1. Effect of Al doping on structural and magnetic properties of Ni50Mn37AlxSb13-x alloy.
- Author
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Ray, Mayukh K., Bagani, K., Singh, R. K., Majumdar, B., and Banerjee, S.
- Subjects
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ALUMINUM , *DOPING agents (Chemistry) , *MOLECULAR structure , *MAGNETIC properties of nickel compounds , *NICKEL alloys , *PARAMAGNETISM - Abstract
The Ni50Mn37AlxSb13-x (x=0, 1, 3 and 5) alloys were prepared by tri-arc melting technique. The replacement of Sb by Al increases the martensitic transformation temperature (TM) as well as ferromagnetic to paramagnetic transformation temperature (=start_CONVERSION_=TCA=start_CONVERSION_=) within the austenite phase. The increase in TM is found to due to the enhancement of hybridization between 3d states of Ni and Mn atoms. We also observed a large exchange bias field (HEB) of 470Oe for x=0 and it decreases with the Al concentration for field cooled (FC) magnetic hysteresis loop. A large magnetic entropy change (ΔSM) of 10J/kg-K is found for x=1 alloy under a field change (ΔH) of 50kOe and it decreased for further higher concentration of Al doping. The possible reasons for observed behaviors are discussed. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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