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The surface shear rheology of many insoluble surfactants depends strongly on the surface pressure (or concentration) of that surfactant. Here we highlight the dramatic consequences that surface-pressure-dependent surface viscosities have on interfacially dominant flows, by considering lubrication-style geometries within high Boussinesq (Bo) number flows. As with three-dimensional lubrication, high-Bo surfactant flows through thin gaps give high surface pressures, which in turn increase the local surface viscosity, further amplifying lubrication stresses and surface pressures. Despite their strong nonlinearity, the governing equations are separable, so that results from two-dimensional Newtonian lubrication analyses may be immediately adapted to treat surfactant monolayers with a general functional form of ηs(Π). Three paradigmatic systems are analyzed to reveal qualitatively new features: a maximum, self-limiting value for surfactant fluxes and particle migration velocities appears for Π-thickening surfactants, and kinematic reversibility is broken for the journal bearing and for suspensions more generally.

The mechanics of curved, heterogeneous, surfactant-laden surfaces and interfaces are important to a variety of engineering and biological applications. To date, most models of rheologically complex interfaces have focused on homogeneous systems of planar or fixed curvature. In this study, we investigate a simple, dynamical model of a two-phase surface fluid on a curved interface: a condensed, surface-viscous domain embedded within a surface-inviscid, spherical interface of time-varying radius of curvature. Our aim is to understand how changes in surface curvature generate two-dimensional Stokes flows inside the domain, thereby resisting curvature deformation and distorting the domain shape. We model the surface stress within the domain using the classical Boussinesq-Scriven constitutive equation, simplified for a near-spherical cap undergoing a small-amplitude curvature deformation. We then analyze the frequency-dependent dynamics of the surface stress and curvature within the domain when the pressure difference across the surface is sinusoidally oscillated. We find that the curvature relaxes diffusively, and thus define a Peclet number (Pe) relating the rate of diffusion to the oscillation frequency. At small enough Pe, the surface deforms quasi-statically, whereas at high Pe, the curvature varies sharply within a thin boundary layer adjacent to the domain border. Consequently, the curvature of the domain appears discontinuous from the rest of the surface under rapid oscillation. We then examine the linear stability of the domain shape to small, non-axisymmetric perturbations when the surface is steadily compressed (i.e., the pressure difference across it is increased). While the line tension at the domain border tends to maintain circular symmetry, surface-viscous stresses generated by surface compression tend to destabilize the perimeter. A shape instability arises above a critical surface capillary number (Ca) relating surface-viscous stresses to line tension. Moreover, we show that the mechanism of instability is distinct from that of the famous Saffman-Taylor fingering instability. Various extensions of our model are discussed, including materials with finite dilatational surface viscosity, linear and nonlinear (visco)elasticity, and large-amplitude deformations.