1. Anisotropic lattice compression of α- and β-CePdZn.
- Author
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Oomi, Gendo, Eto, Tetsujiro, Okada, Taku, and Uwatoko, Yoshiya
- Subjects
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CERIUM compounds , *CRYSTAL lattices , *PRESSURE , *BULK modulus , *ELECTRONIC structure , *FERMI surfaces - Abstract
The lattice constants of ZrNiAl type α-CePdZn and TiNiSi type β-CePdZn were measured at high pressure up to 14 GPa at room temperature using X-ray diffraction (XRD) and a diamond anvil cell. The pressure dependence of lattice constants and volume of α-CePdZn were found to be smooth without any discontinuity, and having a bulk modulus, B 0 , and its pressure derivative, B 0 ′, of 67 GPa and 5.1, respectively. On the other hand, the a and b axes as well as volume of β-CePdZn were found to show anomalous pressure dependence at around 8 GPa. B 0 and B 0 ′ of β-CePdZn were 90 GPa and 2.1, respectively. These results suggest that a crossover in the electronic states is induced by applying pressure to β-CePdZn. The origins of these anomalous behaviors are discussed in connection with crossover and change in the topology of Fermi surface. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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