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Shale gas is essentially non-traditional natural gas (NG). Shale gas can be considered an unusual alternative energy source. Shale gas production is a method of obtaining the NG trapped between deep underground rocks. Shale gas production is not economical, except for horizontal drilling and hydraulic fracturing methods. Advanced analysis of shale gaseous samples can be done using gas chromatography, mass spectrometry and other modern testing methods. The Orsat apparatus includes three absorption pipettes containing chemical solutions that absorb gases. Absorbents are a 33% by weight aqueous solution of potassium hydroxide (KOH) for carbon dioxide (CO2), alkali pyrogallol for oxygen (O2) and ammoniacal cuprous for carbon monoxide (CO) measurement. Oxygen is absorbed in alkaline pyrogallol or in a chromous solution. Shale gas can be analyzed best gas chromatographically. The capillary column can be separated from all the hydrocarbons and their isomers by alumina, which is used as a stationary phase...

Petroleum coke is often shortened as pet coke. Petroleum coke or pet coke is a product obtained from oil of all kinds during the oil refining process. Petroleum coke is a carbon-rich solid ...

Hydrocarbon compounds are formed by carbon and hydrogen elements. The higher heating values (HHVs) of the hydrocarbon compounds can be calculated based on the carbon (C) and hydrogen (H) contents of the chemical structures. HHVs (MJ / kg) as a function of the carbon (C) and hydrogen (H) fractions of N-saturated hydrocarbons can be calculated by the following equation: HHV = 0.303 (C)+ 1.423 (H) According to this Equation, the HHV is a function of the percentages of the carbon (C) and hydrogen (H) of pure n-saturated hydrocarbon compounds. This Equation represents the correlation obtained by means of regression analysis. It is found that the calculated values shows mean difference of 0.18%. The correlation coefficient is 0.9955. HHVs as a function of the iodine value (IV) and the saponification value (SV) of fatty acids can be calculated by the following equation: HHV(MJ/kg) = 49.43 − 0.015(IV)−0.041(SV). © 2018 Taylor & Francis Group, LLC.

Heavy oil is less expensive than light crude oil, but heavy oil is more expensive to obtain light oil products. Conventional light crude oil resources are decreasing, therefore heavy oil resources will be needed more in the future. There are huge differences from field to field for heavy oil deposits. In terms of final productive use, heavy oil is considered as an unconventional resource. Heavy oil upgrading depends on four important factors: catalyst selection, heavy oil classification, process design, and production economics. Heavy and extra-heavy oils are unconventional reservoirs of oil. Globally, 21.3% of total oil reserves are heavy oil. Heavy oil is composed of long chain organic molecules called heavy hydrocarbons. The thermal degradation of the heavy hydrocarbons in heavy oil generates liquid and gaseous products. All kinds of heavy oils contain asphaltenes, and therefore are considered to be very dense material. The most similar technologies for upgrading of heavy oils are pyrolysis and catalytic pyrolysis, thermal and catalytic cracking, and hydrocracking. The amount of liquid products obtained from pyrolysis of heavy oil was dependent on the temperature and the catalyst. Pyrolytic oil contains highly valuable light hydrocarbons as gasoline and diesel components range. The constant increase in the use of crude oils has raised prices of the most common commercial conventional products and consequently seeking for new alternative petroleum resources, like some unconventional oil resources, becomes an interesting issue. The mass contents of gasoline, diesel, and heavy oil in the crude oil are 44.6%, 38.3%, and 17.1%, respectively. The gasoline yield from the heavy oil catalytic (Na2CO3) pyrolysis is higher than the diesel efficiency for all conditions. The yield of gasoline products increases with increasing pyrolysis temperature (from 230°C to 350°C) and percentage of catalyst (from 5% to 10%). The yields of gasoline-like product are from 21.5% to 39.1% in 5% catalytic run and from 32.5% to 42.5% in 10% catalytic run. The yields of diesel-like product are from 9.3% to 29.8% in 5% catalytic run and from 15.5% to 33.7% in 10% catalytic run. © 2017 Taylor & Francis Group, LLC.

The environmental impacts of petroleum are often negative because they are toxic to almost all lifestyles, and there is a possibility of causing climate change. Oil pollution in the air and in the water can be toxic and dangerous to the human body. Preliminary researchers have thoroughly studied and discussed the methods of treatment of oily wastewater. Removing oily wastewater from the oil without damaging the environment is an important problem for the oil industry. The three-phase solid, water, and oil blends can be separated from each other when a continuous oil–water separator system is used. Oil contaminated wastewater is generally treated by gravity sedimentation, coagulation, flotation, coagulation composite flotation, demulsification, membrane separation, flocculation treatment, chemical precipitation, and biological treatment and filtration.

Crude oils are composed of hundreds of different hydrocarbon molecules, which are separated through the process of refining and small quantities of oxygen, sulfur, nitrogen, vanadium, nickel, and c...

Despite the low percentage of trace level sulfur in natural gas (NG), its use as a jet fuel for reduction from the ultra level is very important. Clean and efficient NG as a fuel has major advantages and importance. If the sulfur content of natural gas will decrease in how much it is substantially upgraded. The main problems and difficulties encountered method of removing minor amounts of sulfur remaining in gases after conversion of the major portion of the sulfur content of the gas to elemental sulfur by the Claus or Stretford methods, or any method. Low-quality NG contains hydrogen sulfide, carbon dioxide, and nitrogen, but is not suitable for treatment using current conventional gas treating methods due to economic and environmental challenges. To remove sulfur from natural gas as the most common on the Claus process is applied. However, the Claus process itself is not sufficient for removal of sulfur in the ultra level. The tail gas from the Claus reaction is then passed through a catalytic h...

Distillation is a unit operation of separating the components from a liquid mixture by selective evaporation and condensation. To obtain a pure liquid by distillation of a mixture must be applied in this process, numerous consecutive. Multistage distillation usually preferred instead of a single stage distillation. Fractional distillation is an example of a multistage distillation. Industrial-scale productions in all multistage or multitray distillation are applied. The composition of crude varies with its origin or geographical location. The contents of crude oil can be separated into different fractions with a series of fractional distillation processes.

In recent years, attention has been given to obtaining methane gas from natural gas hydrates (NGHs) sediment; but its production, economics, and safety are still far away from being commercially viable for many years, and so more research is needed. NGHs are nonstoichiometric crystalline solid compounds that form from mixtures of water molecules and light weight natural gases such as methane, ethane, propane, and carbon dioxide. They are formed in specific thermodynamic conditions, low temperatures (5–15°C) and high pressures (2–3 MPa), and are found in (a) onshore polar regions beneath permafrost and (b) offshore deep-sea sediments. Methane, NG, is the cleanest fossil fuel and its huge amounts in NGHs have carbon quantities more than double of all fossil fuels. The methods that have been proposed for NG extraction from NGHs include: (a) depressurization, (b) thermal stimulation, and (c) chemical inhibitor injections. The authors review the potential of methane gas from NGHs as an unconventional s...

Wax deposition is one of the chronic problems in the petroleum industry. The various crude oils present in the world contain wax contents of up to 32.5%. Paraffin waxes consist of straight chain saturated hydrocarbons with carbons atoms ranging from C18 to C36. Paraffin wax consists mostly with normal paraffin content (80–90%), while, the rest consists of branched paraffins (iso-paraffins) and cycloparaffins. The sources of higher molecular weight waxes in oils have not yet been proven and are under exploration. Waxes may precipitate as the temperature decreases and a solid phase may arise due to their low solubility. For instance, paraffinic waxes can precipitate out when temperature decreases during oil production, transportation through pipelines, and oil storage. The process of solvent dewaxing is used to remove wax from either distillate or residual feedstocks at any stage in the refining process. The solvents used, methyl-ethyl ketone and toluene, can then be separated from dewaxed oil filtr...

Crude oil contains four chemical group classes, namely saturates, aromatics, resins, and asphaltenes (SARA fractions). Resins fraction of crude oil comprises polar molecules often containing heteroatoms such as nitrogen, oxygen, or sulfur. Resin is a heavier fraction than aromatics and saturates. Resins are composed of fused aromatic rings with branched paraffin and polar compounds. The resin fraction is soluble in light alkanes such as pentane and heptane, but insoluble in liquid propane. The resins are adsorbed on a solid such as alumina, clay, or silica, and subsequently recovered by use of a more polar solvent and the oils (aromatics and saturates) remain in solution. The resins often coprecipitate with the asphaltenes in controlled propane deasphalting procedures. The composition of the resins can vary considerably and is dependent on the kind of precipitating liquid and on the temperature of the liquid system. The resins are adsorbed on a solid such as alumina, clay, or silica, and subsequen...

Desulfurization of crude oil using supercritical water (SCW) is one of the promising nonconventional processes for upgrading oil. SCW is an excellent solvent for high molecular weight organic compounds in crude oils. Low sulfur content of crude oil is particularly preferred. Water is one of the most commonly used supercritical fluids suitable as a substitute for organic solvents in a range of industrial processes. Supercritical fluid treatment depends on various parameters such as pressure, temperature, extraction time, solvent type, and chemical composition of the extracted material. SCW desulfurization has potential as a technique for removing sulfur from feedstocks such as heavy oil and bitumen. SCW upgrading of crude oils reduces sulfur content and decreases average molecular weight. Catalytic desulfurization of residual oil has been carried out through partial oxidation in supercritical water and thus 60% of the sulfur was removed.

A crude oil has four main SARA constituents: saturates, aromatics, resins, and asphaltenes. The asphaltenes in crude oil are the most complex and heavy organic compounds. The asphaltenes contain highly polar substituents and are insoluble in an excess of n-heptane (or n-pentane). The classic definition of asphaltenes is based on the solution properties of petroleum residuum in various solvents. Asphaltenes are a solubility range that is soluble in light aromatics such as benzene and toluene, but is insoluble in lighter paraffins. The particular paraffins, such as n-pentane and n-heptane, are used to precipitate asphaltenes from crude oil. The effects of four different solvents (water, carbon dioxide, propane, and ethanol) on the deasphalting process under the supercritical conditions were reviewed. Supercritical water is an excellent solvent for removing of high molecular weight organic compounds such as asphaltenes from crude oils under the supercritical conditions.

Currently, more than half of the oil reserves (53.3%) in the world are in the form of restorable oils such as heavy oil, extra heavy oil, oil sand, tar sands, oil shale, and bitumen. Heavy oil is one of the petroleum oil varieties that contain long chain hydrocarbons. All types of heavy oils contain asphaltenes and thus are considered very dense substances. The asphaltenes are one of the most complex and heavy organic compounds present in the heavy oil. The heavy oil is defined as one having an American Petroleum Institute scale index equal or smaller than 20°. In conventional refining procedures, heavy oil poses many challenges. Recycling and re-refining are applied techniques for the processing of petroleum based heavy oils into reusable light oils such as gasoline and diesel fuel. In this regard, catalytic pyrolysis and thermal cracking are promising technologies for light oil production. The authors review the heavy oil upgrading processes and their associated challenges with ambition to find ...

A crude oil has four main constituents: saturates, aromatics, resins, and asphaltenes. The asphaltenes in crude oil are the most complex and heavy organic compounds. The classic definition of asphaltenes is based on the solution properties of petroleum residuum in various solvents. Asphaltenes are a solubility range that is soluble in light aromatics such as benzene and toluene, but are insoluble in lighter paraffins. The particular paraffins, such as n-pentane and n-heptane, are used to precipitate asphaltenes from crude oil. Deposition of asphaltenes in petroleum crude and heavy oil can cause a number of severe problems. The precipitation of asphaltene aggregates can cause such severe problems as reservoir plugging and wettability reversal. Asphaltenes can precipitate on metal surface. Cleaning the precipitation site as well as possible appears to slow reprecipitation. To prevent deposition inside the reservoir, it is necessary to estimate the amount of deposition due to various factors. The pro...

A solid waste management system based on the 3R principle: reduce, reuse, and recycle. There are two major recycling methods for conversion of plastic wastes to synthetic fuels: (a) pyrolysis in absence and presence of catalyst and (b) thermal and/or catalytic cracking. Pyrolysis is a complex series of chemical and thermal reactions to decompose or depolymerize organic material under oxygen-free conditions. The most affecting variables of plastic pyrolysis are catalyst type and shape, temperature, and residence time. Certain types of waste plastics such as polystyrene (PS), polyethylene (PE), and polypropylene (PP) are generally used in pyrolysis. The plastic wastes can be pyrolyzed into liquid, gas, and solid residue products. The pyrolysis of plastic wastes produces a whole spectrum of hydrocarbons including paraffins, olefins, naphthalenes, and aromatics. The total yields of paraffins and olefins of PE and PP wastes obtained by pyrolysis were higher than that of PS. The oil obtained from plastic pyroly...

In general, vegetable oils are triglycerides, which consist of 18-carbon fatty acids. There is no boiling point of vegetable oils, because oils start to decompose when heated to a certain temperature after removing smoke. The smoke point is the temperature at which the oil is decomposed and where possibly toxicological relevant compounds are formed. There is a very small amount of hydrocarbons in the content of vegetable oils. Thermal cracking of triglycerides has been carried out for over 100 years, with a recent focus on converting fats and oils to liquid fuels. Catalytic pyrolysis and cracking processing have the potential to become an important process for conversion of vegetable oils into gasoline and diesel range hydrocarbons. Decarboxylation and deoxygenation mainly occur during pyrolysis and cracking reactions.

Fuel oils (numbers 1–6) are fractions of crude oil. The boiling point and carbon chain length of the fuel increases with fuel oil number. Viscosity increases with the number, and is needed to flow the heated heavy oil. No. 4 fuel oils are used as burner fuel for domestic and industrial heating and have to raise steam for power generation and marine propulsion. Recycling and rerefining are application processes for the treatment of petroleum-based heavy products by converting into reusable light products such as gasoline and No. 2 diesel fuel. Possible pyrolysis and cracking processes are appropriate. The purpose of this study is performed to obtain light products, especially gasoline and No. 2 diesel fuel from No. 4 fuel oil by the method of pyrolytic distillation. Sodium carbonate (Na2CO3) was used in pyrolysis as catalyst and the purified oil samples were blended separately with catalysts having a mass basis of 5% and 10%. If the objective is to maximize the yield of distillate producing from No. 4 fuel...

Surfactant flooding is a well-known enhanced oil recovery (EOR) technique that has been used worldwide for decades. The surfactant can meaningful lower interfacial tension and change the wetting properties. Surfactant related recovery processes are of increasing interest and importance because of high oil prices and the urge to meet energy demand. The water flooding methods include chemical flooding and low-salinity water (LSW) flooding. Chemical flooding methods have been developed to recover residual oil trapped after conventional oil recovery is getting important recovery. The LSW flooding includes injecting brine with a lower content of salt or ionic strength. Water flooding improves oil recovery by displacing oil, and injection water is usually taken from the nearest available source. The injected alkali and surfactant, so that the interfacial tension between oil and water is lowered and thus residual oil can move. There is a relationship among chemical EOR efficiency and fluid viscosity, relative pe...

Gasoline is a petroleum-derived liquid that is used primarily as a fuel in internal combustion engines (ICE), particularly spark ignition Otto Engine. Gasoline is a blend of hydrocarbons with some contaminants, including sulfur, nitrogen, oxygen, and certain metals. The four major constituent groups of gasoline are olefins, aromatics, paraffins, and napthenes. Octane number (ON) is measure of the ignition quality or flammability of gasoline. The ONs are Research Octane Number (RON) and Motor Octane Number (MON). RON is measured relative to a mixture of isooctane and n-heptane. Antiknock Index (AKI) is a measure of a fuel's ability to resist engine knock or octane quality. The AKI is an arithmetic average of RON and MON. The ON decreases with an increase chain length in the hydrocarbon molecule. The ONs increase with carbon chain branching. Another way of increasing the ON is used gasoline octane boosters as additives, such as tetraethyl lead (TEL), methyl tertiary-butyl ether (MTBE), and ferrocene. Aromat...

The aim of this study was to estimate mathematical relationships between higher heating value (HHV) and specific gravity of petroleum fuels. The HHV is an important property defining the energy content of petroleum related fuels. The specific gravities of petroleum fuels generally range from 0.56 to 0.92 (based on the specific gravity of pure water is 1 at 15.6°C). There is high regression between specific gravity and HHVs for petroleum fuels. An increase in specific gravity from 0.56 to 0.92 for petroleum fuels decreases the HHVs from 50.4 to 41.6 and the decreases are highly regular. The HHV (MJ/kg) of the petroleum sample as a function of the specific gravity of petroleum constituent can be calculated from:For aliphatics and alicyclicsHHV = –21.63SG + 62.88For aromaticsHHV = –2.67SG + 39.23According to the two equations, higher heating value of petroleum is a function of the specific gravity of petroleum constituent. The HHVs (MJ/kg) of the crude oil samples as a function of carbon (C), hydrogen (H), o...

Turkey is at the crossroads of Europe and several volatile and strategically and economically important regions, including the Caspian Sea basin region, the Middle East, and Russia. Turkey is the most important part of Caspian Sea Basin-Middle East-Turkey triangle. Its location on two continents plays a central part in Turkish history and gives the country a major advantage in serving the markets of Europe, the Middle East, Central Asia, and North Africa. Turkey's geopolitical situation will play possible important role in regional politics in the near future. Turkey's domestic energy sources especially new petroleum reserves will become important in the future. Petroleum plays very important role in foreign policies and their international relations of Caspian and Middle East countries. The Middle East itself produces 32% of the world's oil, but even more impressive is they have 64% of the total proven oil reserves in the world.

Recycling and rerefining are the applicable processes for upgrading of petroleum-based wastes by converting them into reusable products such as gasoline, diesel fuel, and heavy oil. Possible acceptable processes are cracking and pyrolysis. The aim of the study was to obtain diesel fuel from waste lubricating oil by pyrolitic distillation method, which can be used in diesel engines. If the purpose were to maximize the yield of distillate products resulting from crude oil pyrolysis, a low temperature, high heating rate, and short gas residence time process would be required. The effect of sodium carbonate (Na2CO3) as an additive on density, viscosity, flash point, sulfur content, higher heating value, and pyrolytic distillation yields was investigated. The purified oil samples are blended separately with additives having mass basis of 2%, 6%, and 10%. The mixed samples were exposed to pyrolytic distillation process to produce fuels to be used in engines.

Most the lubricant oils are generally obtained from petroleum resources. Waste lubricating oil can be converted into valuable fuel products by refining and treating processes. Recycling is the applicable process for upgrading of petroleum-based wastes by converting them into reusable products such as gasoline, diesel fuel, and heavy oil. Possible acceptable processes are cracking and pyrolysis. A pyrolytic distillation process is often employed in oil refinery operations to produce lower molecular weight hydrocarbon fuels from waste feedstocks. If the purpose is to maximize the yield of distillate products resulting from lubricant oil pyrolysis, a low temperature, high heating rate, and short gas residence time process would be required. The effect of calcium oxide (CaO) as additive on density, viscosity, flash point, sulfur content, higher heating value, and pyrolytic distillation yields was investigated. The purified oil samples are blended separately with additives having mass bases of 2%, 4%, 6%, 8%, ...

In this review, strategies for crude oil desulfurization are evaluated by reviewing desulfurization literature. The most important characteristics of crude oil that affect the market price are its sulfur content and gravity. Low sulfur content of crude oil is particularly preferred. Petroleum includes crude oil, natural gas, and heavy oil. Petroleum refineries convert crude oils and other input streams into dozens of refined (co)products. Two properties are especially useful for quickly classifying and comparing crude oils: API gravity (a measure of density) and sulfur content. Sulfur is naturally present as an impurity in fossil fuels. The removal of organosulfur compounds from crude oil is an important aspect of all countries to reduce air pollution. The sulfur compounds from gasoline are generally removed by treatment with an alkaline solution sodium plumbite. At large scales, the most economical technology for converting hydrogen sulfide into sulfur is the Claus process. This well-established process ...

Asphaltenes and resins are two of the several, but important, heavy organics present in petroleum fluids. Asphaltenes are operationally defined as the non-colatile and polar fraction of petroleum that is insoluble in n-alkanes (i.e., n-pentane). Conversely resins are defined as the non-colatile and polar fraction of petroleum that is soluble in n-alkanes (i.e., n-pentane), and aromatic solvents (i.e., toluene), and insoluble in ethyl acetate. A commonly accepted view in the petroleum chemistry is that crude oil asphaltenes form micelles which are stabilized by adsorbed resins kept in solution by aromatics. Two key parameters that control the stability of asphaltene micelles in a crude oil are the ratio of aromatics to saturates and that of resins to asphaltenes. When these ratios decrease, asphaltene micelles will coalesce and form larger aggregates. The precipitation of asphaltene aggregates can cause problems such as reservoir plugging and wettability reversal.

Physical, chemical, and fuel properties of diesel fuel samples were investigated in the research. Combustion heats as higher heating values (HHV) of the samples were determined experimentally and calculated from ultimate analysis data. The HHV (MJ kg−1) of the samples as a function of carbon (C, wt%) and hydrogen (H, wt%) was calculated from the following equation : for which the correlation coefficient was 0.999. The calorific values calculated from the equation showed a mean difference of 0.41 %.