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High-latitude permafrost peatlands are sensitive to global warming, and understanding their paleohydrological evolution is critical for assessing future hydrological and environmental changes. This paper presents a diatom record from a peat deposit covering the past 3300 years to reconstruct the moisture and acidity conditions in the Tuqiang permafrost peatland in the northern Greater Khingan Mountains of northeast China. Our findings are integrated with previously published records of plant macrofossils, palynology, and geochemistry from the same profile. From 3300 to 2800 cal yr BP, planktonic and benthic diatoms were equally abundant, indicating relatively high moisture conditions, while the low abundance of acidophilous diatoms reflects relatively high pH during this interval. Pollen data show dominance by sedges with input from the surrounding Pinus forest, while LOI data and lithology suggest that the site was a non-peat accumulating wetland. During the period 2800–1100 cal yr BP, the dominance of planktonic diatoms indicates a wetter local environment, concurrent with the dominance of peat-forming sedges (Eriophorum), indicating the development of a peatland. Between 1100 and 500 cal yr BP, a short-lived increase in acidophilous diatoms (Eunotia) marks a decrease in pH. Since 500 cal yr BP, the dominance of benthic diatoms reflects a drier environment, while a vegetation shift from an Eriophorum -dominated rich fen to a Sphagnum- and Ericaceae-dominated poor fen. An increase in Eunotia diatoms prior to the Sphagnum peak may indicate that diatoms are more sensitive to local acidified habitats than moss. Peatland development in the northern Greater Khingan Mountains was likely induced by the onset of a cooler and wetter climate starting at approximately 2800 cal yr BP, a scenario supported by regional paleoclimate records. Since 700 cal yr BP, the peatland has been affected by both anthropogenic activities and climatic changes, as a drying climate and intensified human activities around the study area reduced diatom species diversity and peat accumulation. Under the background of future global warming and enhanced human activities, the decreasing species diversity and carbon accumulation rate of peatlands in high-latitude permafrost regions need more attention. • Diatoms can indicate local moisture and acidity in permafrost peatlands. • Diatoms are likely more sensitive to microhabitats than bryophytes. • TQ peatland formed after 2800 cal yr BP caused by the cooler and wetter climate. • Rich-fen shifted to poor-fen which co-influenced by deforestation and dry climate at LIA. [ABSTRACT FROM AUTHOR]

The Ordovician-Silurian (O S) transition witnessed dramatic tectonic, climatic, marine, and biological coevolution, during which organic-rich black shale was widely deposited and is considered an important source rock. However, the potential links between the differential enrichment pattern of organic matter and climate fluctuations and paleoenvironmental evolution during this period are still unclear. In this paper, the Late Ordovician-early Silurian black shale in a JieLong (JL) section in South China was identified by graptolitic fossils, total organic carbon (TOC) content, X-ray diffraction (XRD), scanning electron microscopy (SEM) and geochemical analysis. The results show that the provenances of sedimentary rocks are all granodiorite-like. According to the variations in the TOC content and geochemical indicators, four layers are delineated. Under warm and humid climatic conditions, sea level rise and unstable seasonal upwelling led to Unit 1 organic matter enrichment controlled by high primary productivity, anoxic conditions and effective smectite production. Unit 2 organic matter burial was controlled by cold, arid and oxic environmental conditions, but primary productivity was still relatively high. After the end of the glacial period, warm and humid climatic conditions and rapid transgression were the main factors affecting the burial of organic matter in Unit 3. Under hot and humid climate conditions, higher terrigenous detrital inputs and unfavourable preservation environments, the dilution of organic matter in Unit 4 was accelerated. The corrected chemical index of alteration (CIA corr) values show that the study area experienced a climate change of alternating cold and warm conditions in response to the climate fluctuation during the glacial-interglacial period. The CIA corr value is negatively correlated with the TOC content, while the generation of available clay minerals (smectite) in warm and humid climates is usually consistent with the enhanced burial flux of organic matter, supporting the important role of climate fluctuations in the accumulation of organic matter. Finally, a comparison of the data from the present study with geochemical data from different profiles in South China reveals the role of climatic fluctuations during the O S transition in controlling paleoenvironmental evolution and organic matter enrichment, while such a heterogeneous factor is usually associated with global or regional geological events. Our study highlights this differential enrichment mechanism as a combined response of multiple factors and provides important implications for glacial-interglacial organic matter enrichment mechanisms. • Rapid changes of weathering indices imply climatic fluctuations during the Late Ordovician-Early Silurian. • Four different patterns were established for organic matter accumulation across the O/S. • Climate fluctuations and the heterogeneity nature of ocean systems explain the regional variations of OM accumulation. [ABSTRACT FROM AUTHOR]