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In this work, we report on the synthesis of ethyl lactate-based plasma polymer film (ELPPF) by plasma enhanced chemical vapour deposition (PECVD). Using a design of experiments, it appears that, among other, the injected power ( PRF) is the key parameter affecting the ELPPF features. Indeed, we observe a strong decrease of the COO-C/H functionalities (from 12 to 2 at.%) within a limited PRF domain. A more precise analysis of the film chemistry by combining XPS and chemical derivatization reveals that up to 95% of these carboxyl-based functions are esters. On the other hand, we show that the cross-linking degree of the ELPPF can be increased by a factor of two as a function of PRF. This work paves the way for the tailoring of the barrier properties of ELPPF by controlling the ester content and the cross-linking degree of the PPF. [ABSTRACT FROM AUTHOR]