1. α-Phosphino Amino Acids: Synthesis, Structure, and Reactivity.
- Author
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Heinicke, Joachim, Lach, Joanna, Basvani, Kaleswara R., Peulecke, Normen, Jones, Peter G., and Kockerling, Martin
- Subjects
ORGANIC synthesis ,AMINO acids ,MOLECULAR structure ,REACTIVITY (Chemistry) ,AMINES ,CHIRALITY ,HYDROLYSIS ,NICKEL catalysts ,OLIGOMERS - Abstract
One-pot three-component reactions of secondary or primary phosphines and primary amines with glyoxylic acid provide a wide variety of acyclic or cyclic phosphinoglycines, in the case of some chiral amines with high diastereoselectivity. The structure, hydrolysis, oxidation, coordination at M(CO)5 (M = Cr, Mo, W), and use in nickel-catalyzed ethylene oligomerization were studied. [ABSTRACT FROM AUTHOR]
- Published
- 2011
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