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Liquids are condensed matter in which atoms are strongly correlated in position and momentum. The atomic pair density function (PDF) is used often in describing such correlation. However, elucidation of many properties requires higher degrees of correlation than the pair correlation. For instance, viscosity depends upon the stress correlations in space and time. In this paper, we examine the cross correlation between the stress correlation at the atomic level and the PDF for two-dimensional liquids. We introduce the concept of the stress-resolved pair distribution function (SRPDF) that uses the sign of atomic-level stress as a selection rule to include particles from density correlations. The connection between SRPDFs and stress correlation function is explained through an approximation in which the shear stress is replaced by a pseudospin. We further assess the possibility of interpreting the long-range stress correlation as a consequence of short-range Ising-like pseudospin interactions. [ABSTRACT FROM AUTHOR]

In this paper we demonstrate the presence of anisotropic stress correlations in the simulated two-dimensional liquids. Whereas the temporal correlation of macroscopic shear stress is known to contribute to viscosity via the Green-Kubo formula, the general question regarding angular dependence of the spatial correlation among atomiclevel stresses in liquids without external shear has not been explored. We observed the apparent anisotropicity with well-defined symmetry which can be explained in terms of the elastic continuum theory by Eshelby. In addition, we found that the shear stress correlation is screened compared to the prediction by the elastic continuum theory, and the screening length depends on temperature and follows the power law, suggesting divergence around the glass transition temperature. The success of the Eshelby theory to explain the anisotropy of the stress correlations justifies the idea that the mismatch between the atom and its nearest neighbor cage produces the atomic-level stress as well as the long-range stress fields. [ABSTRACT FROM AUTHOR]