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The effect of Mo doping on the structural and dielectric properties has been investigated in detail for Co-Zn spinel ferrite. Solid state reaction technique has been used to prepare the CZMO. The structural analysis is performed using HRXRD technique which confirms the inverse spinel structure of the material. The frequency and temperature dependence of dielectric constant are studied which reveals that the dielectric dispersion is due to Maxwell-Wagner type polarization in agreement with Koop's phenomenological theory. The contribution of grain and grain boundary at high and low frequency respectively are evident in the dielectric constant. The variation of dielectric loss tangent with both the temperature and frequency has been studied. The room temperature and high frequency dielectric loss is observed to be very small. Also it is revealed that the dielectric loss tangent decreases with Mo substitution. [ABSTRACT FROM AUTHOR]

We have optimized Gd ion substitution in BiFeO 3 (BFO) and observed prominently change in structural, electrical and magnetic behavior of Bi 1+2x Gd 2x/2 Fe 1−2x O 3 ceramics synthesized through slow step sintering schedule. It is observed that with the increase in concentration of Gd (x=0.1), original structure of BFO is transformed from rhombohedral R 3 c space group to orthorhombic Pn 21 a space group. Surprisingly, unit cell volume is drastically contracted (35% for x=0.2) and the sintered specimen showed enhanced room temperature ferromagnetic behavior although the original BFO is normally G-type antiferromagnetic in nature at 643 K. It is expected that intrinsic chemical pressure within the bulk body built by the substitution of Gd in presence of excess bismuth greatly supported through unidirectional movement of electrical dipole moment with in each individual domain as a result of which suppression of leakage current with enhanced dielectric and ferroelectric hysteresis is observed. [ABSTRACT FROM AUTHOR]