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1. Indium-mediated monoallylation of carbonyl compounds with allylic chlorides and bisallylation of 2-pyridyl carboxylates with allylic halides in aqueous media

Author

Soon Bang Kang, Youseung Kim, Kyung Eun Oh, Gyochang Keum, and Jehyeon Yoo

Subjects
Inorganic Chemistry, Allylic rearrangement, Aqueous medium, Chemistry, Sonication, Reagent, Materials Chemistry, chemistry.chemical_element, Organic chemistry, Halide, Physical and Theoretical Chemistry, Allyl halides, Indium
Abstract

Allylic chlorides are efficient reagents in the indium-mediated Barbier-type allylation reaction with various aldehydes and ketones in pure water under sonication or in a 1:1 mixture of H 2 O and t-BuOH. Also indium is effective in bisallylation reactions of the 2-pyridyl esters with allyl halides in pure water.

Published
2000
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