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To meet the environmental protection and flame retardancy requirements for epoxy resins (EPs) in certain fields, in this study, a novel triazine-ring-containing DOPO-derived compound (VDPD), derived from vanillin, 2,4-Diamino-6-phenyl-1,3,5-triazine, and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), was synthesized using a one-pot method. Flame-retardant epoxy resin (FREP) was prepared by adding various ratios of VDPD to EP and curing with 4,4-diaminodiphenylmethane (DDM). The curing behavior, thermal stability, mechanical properties, and flame-retardant properties of the FREP were examined in various tests. According to the results, when the amount of VDPD added to the EP increased, the glass transition temperature of the FREP decreased linearly, and the flame-retardant properties gradually improved. With a 0.4 wt.% P content, the vertical burning rating of EP/DDM/VDPD-0.4 (according to the theoretical content of VDPD) reached the V-0 level, and the LOI value reached 33.1%. In addition, the results of a CCT showed that the peak heat release rate (PHRR) of EP/DDM/VDPD-0.4 decreased by 32% in comparison with that of the EP. Furthermore, compared with those of the EP, the tensile strength of EP/DDM/VDPD-0.4 decreased from 80.2 MPa to 74.3 MPa, only decreasing by 6 MPa, and the tensile modulus increased. Overall, VDPD can maintain the mechanical properties of EP and effectively improve its flame-retardant properties. [ABSTRACT FROM AUTHOR]

Fiber-reinforced polymer (FRP) composites have been widely used for strengthening or constructing structures due to their excellent corrosion resistance and high tensile strength. An emerging hybrid structural member form with FRP composites—which consist of a steel section as internal reinforcement, an external FRP wrap/tube, and concrete filled between them (referred to as FRP-confined steel-reinforced concrete (FCSRC) systems)—has attracted increasing research interest. To date, the concept has been adopted to strengthen/repair steel structures or used as new hybrid structural members (e.g., hybrid columns or beams, including buckling restrained braces (BRBs)). The FRP confinement and composite action between the three components in FCSRCs result in the excellent performance of the hybrid member. This paper presents a state-of-the-art review of FCSRCs for structural applications. The gaps in knowledge and future research opportunities on FCSRC structural members are also identified. [ABSTRACT FROM AUTHOR]