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This study aims to examine the 50/50 polypropylene/polyamide 6 (iPP/PA6) system molded under confined flow conditions, both in its original state and after being modified by two different interfacial agents. This study provides two main insights. Firstly, it focuses on a polymer blend close to phase inversion. Secondly, it investigates the impact of using two different types of interfacial agents (derived from polymer waste) to enhance the compatibility between iPP and PA6. Dynamic Mechanical Analysis (DMA) has been employed to achieve these objectives. It is important to note that the investigation of the 50/50 iPP/PA6 system is a crucial focus predicted in previous studies, where a series of mechanical properties were evaluated using Box-Wilson design of experiments (DOEs) over the whole compositional range on the iPP/PA6 binary system. Thus, two interfacial modifiers, namely succinic anhydride (SA)-grafted atactic polypropylene with terminal, side, and bridge SA grafts (aPP-SASA) and succinyl-fluoresceine (SF) with bridge succinic anhydride grafting atactic polypropylene (aPP-SFSA), were employed. The authors obtained and characterized these agents. The quantity of these agents used in the blend was identified as a critical coordinate in prior studies conducted by the authors. The processing method used, compression molding under confined conditions, was chosen to minimize any orientation effect on the emerging morphology. All characterization procedures were performed on samples processed by contour machining to retain the blend morphologies as they emerged from the processing stage. Results from WAXS and SAXS synchrotron tests concluded there were no changes in the crystal morphology of the iPP or the PA6 in the blends nor any co-crystallization process throughout the compositional range. These findings, and the long period fits on the PP crystalline phase for the fifty/fifty blends we are discussing, will support the present DMA study. Finally, the efficiency of these interfacial modifiers has been concluded, even in this unfavorable scenario.

The present work deeply studied the mechanical behavior of woven non-woven PLA/OLA/MgO electrospun fibers, efibers, by using Box-Wilson surface response methodology. This work follows up a previous one where both the diameters and the thermal response of such efibers were discussed in terms of both the different amounts of magnesium oxide nanoparticles, MgO, as well as of the oligomer (lactic acid), OLA, used as plasticizer. The results of both works, in term of diameters, degree of crystallinity, and mechanical response, can be strongly correlated to each other, as reported here. In particular, the strain mechanism of PLA/OLA/MgO efibers was studied, showing an orientation of efibers parallel to the applied stress and identifying the mechanically weakest points that yielded the start of the breakage of efibers. Moreover, we identified 1.5 wt% as the critical amount of MgO, above which the plasticizing effect of OLA was weaker as the amount of both components increased. Moreover, the minimum elastic modulus value took place at 15 wt% of OLA, in agreement with the previously reported convergence point in the evolution of the degree of crystallinity. Regarding the yield point, a concentration of OLA between 20 and 30 wt% led to a slight improvement in the yielding capability in terms of tensile strength in comparison with neat PLA efibers. Therefore, the approach presented here permits the design of tailor-made electrospun nanocomposites with specific mechanical requirements.

This work has a two-fold objective. First, it attempts to present the excellent efficiency of a maleated interfacial agent (obtained by the authors by using atactic polypropylene industrial waste) when used as interfacial additive in polypropylene/short carbon fiber composites (iPP/SCF). Second, in this paper, we pay attention to the role played by processing in the final properties of the composite. This work has been performed by considering the emerging crystalline morphologies generated by the different shear forces that the molten material suffers depending on the molding method employed. The interfacial agent analyzed here consists of an atactic polypropylene containing succinic anhydride grafts obtained through a chemical modification process performed in solution. It incorporates different types of succinic grafts, such as succinic bridges between aPP chains and backbone and terminal grafts (aPP-SASA) in its structure, and contains 5.6% (5.6 × 10 -4 g/mol) of grafted polar groups in total. The adhesion of the polyamide SCF sizing and the succinic units is followed by Field Emission Scanning Electronic Microscopy (FESEM) and Synchrotron Infrared Microscopy (SIRM). However, the main objective of this work is the study of the thermal and the dynamic mechanical behavior of the materials of a series of both compression- and injection-molded samples to ascertain the enhanced interfacial interactions in the material and further comparison between the results obtained by both processing operations. Therefore, we detect improvements of 200% in stiffness and 400% in the viscous response of the same SCF content composites caused by aPP-SASA, depending on the processing method used.

In the present work, a statistical study of the morphology and thermal behavior of poly(lactic acid) (PLA)/oligomer(lactic acid) (OLA)/magnesium oxide nanoparticles (MgO), electrospun fibers (efibers) has been carried out. The addition of both, OLA and MgO, is expected to modify the final properties of the electrospun PLA-based nanocomposites for their potential use in biomedical applications. Looking for the compositional optimization of these materials, a Box−Wilson design of experiment was used, taking as dependent variables the average fiber diameter as the representative of the fiber morphologies, as well as the glass transition temperature (Tg) and the degree of crystallinity (Xc) as their thermal response. The results show values of 73.76% (diameter), 88.59% (Tg) and 75.61% (Xc) for each polynomial fit, indicating a good correlation between both OLA and MgO, along with the morphological as well as the thermal behavior of the PLA-based efibers in the experimental space scanned.

This work deals with the changes of the glass transition temperature (T g ) of the polymer in polypropylene/mica composites due to the combined and synergistic effect of the reinforcement and the interfacial modifier. In our case, we studied the effect on T g of platy mica and an interfacial modifier with p -phenylen-bis-maleamic acid ( p PBMA) grafted groups onto atactic polypropylene (aPP- p PBMA). This one contains 5.0 × 10 -4 g·mol -1 (15% w/w ) grafted p PBMA and was previously obtained by the author's labs by using industrial polymerization wastes (aPP). The objective of the article must be perceived as two-fold. On one hand, the determination of the changes in the glass transition temperature of the isotactic polypropylene phase (iPP) due to both the reinforcement and the agent as determined form the damp factor in DMA analysis. On the other hand, forecasting the variation of this parameter (T g ) as a function of both the interfacial agent and reinforcement content. For such purposes, and by assuming the complex character of the iPP/aPP- p PBMA/Mica system, wherein interaction between the components will define the final behaviour, a Box-Wilson experimental design considering the amount of mica particles and of interface agent as the independent variables, and the T g as the dependent one, has been used. By taking in mind that the glass transition is a design threshold for the ultimate properties of parts based in this type of organic-inorganic hybrid materials, the final purpose of the work is the prediction and interpretation of the effect of both variables on this key parameter.

The present article adequately supports a twofold objective. On one hand, the study of the dynamic mechanical behavior of polypropylene/polyamide-6 blends modified by a novel compatibilizer was the objective. This was previously obtained by chemical modification of an atactic polypropylene polymerization waste. On the other hand, the accurate predictions of these properties in the experimental space scanned was the objective. As a novelty, this compatibilizer contains grafts rather than just maleated ones. Therefore, it consists precisely of an atactic polymer containing succinic anhydride (SA) bridges and both backbone and terminal grafted succinyl-fluorescein groups (SFSA) attached to the atactic backbone (aPP-SFSA). Therefore, it contains 6.2% of total grafting (2.5% as SA and 3.7% as SF), which is equivalent to 6.2·× 10 -4 g·mol -1 . This interfacial agent was uniquely designed and obtained by the authors themselves. Essentially, this article focuses on how the beneficial effect of both PA6 and aPP-SFSA varies the elastic ( E ') and the viscous ( E '') behavior of the iPP/aPP-SFSA/PA6 blend at the iPP glass transition. Thus, we accurately measured the Dynamic Mechanical Analysis (DMA) parameters ( E ', E '') at this specific point considering it represents an extremely unfavorable scenario for the interfacial modifier due to mobility restrictions. Hence, this evidences the real interfacial modifications caused by aPP-SFSA to the iPP/PA6 system. Even more, and since each of the necessary components in the blend typically interacts with one another, we employed a Box-Wilson experimental design by its marked resemblance to the "agent-based models". In this manner, we obtained complex algorithms accurately forecasting the dynamic mechanical behavior of the blends for all the composition range of the iPP/aPP-SFSA/PA6 system at the glass transition of iPP.