1. Dynamics of ion transport in ionic liquids
- Author
-
Svyatoslav Kondrat, Alain Goriely, Dominic Vella, Alpha A. Lee, Lee, Alpha [0000-0002-9616-3108], Kondrat, Svyatoslav [0000-0003-4448-0686], Vella, Dominic [0000-0003-1341-8863], and Apollo - University of Cambridge Repository
- Subjects
Anions ,Materials science ,FOS: Physical sciences ,General Physics and Astronomy ,Ionic Liquids ,Electrolyte ,Condensed Matter - Soft Condensed Matter ,chemistry.chemical_compound ,Physics - Chemical Physics ,Lattice (order) ,Cations ,Statistical physics ,Condensed Matter - Statistical Mechanics ,Ion transporter ,Chemical Physics (physics.chem-ph) ,Statistical Mechanics (cond-mat.stat-mech) ,Continuum (measurement) ,Temperature ,chemistry ,Models, Chemical ,Chemical physics ,Ionic liquid ,Soft Condensed Matter (cond-mat.soft) ,Granularity ,Transport phenomena ,Equations for a falling body - Abstract
A gap in understanding the link between continuum theories of ion transport in ionic liquids and the underlying microscopic dynamics has hindered the development of frameworks for transport phenomena in these concentrated electrolytes. Here, we construct a continuum theory for ion transport in ionic liquids by coarse graining a simple exclusion process of interacting particles on a lattice. The resulting dynamical equations can be written as a gradient flow with a mobility matrix that vanishes at high densities. This form of the mobility matrix gives rise to a charging behaviour that is different to the one known for electrolytic solutions, but which agrees qualitatively with the phenomenology observed in experiments and simulations., Comment: To appear in PRL
- Published
- 2015