1. Spectroscopic investigations and Judd-Ofelt analysis of Sm3+ doped Y2O3 transparent ceramics.
- Author
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Hu, Zongwen, Liu, Peng, Wang, Xiaodan, Wang, Jun, Liu, Jian, Zhang, Jian, Xu, Jun, and Xu, Xiaodong
- Subjects
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TRANSPARENT ceramics , *STIMULATED emission , *MOLECULAR spectra , *BRANCHING ratios , *ABSORPTION spectra , *LUMINESCENCE - Abstract
Sm3+ doped yttria transparent ceramics (Sm x Y 1-x) 2 O 3 (x = 0.01, 0.015, 0.03) were fabricated by Spark Plasma Sintering method. Absorption spectra, as well as emission spectra and luminescence lifetime were carried out at room temperature. Judd-Ofelt (J-O) theory was used to calculate the Ω t (t = 2, 4, 6) intensity parameters. The spontaneous transition probabilities, radiative lifetime, branching ratio, and stimulated emission cross-sections have been calculated for 4G 5/2 excited level. The emission cross section for the 4G 5/2 → 6H 7/2 transition at about 607 nm was calculated to be 6.73 × 10−22 cm2. The results indicate that Sm:Y 2 O 3 ceramic may be a potential reddish orange-light laser material around 607 nm. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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