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Foaming behavior of thermoplastic polyurethane (TPU) is extremely difficult to be regulated due to the special microphase-separation structure. Therefore, organic montmorillonite (O-MMT) was applied in TPU foaming to regulate cell nucleation, growth and stabilization simultaneously: (1) strong interfacial interaction between O-MMT with TPU could not only facilitate O-MMTs’ nanoscale dispersion but also ensure a similar cell nucleation at various O-MMT loading, which effectively decoupled the complicated influences of cell nucleation and growth on TPU foam's shrinkage; (2) TPU/O-MMT topological network was constructed by O-MMT loading, regulating cell growth and corresponding decreasing cell size; (3) -OH group on O-MMT surface could hydrogen bond with TPU molecular chains in soft/hard segments, stabilizing TPU molecular chains and finally reducing foams' shrinkage. Combining hydrogen bonding and topological network resulted from O-MMT, it enables us to optimize TPU foam structure by controlling cell nucleation, growth and stabilization simultaneously, the optimal O-MMT loading was 1 wt%.

Properties of plastic products depend on their microstructure and morphology. To improve the pressure rating (maximum pressure) of plastic pipes, a novel rotational shear system (RSS) was developed in this study to fabricate plastic pipes with enhanced hoop tensile strength through applying hoop shear on the pipes using a rotational mandrel. Morphology study results showed that different morphologies of the HDPE pipes were produced when the mandrel rotated at 5 rpm, 7.5 rpm, 10 rpm, 12.5 rpm and 15 rpm. The hoop tensile strength and heat resistance of the pipes were found to increase rapidly with the rotation speed and the properties peaked at 7.5 rpm. At this speed, the hoop tensile strength and Vicat softening temperature (VST) increased by about 338% and 26.8 °C, respectively. The axial tensile strength of the pipe was also slightly improved under this condition. The high mechanical and thermal performance of the pipe produced at 7.5 rpm was attributed to homogeneously distributed shish-kebab structures throughout the pipe wall.