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The PTAL project aims at building and exploiting a database involving several analytical techniques, the Planetary Terrestrial Analogues Library, to help characterizing the mineralogical evolution of terrestrial bodies, starting with Mars. A total of 94 natural Earth rocks have been collected from selected locations around the world to get a selection of analogues for Martian geology. The PTAL library gathers a variety of igneous rocks from different plutonic and volcanic origins and compositions, associated to different environments and levels of aqueous alteration. Samples of impact craters and sedimentary units are also present. The full set of samples will be characterized with optical thin section analysis and XRD (Oslo University, Norway), NIR spectroscopy (Paris-Saclay University, France), Raman spectroscopy (Valladolid University, Spain) and LIBS (Paul Sabatier University, France). The multianalytical study used within the PTAL project provides an unique opportunity to coordinate minerals/elements detection by different techniques that are similar to the instruments onboard current and forthcoming Martian missions. Such combined analysis should give the opportunity to prepare and improve ExoMars/ESA-Roscosmos and Mars2020/NASA observations. This paper focuses only on the NIR measurements and interpretations. The diversity of the PTAL samples is well revealed by the diversity of spectra from the NIR observations. The detected minerals are representative of various formation, alteration and geochemical environments. The major diagnostic features observed are those of primary Fe2+ bearing silicates like olivine or pyroxene with low and/or high calcium content; altered silicates detected with vibrational features associated to OH and/or H2O and/or metal-OH features; oxides; zeolites; and carbonates. This collection brings together a set of rocks and minerals that have been reported elsewhere in the Solar System and particularly on Mars.

Phyllosilicate deposits on Mars provide an opportunity to evaluate aqueous activity and the possibility that habitable environments may have existed during the Noachian period there. Analysis of hyperspectral visible/near-infrared (VNIR) Mars Reconnaissance Orbiter (MRO) Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) images has shown thick, complex profiles of phyllosilicates at Mawrth Vallis, Mars that are consistent with long-term aqueous activity and active chemistry. The ancient phyllosilicates in places such as this could have served as reaction centers for organic molecules. Previous experiments even suggest that phyllosilicates could have played a role in the origin of life. Regardless of whether life formed on early Mars or not, evaluating the type and thickness of clay-bearing units on Mars provides insights into plausible aqueous processes and chemical conditions both during the time of formation of the phyllosilicates, but also the subsequent period following their formation. The phyllosilicate outcrops at Mawrth Vallis extend across a broad (∼1000 km) region and exhibit a consistent general trend of Al-phyllosilicates and amorphous Al/Si species at the top of the clay profile and Fe/Mg-phyllosilicates on the bottom. This implies either a change in water chemistry, a change in material being altered, or an alteration profile where the upper clays were leached and altered more significantly than those below. A change in iron in the phyllosilicate units is also observed such that an Fe2+-bearing unit is frequently observed between the Fe3+- and Mg-rich phyllosilicates below and the Al/Si-rich materials above. Abrupt changes in chemistry like this are often indicative of biogeochemical activity on Earth. Possible microbe-clay interactions are considered in comparison with the CRISM observations. This study evaluates CRISM spectra from four images of different outcrops across the Mawrth Vallis region and evaluates the observed phyllosilicates and clay components in terms of plausible aqueous and microbial processes and the potential for retention of biosignatures, if present.

The Mawrth Vallis area displays some of the largest phyllosilicate-rich outcrops of Mars, on Noachian highlands. The Mawrth Vallis region is located just at the dichotomy boundary between the Noachian highlands and the younger, northern lowlands. A large, thick, layered clay-rich unit is present throughout the inter-crater plateaus. Clay-rich layers have also been identified in parts of the Mawrth Vallis and Oyama crater floors. The age of the alteration and its relationships with other processes such as fluvial activity is fundamental for estimating the timing of aqueous activity and habitability in this region, and on Mars. We have investigated the relative stratigraphy and ages of the regional plateau, of key surfaces of the inter-crater plateau, of Oyama crater's floor and of Chryse Planitia deposits in Mawrth Vallis' mouth to constrain the age of the clay unit and its alteration. According to the cratering model results, the main layered unit may have started forming prior to ∼4.0 Ga ago, was largely deposited by ∼3.9 Ga ago, and suffered erosion and redeposition up to ∼3.8 Ga ago, as indicated by the latest age of the deposits on the floor of Oyama crater. Surface aqueous alteration stopped no later than 3.7–3.6 Ga ago, corresponding to the age of the dark, non-altered material capping the region, and of the dark deposits in Mawrth Vallis' mouth. This work provides useful boundaries for constraining the time period of surface or shallow sub-surface water activity in this region. This preserved window into early phases of aqueous activity on Mars gives us a unique opportunity to study an aqueous environment of exobiological interest in the early solar system.