1. Spin dynamics, short-range order, and spin freezing inY0.5Ca0.5BaCo4O7
- Author
-
Peter Fouquet, Christophe Payen, H. Mutka, J. R. Stewart, Georg Ehlers, and Rolf Lortz
- Subjects
Physics ,Condensed matter physics ,Magnetic moment ,Scattering ,Neutron diffraction ,Order (ring theory) ,02 engineering and technology ,Neutron scattering ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Magnetic susceptibility ,Inelastic neutron scattering ,Electronic, Optical and Magnetic Materials ,0103 physical sciences ,Condensed Matter::Strongly Correlated Electrons ,010306 general physics ,0210 nano-technology ,Spin-½ - Abstract
Y${}_{0.5}$Ca${}_{0.5}$BaCo${}_{4}$O${}_{7}$ was recently introduced as a possible candidate for capturing some of the predicted classical spin kagome ground-state features. Stimulated by this conjecture, we have taken up a more complete study of the spin correlations in this compound with neutron scattering methods on a powder sample characterized with high-resolution neutron diffraction and the temperature dependence of magnetic susceptibility and specific heat. We have found that the frustrated near-neighbor magnetic correlations involve not only the kagome planes but concern the full Co sublattice, as evidenced by the analysis of the wave-vector dependence of the short-range order. We conclude from our results that the magnetic moments are located on the Co sublattice as a whole and that correlations extend beyond the two-dimensional kagome planes. We identify intriguing dynamical properties, observing high-frequency fluctuations with a Lorentzian linewidth $\ensuremath{\Gamma}\ensuremath{\leqslant}20$ meV at ambient temperature. On cooling a low-frequency ($~$1 meV) dynamical component develops alongside the high-frequency fluctuations, which eventually becomes static at temperatures below $T\ensuremath{\approx}50$ K. The high-frequency response with an overall linewidth of $~$10 meV prevails at $T\ensuremath{\leqslant}2$ K, coincident with a fully elastic short-range-ordered contribution.
- Published
- 2011
- Full Text
- View/download PDF