Dicarbide Cluster Compounds Derived from Ethynediyldiiron Complex, (η^5^-C_5_Me_5_)(CO)_2_Fe-C≡C-Fe(η^5^-C_5_Me_5_)(CO)_2_
33. Photochromic Organometallics, A Stimuli-Responsive System: An Approach to Smart Chemical Systems
34. Dirhodium Complexes Bridged by Bis(diphenylphosphino)phthalazine (PNNPPh): Central Ring Size and Charge Effects As Compared with the Pyrazolate Derivative (PNNPPy)
35. Electronic and Magnetic Couplings in Free and π-Coordinated 1,4-Diethynylnaphthalene-Bridged [Cp*(dppe)Fe]n+ (n = 0, 1) Units
36. Chemical Stimuli Induced Phosphorescence Modulation of Secondary Thioamide-Based Pincer Platinum Complexes
37. Preparation and Photochemical Behavior of Organoruthenium Derivatives of Photochromic Dithienylethene (DTE): DTE−(RRuLm)n(RRuLm= (η6-C6H5)Ru(η5-C5Me5), (η6-C6H5)RuCl2(PPh3), (η5-C5Me4)Ru(CO)2;n= 1, 2)
38. C−C Coupling of a Permetalated Ethene, (μ4-CC)Ru2(FeCp*)2(CO)10, with Alkynes, and Isolation of a Labile MeCN Adduct, (μ4-CC)Ru2(FeCp*)2(CO)8(NCMe)2
39. Synthesis of a Series of Diiron Complexes Based on a Tetraethynylethene Skeleton and Related C6-Enediyne Spacers, (dppe)Cp*Fe−C⋮CC(R)C(R)C⋮C−FeCp*(dppe): Tunable Molecular Wires
40. Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M‘L‘]BF4. 2. Preparation, Basic Coordination Properties, and Reactivity of the Carbonyl Complexes
41. Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M‘L‘]BF4. 1. Specific Synthesis of Isomeric Heterodinuclear Complexes with Switched Metal Arrangements
42. Photochromic Behavior and Diastereomeric Isomerism in [(η6-spirobenzopyran)RuCp*]PF6
43. Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand: Dynamic and Diverse M···M Interactions in [(μ-X)Rh2(PNNP)(CO)2]n+ and [(μ4-X)Rh4(PNNP)2(CO)4]n+ [X = H, O, C⋮C−R, R−C⋮C−R, C⋮C, CHCH2, SMe2; n = 0, 1: PNNP = 3,5-bis(diphenylphosphinomethyl)pyrazolato]
44. Tetranuclear Complexes Based on a Dynamic Metal−Metal Linkage, [(μ4-X)Rh4(CO)4(PNNP)2]n+(X/n= RC⋮C/1 (Acetylide), C2/0 (Dicarbide))
45. Formal Hydrogenation of a Permetalated Ethene, (μ4-CC)Fe2Ru2(η5-C5Me5)2(CO)8(dppm), via Successive Protonation−Hydride Reduction Leading to C2Hn Cluster Compounds
46. Synthesis and Characterization of Coordinatively Unsaturated Alkynyl- and Aryl-Cobalt Complexes with 15 Valence Electrons, TpiPr2Co−R, Bearing the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (TpiPr2)
47. Rational Synthesis and Reversible Metal−Metal Bond Scission of Heterobimetallic Xenophilic Complexes Containing an Unsupported, Polar Metal−Metal Bond, TpiPr2M−Co(CO)3L (M = Ni, Co, Fe, Mn; L = CO, PPh3)
48. N/O- and C-Bound (Enolato)palladium Complexes with Hydrotris(pyrazolyl)borato Ligands (TpR: R = iPr2, Me2) Obtained via Dehydrative Condensation between the Hydroxo Complexes TpRPd(Py)OH and Active Methylene Compounds: Factors Determining the Isomer Distribution and Dimerization of Cyano Compounds
49. Tetrahedral, Highly Coordinatively Unsaturated 14e (Fe) and 15e (Co) Hydrocarbyl Complexes Bearing Hydrotris(pyrazolyl)borato Ligands (TpR‘), TpR‘M−R (M = Fe, Co, Ni)
50. Nucleophilic Addition to the η2-Alkyne Ligand in [CpFe(CO)2(η2-R−C⋮C−R)]+. Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile
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