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Anodized aluminum oxide (AAO) molds were used for the production of large-area and inexpensive superhydrophobic polymer films. A controlled anodization methodology was developed for the fabrication of hierarchical micro-nanoporous (HMN) AAO imprint molds (HMN-AAO), where phosphoric acid was used as both an electrolyte and a widening agent. Heat generated upon repetitive high-voltage (195 V) anodization steps is effectively dissipated by establishing a cooling channel. On the HMN-AAO, within the hemispherical micropores, arrays of hexagonal nanopores are formed. The diameter and depth of the micro- and nanopores are 18/8 and 0.3/1.25 µm, respectively. The gradual removal of micropatterns during etching in both the vertical and horizontal directions is crucial for fabricating HMN-AAO with a high aspect ratio. HMN-AAO rendered polycarbonate (PC) and polymethyl methacrylate (PMMA) films with respective water contact angles (WCAs) of 153° and 151°, respectively. The increase in the WCA is 80% for PC (85°) and 89% for PMMA (80°). On the PC and PMMA films, mechanically robust arrays of nanopillars are observed within the hemispherical micropillars. The micro-nanopillars on these polymer films are mechanically robust and durable. Regular nanoporous AAO molds resulted in only a hydrophobic polymer film (WCA = 113-118°). Collectively, the phosphoric acid-based controlled anodization strategy can be effectively utilized for the manufacturing of HMN-AAO molds and roll-to-roll production of durable superhydrophobic surfaces.

The development of environmentally friendly technology is vital to effectively address the issues related to environmental deterioration. This work integrates ZnO-decorated MoS 2 (MZ) to create a high-performing PVDF-based PVDF/MoS 2 -ZnO (PMZ) hybrid polymer composite film for sonocatalytic organic pollutant degradation. An efficient synergistic combination of MZ was identified by altering the ratio, and its influence on PVDF was assessed using diverse structural, morphological, and sonocatalytic performances. The PMZ film demonstrated very effective sonocatalytic characteristics by degrading rhodamine B (RhB) dye with a degradation efficiency of 97.23%, whereas PVDF only degraded 17.7%. Combining MoS 2 and ZnO reduces electron-hole recombination and increases the sonocatalytic degradation performance. Moreover, an ideal piezoelectric PVDF polymer with MZ enhances polarization to improve redox processes and dye degradation, ultimately increasing the degradation efficiency. The degradation efficiency of RhB was seen to decrease while employing isopropanol (IPA) and p-benzoquinone (BQ) due to the presence of reactive oxygen species. This suggests that the active species •O 2 and •OH are primarily responsible for the degradation of RhB utilizing PMZ2 film. The PMZ film exhibited improved reusability without substantially decreasing its catalytic activity. The superior embellishment of ZnO onto MoS - and •OH are primarily responsible for the degradation of RhB utilizing PMZ2 film. The PMZ film exhibited improved reusability without substantially decreasing its catalytic activity. The superior embellishment of ZnO onto MoS 2 and effective integration of MZ into the PVDF polymer film results in improved degrading performance.

Customer demand for natural packaging materials in the food industry has increased. Biocomposite films developed using boiled rice water could be an eco-friendly and cost-effective packaging product in the future. This study reports the development of bio-based films using waste materials, such as boiled rice water (matrix) and Pistacia vera shells (reinforcement material), using an adapted solution casting method. Several film combinations were developed using various concentrations of plasticizing agent (sorbitol), thickening agent (oil and agar), and stabilizing agents (Arabic gum, corn starch, and Pistacia vera shell powder). Various packaging properties of the film were analyzed and examined to select the best bio-based film for food packaging applications. The film fabricated with Pistacia vera shell powder in the biocomposite film exhibited a reduced water solubility, swelling index, and moisture content, as compared to polyethene packaging material, whereas the biocomposite film exhibited poor antimicrobial properties, high vapor transmission rate, and high biodegradability rate. The packaging properties and characterization of the film indicated that the boiled rice water film with Pistacia vera shell powder was suitable for packaging material applications.

Microbial fuel cells (MFCs) provide considerable benefits in the energy and environmental sectors for producing bioenergy during bioremediation. Recently, new hybrid composite membranes with inorganic additives have been considered for MFC application to replace the high cost of commercial membranes and improve the performances of cost-effective polymers, such as MFC membranes. The homogeneous impregnation of inorganic additives in the polymer matrix effectively enhances the physicochemical, thermal, and mechanical stabilities and prevents the crossover of substrate and oxygen through polymer membranes. However, the typical incorporation of inorganic additives in the membrane decreases the proton conductivity and ion exchange capacity. In this critical review, we systematically explained the impact of sulfonated inorganic additives (such as (sulfonated) sSiO 2 , sTiO 2 , sFe 3 O 4 , and s-graphene oxide) on different kinds of hybrid polymers (such as PFSA, PVDF, SPEEK, SPAEK, SSEBS, and PBI) membrane for MFC applications. The membrane mechanism and interaction between the polymers and sulfonated inorganic additives are explained. The impact of sulfonated inorganic additives on polymer membranes is highlighted based on the physicochemical, mechanical, and MFC performances. The core understandings in this review can provide vital direction for future development.

A direct methanol fuel cell (DMFC) is an excellent energy device in which direct conversion of methanol to energy occurs, resulting in a high energy conversion rate. For DMFCs, fluoropolymer copolymers are considered excellent proton-exchange membranes (PEMs). However, the high cost and high methanol permeability of commercial membranes are major obstacles to overcome in achieving higher performance in DMFCs. Novel developments have focused on various reliable materials to decrease costs and enhance DMFC performance. From this perspective, cellulose-based materials have been effectively considered as polymers and additives with multiple concepts to develop PEMs for DMFCs. In this review, we have extensively discussed the advances and utilization of cost-effective cellulose materials (microcrystalline cellulose, nanocrystalline cellulose, cellulose whiskers, cellulose nanofibers, and cellulose acetate) as PEMs for DMFCs. By adding cellulose or cellulose derivatives alone or into the PEM matrix, the performance of DMFCs is attained progressively. To understand the impact of different structures and compositions of cellulose-containing PEMs, they have been classified as functionalized cellulose, grafted cellulose, acid-doped cellulose, cellulose blended with different polymers, and composites with inorganic additives., Competing Interests: The authors declare no conflicts of interest.

Hydrogen fuel cell (FC) technologies are being worked on as a possible replacement for fossil fuels because they produce a lot of energy and do not pollute the air. In FC, ion-exchange membranes (IEMs) are the vital components for ion transport between two porous electrodes. However, the high production cost of commercialized membranes limits their benefits. Various research has focused on cellulose-based membranes such as IEM with high proton conductivity, and mechanical, chemical, and thermal stabilities to replace the high cost of synthetic polymer materials. In this review, we focus on and explain the recent progress (from 2018 to 2022) of cellulose-containing hybrid membranes as cation exchange membranes (CEM) and anion exchange membranes (AEM) for proton exchange membrane fuel cells (PEMFC) and alkaline fuel cells (AFC). In this account, we focused primarily on the effect of cellulose materials in various membranes on the functional properties of various polymer membranes. The development of hybrid membranes with cellulose for PEMFC and AFC has been classified based on the combination of other polymers and materials. For PEMFC, the sections are associated with cellulose with Nafion, polyaryletherketone, various polymeric materials, ionic liquid, inorganic fillers, and natural materials. Moreover, the cellulose-containing AEM for AFC has been summarized in detail. Furthermore, this review explains the significance of cellulose and cellulose derivative-modified membranes during fuel cell performance. Notably, this review shows the vital information needed to improve the ion exchange membrane in PEMFC and AFC technologies.

Polymers are well-recognized carriers useful for delivering therapeutic drug and imaging probes to the target specified in the defined pathophysiological site. The functional drug molecules and imaging agents were chemically attached or physically loaded in the carrier polymer matrix via cleavable spacers. Using appropriate targeting moieties, these polymeric carriers (PCs) loaded with functional molecules were designed to realize target-specific delivery at the cellular level. The biodistribution of these carriers can be tracked using imaging agents with suitable imaging techniques. The drug molecules can be released by cleaving the spacers either by endogenous stimuli (e.g., pH, redox species, glucose level and enzymes) at the targeted physiological site or exogenous stimuli (e.g., light, electrical pulses, ultrasound and magnetism). Recently, two-photon absorption (2PA)-mediated drug delivery and imaging has gained significant attention because TPA from near-infrared light (700-950 nm, NIR) renders light energy similar to the one-photon absorption from ultraviolet (UV) light. NIR has been considered biologically safe unlike UV, which is harmful to soft tissues, cells and blood vessels. In addition to the heat and reactive oxygen species generating capability of 2PA molecules, 2PA-functionalized PCs were also found to be useful for treating diseases such as cancer by photothermal and photodynamic therapies. Herein, insights attained towards the design, synthesis and biomedical applications of 2PA-activated PCs are reviewed. In particular, specific focus is provided to the imaging and drug delivery applications with a special emphasis on multi-responsive platforms.

In the present scenario, much importance has been provided to hydrogen energy systems (HES) in the energy sector because of their clean and green behavior during utilization. The developments of novel techniques and materials have focused on overcoming the practical difficulties in the HES (production, storage and utilization). Comparatively, considerable attention needs to be provided in the hydrogen storage systems (HSS) because of physical-based storage (compressed gas, cold/cryo compressed and liquid) issues such as low gravimetric/volumetric density, storage conditions/parameters and safety. In material-based HSS, a high amount of hydrogen can be effectively stored in materials via physical or chemical bonds. In different hydride materials, Mg-based hydrides (Mg-H) showed considerable benefits such as low density, hydrogen uptake and reversibility. However, the inferior sorption kinetics and severe oxidation/contamination at exposure to air limit its benefits. There are numerous kinds of efforts, like the inclusion of catalysts that have been made for Mg-H to alter the thermodynamic-related issues. Still, those efforts do not overcome the oxidation/contamination-related issues. The developments of Mg-H encapsulated by gas-selective polymers can effectively and positively influence hydrogen sorption kinetics and prevent the Mg-H from contaminating (air and moisture). In this review, the impact of different polymers (carboxymethyl cellulose, polystyrene, polyimide, polypyrrole, polyvinylpyrrolidone, polyvinylidene fluoride, polymethylpentene, and poly(methyl methacrylate)) with Mg-H systems has been systematically reviewed. In polymer-encapsulated Mg-H, the polymers act as a barrier for the reaction between Mg-H and O 2 /H 2 O, selectively allowing the H 2 gas and preventing the aggregation of hydride nanoparticles. Thus, the H 2 uptake amount and sorption kinetics improved considerably in Mg-H.

With regard to global concerns, such as water scarcity and aquatic pollution from industries and domestic activities, membrane-based filtration for wastewater treatment has shown promising results in terms of water purification. Filtration by polymeric membranes is highly efficient in separating contaminants; however, such membranes have limited applications. Nanocomposite membranes, which are formed by adding nanofillers to polymeric membrane matrices, can enhance the filtration process. Considerable attention has been given to nanofillers, which include carbon-based nanoparticles and metal/metal oxide nanoparticles. In this review, we first examined the current status of membrane technologies for water filtration, polymeric nanocomposite membranes, and their applications. Additionally, we highlight the challenges faced in water treatment in developing countries.

According to the Global Burden of Diseases, Injuries, and Risk Factors Study, cases of bone fracture or injury have increased to 33.4% in the past two decades. Bone-related injuries affect both physical and mental health and increase the morbidity rate. Biopolymers, metals, ceramics, and various biomaterials have been used to synthesize bone implants. Among these, bioactive glasses are one of the most biomimetic materials for human bones. They provide good mechanical properties, biocompatibility, and osteointegrative properties. Owing to these properties, various composites of bioactive glasses have been FDA-approved for diverse bone-related and other applications. However, bone defects and bone injuries require customized designs and replacements. Thus, the three-dimensional (3D) printing of bioactive glass composites has the potential to provide customized bone implants. This review highlights the bottlenecks in 3D printing bioactive glass and provides an overview of different types of 3D printing methods for bioactive glass. Furthermore, this review discusses synthetic and natural bioactive glass composites. This review aims to provide information on bioactive glass biomaterials and their potential in bone tissue engineering.

In recent years, vanadium redox flow batteries (VRFB) have captured immense attraction in electrochemical energy storage systems due to their long cycle life, flexibility, high-energy efficiency, time, and reliability. In VRFB, polymer membranes play a significant role in transporting protons for current transmission and act as barriers between positive and negative electrodes/electrolytes. Commercial polymer membranes (such as Nafion) are the widely used IEM in VRFBs due to their outstanding chemical stability and proton conductivity. However, the membrane cost and increased vanadium ions permeability limit its commercial application. Therefore, various modified perfluorinated and non-perfluorinated membranes have been developed. This comprehensive review primarily focuses on recent developments of hybrid polymer composite membranes with inorganic TiO 2 nanofillers for VRFB applications. Hence, various fabrications are performed in the membrane with TiO 2 to alter their physicochemical properties for attaining perfect IEM. Additionally, embedding the -SO 3 H groups by sulfonation on the nanofiller surface enhances membrane proton conductivity and mechanical strength. Incorporating TiO 2 and modified TiO 2 (sTiO 2 , and organic silica modified TiO 2 ) into Nafion and other non-perfluorinated membranes (sPEEK and sPI) has effectively influenced the polymer membrane properties for better VRFB performances. This review provides an overall spotlight on the impact of TiO 2 -based nanofillers in polymer matrix for VRFB applications.

Polymeric hydrogels are widely explored materials for biomedical applications. However, they have inherent limitations like poor resistance to stimuli and low mechanical strength. This drawback of hydrogels gave rise to ''smart self-healing hydrogels'' which autonomously repair themselves when ruptured or traumatized. It is superior in terms of durability and stability due to its capacity to reform its shape, injectability, and stretchability thereby regaining back the original mechanical property. This review focuses on various self-healing mechanisms (covalent and non-covalent interactions) of these hydrogels, methods used to evaluate their self-healing properties, and their applications in wound healing, drug delivery, cell encapsulation, and tissue engineering systems. Furthermore, composite materials are used to enhance the hydrogel's mechanical properties. Hence, findings of research with various composite materials are briefly discussed in order to emphasize the healing capacity of such hydrogels. Additionally, various methods to evaluate the self-healing properties of hydrogels and their recent advancements towards 3D bioprinting are also reviewed. The review is concluded by proposing several pertinent challenges encountered at present as well as some prominent future perspectives.

In this work, biopolymer based sol-gel was synthesized by doping 3-mercaptopropanoic acid (MPA) with chitosan and a hybrid of 3-glycidoxypropyltrimethoxysilane (GPTMS) and tetraethoxysilane (TEOS). Prepared MPA/hybrid-doped chitosan was applied toa copper (Cu) metal surface by the self-assembly technique to protect the Cu metal from corrosion in a 3.5% NaCl solution. The structure, mechanism and morphology of the modified electrodes were examined using Fourier transform infra-red (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX), and atomic force microscopy (AFM). The decrease in surface roughness for Hy/chitosan/MPA-coated Cu indicates the formation of a dense layer on Cu metal confirmed by AFM. The corrosion protection evaluation of sol-gel coated electrodes was analyzed using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization studies (PDS) in a 3.5% NaCl medium. The MPA/hybrid-doped chitosan sol-gel coated Cu metal showed the greatest resistance to corrosionthanother sol-gel modified electrodes. The MPA-doped-chitosan/Hy sol-gel coating protected the Cu metal by an anodic dissolution process and improved its corrosion protection to 99.9%.

Natural and synthetic polymers have been explored for many years in the field of tissue engineering and regeneration. Researchers have developed many new strategies to design successful advanced polymeric biomaterials. In this review, we summarized the recent notable advancements in the preparation of smart polymeric biomaterials with self-healing and shape memory properties. We also discussed novel approaches used to develop different forms of polymeric biomaterials such as films, hydrogels and 3D printable biomaterials. In each part, the applications of the biomaterials in soft and hard tissue engineering with their in vitro and in vivo effects are underlined. The future direction of the polymeric biomaterials that could pave a path towards successful clinical implications is also underlined in this review.

Biopolymer coatings exhibit outstanding potential in various biomedical applications, due to their flexible functionalization. In this review, we have discussed the latest developments in biopolymer coatings on various substrates and nanoparticles for improved tissue engineering and drug delivery applications, and summarized the latest research advancements. Polymer coatings are used to modify surface properties to satisfy certain requirements or include additional functionalities for different biomedical applications. Additionally, polymer coatings with different inorganic ions may facilitate different functionalities, such as cell proliferation, tissue growth, repair, and delivery of biomolecules, such as growth factors, active molecules, antimicrobial agents, and drugs. This review primarily focuses on specific polymers for coating applications and different polymer coatings for increased functionalization. We aim to provide broad overview of latest developments in the various kind of biopolymer coatings for biomedical applications, in order to highlight the most important results in the literatures, and to offer a potential outline for impending progress and perspective. Some key polymer coatings were discussed in detail. Further, the use of polymer coatings on nanomaterials for biomedical applications has also been discussed, and the latest research results have been reported.