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On the basis of expanded documentation of complex fossils, early Mesoproterozoic has already been proven as an important Era for eukaryotic evolution. In order to portray the biological community of this critical era, we studied a new silicified microbiota from the ∼1560 Ma Gaoyuzhuang Formation in the classic Jixian section, Tianjin, China. In total, eighteen species have been recognized, four species have been identified informally and five species have been identified in open nomenclature. Similar to other Proterozoic microbial mat biota, the new microbiota is dominated by cyanobacteria filaments and coccoids as well. Potential eukaryotic microfossils, such as ornamented coccoids, filaments with flanges and terminal cell, were firstly recovered. Amongst them, filaments with flanges and conidia-like terminal cell probably were the earliest unidirectional growing multi-cellular organisms as well as the earliest phylogeny-resolved multicellular eukaryotes. Combined with increasing records of Proterozoic eukaryotes, these microfossils indicated that eukaryotes have evolved into a new level in Early Mesoproterozoic. [ABSTRACT FROM AUTHOR]

• Spherical ministromatolite clumps in Mesoproterozoic dolostone. • Abundant microfossils within the organic matter surround the ministromatolite. • The unique silicification process favors the preservation of microfossils. • Biogenic and chemical process together contributes the formation of ministromatolite. Although the biogenicity of the very common millimeter-sized ministromatolites in the Proterozoic has been noted, direct biotic evidence is missing, leading to the discussion of a chemical origin that differs from that of the cyanobacteria-related stromatolites in the Phanerozoic. Distinctive ministromatolites were recently discovered in a microbial dolostone interval of the Mesoproterozoic Wumishan Formation, at Lingyuan, North China. Thin section examination of the ministromatolites reveals the presence of abundant coccoidal microfossils ranging 10–30 μm in diameter. Petrofabric analysis shows that the ministromatolites experienced three periods of diagenetic silicification, and that the microfossils are exclusively preserved within early diagenetic chert. This supports the view that silicification penecontemporaneous with mat growth is the key to unique preservation of microfossils. In contrast, the absence of microfossils in most Precambrian carbonate stromatolites may well be interpreted as the lack of hydrochemical conditions favorable for early silicification. Although chemically-formed fibrous carbonate minerals are the dominant components of these ministromatolites, the presence of abundant microfossils indicates that the role of microorganisms in the formation of ministromatolites has previously been underestimated. Therefore, this research suggests that Mesoproterozoic ministromatolites were not solely chemical products but consist of complex associations of both biotic and chemical fabrics. [ABSTRACT FROM AUTHOR]

• The oldest radiolarian fossils were recovered. • Most of the radiolarians are related with the order Spumellaria. • Early morphology of radiolarians is multilayered spherical without spicule(s). • Molecular appearance of radiolarian was estimated deep in Neoproterozoic. • Advent of radiolarians brought biogenetic influence into silica cycle and sediment. Radiolarian, as a group of siliceous skeleton-bearing heterotrophic protist, has a long history from modern ocean back to the Cambrian. The earliest stage in the evolution of radiolarians, although poorly understood, is important not only for itself but also with respect to the development of the global silica cycle and biogenetic siliceous sediments. It has been hypothesized that radiolarians evolved from an ancestral form constructed by spicules, although this is not without controversy since origin and their early morphology is still in dispute. However, the record of Cambrian radiolarians, especially the early Cambrian, is still sparse. Here we report a research in chert of the Liuchapo Formation from the latest Ediacaran to early Cambrian in South China that yielded the most probable oldest radiolarians from deep-water settings. Accompanied fossils and stratigraphic correlation indicate a Fortunian age. Judging by the prominent concentric multilayered shell and absence of spicules, the fossils were classified into the order Spumellaria according to the advance of radiolarian taxonomy and phylogeny. They can be compared with radiolarians from Series 2 to Furongian of the Cambrian. Molecular study conducted here also supports the existence of spumellarian during the Cambrian. Together with other reports of Cambrian radiolarians in recent years, the occurrence of non-spicule forms predates the ones constructed by spicules, which do not support the previous assumption about primitive radiolarian. The discovery not only added to the sparse fossils record of the Cambrian radiolarian, but also demonstrated their contribution to silica cycle and siliceous sediments. Evolution of early radiolarians still subjects to open discussion and awaits more evidence. [ABSTRACT FROM AUTHOR]

• Microbial mats from the Jixian Group, North China were systemically investigated and three types of them were recognized. • Five kinds of sedimentary structure which were built by or related to microbial mat were recovered. • Bottleneck structures and bubble structures have been recovered and studied for the first time. Microbial mats were well established and widespread during the Proterozoic eon, playing a pivotal role in atmospheric oxygen content. In this study, microbial mats were systematically investigated from the 1600 Ma to 1400 Ma Jixian Group, North China. Three types of microbial mats were recognized, including Microbial Mat dominated by Filaments (MMF), Microbial Mat dominated by Coccoids (MMC), Microbial Mat dominated by Filaments and Coccoids (MMFC). These microbial mats were mainly built by Siphonophycus kestron , Siphonophycus solidum , Myxococcoides sp. and Coniunctiophycus majorinum. Due to in situ preservation, five sedimentary structures related to photosynthesis and oxygen release were discovered in these microbial mats. The alternating light-dark laminae and bottleneck structure may be caused by immediate mineralization and phototropism of filaments in a hypersaline environment. Bubble structure, fenestrae structure and hourglass structure probably were related to oxygen release, and their emergence fill the gap between oxygenic photosynthesis of microbial mat and atmospheric oxygen content in Proterozoic eon. [ABSTRACT FROM AUTHOR]

• The maximum depositional age of the Suoi Chieng Formation is 1769 Ma. • The U-Pb age and Hf isotopes indicate sources originate from local basement rocks and the Rae craton of North Laurentia. • Distinct crustal evolutionary histories for the SW Yangtze and N Yangtze before their assembly in the late Paleoproterozoic. • The Yangtze Block was situated between southern Siberia and northern Laurentia within Nuna supercontinent. New U-Pb ages and Hf isotopic data for detrital zircons from the late Paleoproterozoic sedimentary rocks (Suoi Chieng Formation) in the Phan Si Pan Zone of northwest Vietnam constrain their depositional ages, provenance, and tectonic setting. The weighted average age of the youngest coherent zircon population is 1769 ± 31 Ma (MSWD = 1.3, n = 8), which provides a maximum depositional age for the Suoi Chieng Formation. The detrital zircons obtained from six Paleoproterozoic samples exhibit various ages, showing multiple magmatic and metamorphic events. The detrital zircon age pattern shows that magmatic activities in the source areas occurred at 2650 Ma, 2350–2150 Ma, and 2050 Ma, as well as minor activities at 2850 Ma, 1850 Ma, and 1780 Ma. Additionally, a prominent metamorphic age peak is observed around ca. 1850 Ma, while a few metamorphic zircons exhibit ages ranging from 2600 to 2500 Ma and 2100 Ma. This pattern indicates that the primary source of these zircons is the local basement rocks of the Phan Si Pan Zone and SW Yangtze. However, contributions from other adjoining cratonic blocks are also possible and these likely included the Rae craton of North Laurentia. Our new data verifies and expands earlier results, showing that the SW Yangtze and north Yangtze have distinct Archean-Paleoproterozoic crustal evolutionary histories prior to their assembly in the late Paleoproterozoic. Regional correlations based on detrital zircon spectra, stratigraphic and tectono-thermal histories show strong similarities between the SW Yangtze and the Rae craton of north Laurentia throughout the Paleoproterozoic, suggesting the proximity of the two blocks before or during the formation of the Nuna supercontinent. We further suggest that the north Yangtze adjoined southern Siberia in the Archean to late Paleoproterozoic as supported by their identical tectono-thermal histories and detrital zircon age spectra. In combination with published data, we propose that the Yangtze Block was located between north Laurentia and south Siberia during the Nuna assembly. [ABSTRACT FROM AUTHOR]

Highlights • Early Paleoproterozoic magmatism were reported in Phan Si Pan Complex in North Vietnam of the Yangtze Block. • The ca. 2.3 Ga quartz monzonite formed at a collision-related crustal thickening event. • The ca. 2.1 Ga A-type gneissic granite formed within an extensional tectonic setting. • The Phan Si Pan Complex was an independent terrane separated from other parts of the Yangtze Block during the early Paleoproterozoic. • The Yangtze Block was linked to northwestern Laurentia in the Pre-Nuna supercontinent. Abstract Our understanding of the early evolution of the Yangtze Block is limited by the sparsely dispersed nature of pre-Neoproterozoic exposures. New, integrated petrographic, zircon U-Pb age and Hf-Nd isotope analyses, and whole-rock geochemical data for early Paleoproterozoic granites in the Phan Si Pan Complex provides new insights into the evolution of the Yangtze Block as well as its role in the Pre-Nuna supercontinent. LA-ICP-MS zircon U-Pb dating of magmatic zircons from quartz monzonite and gneissic granite yielded 207Pb/206Pb ages of 2306 ± 12 Ma and 2096 ± 15 Ma, respectively. Zircons from the quartz monzonite have ε Hf(t) values ranging from −4.1 to −2.1, corresponding to T DM2 model ages of 3002–2890 Ma, whereas zircons in the gneissic granite have ε Hf(t) values between −0.95 and +1.72 and corresponding T DM2 model ages of 2660–2516 Ma, which are consistent with their whole-rock Nd isotope values. Geochemically, the quartz monzonites are I-type granites. Combined with their relatively high Sr/Y ratios and low Y concentrations, as well as fractionated REE patterns with relatively high LREE but low HREE concentrations, they were probably generated by partial melting of the thickened middle-lower crust under elevated temperature. Geochemical and isotopic signatures suggest that the ca. 2.1 Ga gneissic granites are high-K calc-alkaline, ferroan A-type granites formed by partial melting of juvenile crustal source at high temperature and low pressure with little involvement of ancient crustal material. The Phan Si Pan complex has a distinct early Paleoproterozoic crustal evolution history compared with the other crustal provinces of the Yangtze Block, suggesting independent histories that were not unified until the late Paleoproterozoic during the assembly of Nuna. Moreover, the magmatism and tectonic evolution of the north Vietnam region is broadly similar to that of the Arrowsmith Orogen of the Rae craton in Laurentia suggesting a potential spatial linkage. The geologic record of the Yangtze Block does not support an early Paleoproterozoic shutdown of plate tectonics. [ABSTRACT FROM AUTHOR]

• Ca. 2.30–2.27 Ga, 1.85–1.83 Ga, and 1.75 Ga granitoids in the Phan Si Pan Complex, north Vietnam. • The two older episodes of granitoids formed by partial melting of Archean basements. • The ca. 1.75 Ga trondhjemite formed by partial melting of juvenile crust. • The Yangtze Block was located between southern Siberia and northern Laurentia within Nuna. There is no consensus on the Precambrian paleogeographic reconstructions of Yangtze Block through the various supercontinent cycles and its linkage to other continental blocks. New data on the Paleoproterozoic tectonic history of the block enables linkage with other major Nuna-forming continents to be constrained. Zircon U-Pb-Hf isotopic and whole-rock elemental data highlight three episodes of Paleoproterozoic granitoids, dated at 2.30–2.27 Ga, 1.85–1.83 Ga, and 1.75 Ga from the Phan Si Pan Complex of the Phan Si Pan Zone, a southeast extension of the Yangtze Block in north Vietnam. The older two episodes of granitoid emplacement have negative ε Hf(t) values with similar T DM2 ages of 3.3–2.9 Ga, which suggest reworking of Archean basement rocks possibly at syn- to post-collisional settings. The 1.75 Ga A-type trondhjemite with positive ε Hf(t) values (0 to + 9) formed by partial melting of Paleoproterozoic juvenile crustal materials along with some mantle addition, most likely related to an intra-plate rift setting. Integrating the new results with compilations throughout the Yangtze Block, we suggest that the northern and southwestern Yangtze have different Archean and earliest Paleoproterozoic histories. Furthermore, correlations of Archean-Paleoproterozoic tectono-thermal and detrital zircon signatures between southwestern Yangtze and north Laurentia, and between northern Yangtze and southern Siberia, suggest they were close neighbors at these times. The collision between the northern and southwestern Yangtze in the late Paleoproterozoic is inferred to have led to the assembly of Laurentia and Siberia along a cryptic suture in central Yangtze and widespread crustal magmatism. Thus, we tentatively reconstruct the Yangtze Block as a key tie point between northern Laurentia and southern Siberia within the Nuna Supercontinent. [ABSTRACT FROM AUTHOR]

• Major magmatic episodes in southwestern Yangtze at ca. 3.08, 2.85 and 2.36–2.32 Ga. • Northern and southwestern domains of the Yangtze show differences in crustal growth. • The two domains have independent evolutionary histories prior to mid-Paleoproterozoic. • The two domains share a common history during and after Nuna assembly. New age data from the Cuoke Complex in southwestern Yangtze Block, integrated with published data from this region, indicate an Archean to early Paleoproterozoic magmatic history distinct from the northern Yangtze Block. Zircon cores and rims from eleven granitoids of the Cuoke Complex were analyzed by LA-ICP-MS and SHRIMP and show magmatic U-Pb ages ranging from 2850 to 2194 Ma. Combined U-Pb zircon igneous age data from the Kunming-Hainan Domain in the southwestern Yangtze Block display major magmatism ranging 3.10–3.06 Ga with a peak at ca. 3.08 Ga, 2.92–2.77 Ga with a peak at ca. 2.85 Ga and 2.4–2.1 Ga with peaks at 2.36–2.32 Ga and 2.22 Ga. This age distribution contrasts with the zircon U-Pb magmatic age data from the igneous rocks of the Kongling Domain in the northern Yangtze Block. A gap in magmatic activity in the northern domain between 2.4 and 2.2 Ga overlaps with the major peak in magmatism in the southwestern domain. Furthermore, potassic granitoids, which mark the cratonization of the two domains are more than 200 Ma years earlier in the Kongling Domain than that in the Kunming-Hainan Domain. Hf isotopic compositions of zircons from igneous rocks of the southwestern domain indicates significant juvenile crustal generation during the Mesoarchean era peaked at ca. 3.08 Ga, whereas the early Paleoproterozoic was characterized by crustal reworking and remelting. Zircon Hf isotopic compositions also reveal differences in crustal growth between the two domains. The northern domain shows a wider two-stage Hf model age range, with a peak at ca. 3.17 Ga and a subsidiary peak at ca. 3.78 Ga. Therefore, the northern domain also shows significant crustal growth in the Mesoarchean, though the age peak is about 100 Ma older compared to the southwestern domain. The Eoarchean crustal growth event recorded in the northern domain is absent in the southwestern domain. Therefore, the southwestern and northern Yangtze blocks display independent magmatic histories during the Archean and early Paleoproterozoic. The common records of late Paleo- and Mesoproterozoic tectonothermal events indicate the two domains were juxtaposed at this time, probably in association with assembly of the Nuna supercontinent. [ABSTRACT FROM AUTHOR]

• Accumulations of Cloudina are described from the topmost Dengying Formation in the Three Gorges. • An updated SIMS 206Pb/238U age of 540.6 ± 3.4 Ma is obtained from the upper Dengying Fm. • Bio-, chemo- and chronostratigraphical evidences suggest that the E-CB should be placed in the Yanjiahe Fm. Numerous issues remain concerning palaeobiology, palaeoecology, and biostratigraphy of Cloudina , an iconic tubular organism of the Ediacaran period. In this study, accumulations of Cloudina are described from the topmost bed of the Dengying Formation in the Baiguotang section of the eastern Three Gorges area, South China. The massive occurrence of Cloudina refutes any possibility of setting the Ediacaran-Cambrian boundary (E-CB) beneath the lithological transition between Dengying and Yanjiahe formations in this area. The age of the Cloudina aggregates is younger than 540.6 Ma based on a concordia 206Pb/238U age of 540.6 ± 3.4 Ma obtained from underlying upper part of the Baimatuo Member (Baiguotang section), which is consistent with the 539 Ma E-CB reported from southern Namibia. Combining fossil evidence provided by Asteridium–Heliosphaeridium–Comasphaeridium acritarchs and Anabarites trisulcatus–Protohertzina anabarica small shelly fossil assemblages and the Basal Cambrian Carbon isotope Excursion (BACE), we tentatively place the E-C boundary within the lower part of the Yanjiahe Formation, close to the BACE excursion located in the lower part of the Yanjiahe Formation in the southern Huangling Anticline. [ABSTRACT FROM AUTHOR]

• Fe-S-C-trace elemental analysis was conducted for Tonian Luotuoling Fm. • Redox proxies yielded conflicting redox signals for fossil-bearing intervals. • Redox interpretations are contrasting for fossil- and non-fossil-bearing intervals. • The unique redox data can be best explained by benthic oxygen oasis hypothesis. • Our findings inform Neoproterozoic biogeochemistry and eukaryote evolution. Benthic oxygen oases linked to photosynthetic mats have been reported in modern anoxic aquatic systems. Benthic macroalgal blooms were common in stratified, anoxic Neoproterozoic oceans, leading us to hypothesize the existence of benthic oxygen oases at that time. This hypothesis has significant implications regarding the bioavailability of transition metals (e.g., Cu, Zn, Ni, Mo, V) and the distribution of aerobic eukaryotes in these oceans. However, little research has been directed toward testing the benthic oxygen oasis hypothesis in ancient anoxic marine systems. In this contribution, we report on an integrated investigation of iron speciation, trace elements, and carbon–sulfur-δ34S py for the Tonian Longfengshan Biota-bearing versus non-fossil-bearing shales of the Luotuoling Formation in the Longfengshan section of the Yanshan Basin (North China). Typical marine B/Ga values (6.5–7.3) suggest that the Yanshan Basin was fully marine and well connected with the open ocean. The low Fe HR /Fe T ratios of the non-fossiliferous intervals (mean 0.14) suggest oxic water-column conditions during their deposition, and their Fe HR pool contains significant amounts of pyrite and siderite (up to 44%), implying their formation in underlying reducing sedimentary porewaters. In contrast, the fossil-bearing layers show high and oscillating Fe HR /Fe T ratios (mean 0.39; up to 0.51) and systematically low Fe py /Fe HR (mean ~0), suggesting dominantly ferruginous water-column conditions with redox oscillation. Furthermore, lack of redox sensitive trace-metal and sulfide enrichments and dominance of the Fe HR pool by ferric oxide and magnetite (96–100%) indicate substantially oxidative power in the reducing water-column and underlying surface sediments. In combination with coexisting sedimentological and paleontological data, these conflicting and contrasting redox signals can be best interpreted by the development of benthic oxygen oases in deeper reducing waters, regulated by the Neoproterozoic benthic macroalga Longfengshaniaceae most likely in association with microbial/cyanobacterial mats, which contributed the oxidative power in the reducing environments. Our findings provide new insights into early Neoproterozoic oceanic redox conditions, iron cycling and the evolution of early aerobic eukaryotes, including animals. [ABSTRACT FROM AUTHOR]

• Mesoarchean trondhjemite and potassic granite occur in the Kunming area, southern Yangtze Block. • Trondhjemite formed by partial melting of juvenile mafic crust at low pressure. • Potassic granite formed by partial melting of preexisting TTGs at high pressure. • Yangtze Block is subdivided into northwestern, northeastern and southern domains, which came together in late Paleoproterozoic to form the Yangtze Block. The southern Yangtze is underlain by Mesoarchean igneous rocks that were emplaced in two pulses, including trondhjemites at ca. 3092–3071 Ma followed by potassic granites at 2920 Ma. These represent the oldest TTG suites identified in the southern Yangtze and the oldest potassic granites in the entire Yangtze Block. Hf isotopic analysis reveals ε Hf(t) values of −2.49–7.49 and Hf crustal model ages (T DM C) of 3601–3000 Ma for zircons from the trondhjemites, whereas those from the potassic granites show ε Hf(t) values of −1.79–4.18 and T DM C ages of 3453–3043 Ma. The trondhjemites have high SiO 2 , Mg# and low Al 2 O 3 and K 2 O/Na 2 O, and are highly evolved with low Ni, Cr and Co. The trondhjemites are characterized by low Sr/Y, Eu/Gd and (La/Yb) N , and high Y and HREE, typical of high-HREE and low-pressure TTGs. Their geochemical and isotopic compositions indicate that they are derived from melting of juvenile mafic crust with little contribution from older crustal materials, consistent with a plagioclase-bearing basaltic source. The multielement patterns of potassic granites are similar to that of the trondhjemites, albeit with lower HREE and Y contents. Their high K 2 O values, strongly fractionated REE patterns and low Y contents indicate the presence of garnet and/or amphibole as residual phases in the source region, which indicates they formed at higher pressure than the trondhjemites. The isotopic and geochemical data imply that the formation of the potassic granites could be related to reworking of older TTGs. The increasing K 2 O/Na 2 O of the 3092–3071 Ma trondhjemites to potassic 2920 Ma granites corresponds with stabilization, maturation and thickening of the Archean continental crust in the southern Yangtze. The geochemical data of the TTGs in the Kunming region show important differences from that of contemporaneous TTGs from the Kongling Complex, suggesting that southern Yangtze is composed by an independent old nucleus, which is exotic to the northern Yangtze. A synthesis of petrogenesis, geochronology, geochemistry and isotope data of Archean granites of the Yangtze Block provides important insights into the architecture of its Archean crust. We propose that the Yangtze Block can be subdivided into discrete northwestern, northeastern and southern domains, but which are all affected by late Paleoproterozoic tectonothermal events, suggesting that they had been assembled together by then to form the united Yangtze Block. [ABSTRACT FROM AUTHOR]

• We document sponge spicules from Ediacaran-Cambrian boundary interval. • Earliest spiculites are reported here in the lower Yanjiahe Formation. • Geochemical signal confirms the studied chert is mainly of biogenic origin fixed by sponges. • Ecosystem engineering by sponges was probably an important trigger for the first establishment of modern-type ecosystems. • Taphonomy may have affected morphology of spicules and their scarcity in Precambrian. The lack of unequivocal sponge fossils before the Cambrian despite their probable deep origin during the Cryogenian period has been a conundrum to geologists. Their impact on the dramatic evolution of ecosystems and the seawater silica cycle during the Ediacaran-Cambrian (E-C) transition is also speculative. In this study, abundant sponge spicules and spicule-like structures that probably represent original sponge fossils were recovered from four sections of the E-C boundary interval in the Yangtze Gorges, South China. The paleontological and geochemical data presented herein provides evidence for a continuous distribution of relatively abundant sponge spicules, some even forming spiculites, as well as the earliest biogenic deposition of silica by metazoans in the Ediacaran-Cambrian boundary interval. These results further confirm that a biological takeover of oceanic dissolved Si co-occurred with the evolution of silica biomineralization in the E-C interval, resulting in the widespread deposition of biogenic chert. Hydrothermal input in spicule-bearing cherts is also observed. Such hydrothermal activity might have favored the blooming of sponges through significant nutrient supply. These results provide the first conjunction of geochemical and paleontological proxies in support of previous models considering that sponges, by ventilation, filtration and oxygenation of seawater, were important ecosystem engineers of the E-C bioradiation event and of the related establishment of modern-type ecosystems. [ABSTRACT FROM AUTHOR]

• Late Archean and late Paleoproterozoic magmatism occurs in the Phan Si Pan Complex, North Vietnam, of the Yangtze Block. • The 2.85–2.76 Ga potassic granites formed during collision-related crustal thickening. • The ca. 1.86 Ga A-type granite formed within an extensional tectonic setting. • The spatial changes in crustal compositions in the different Archean complexes of the Yangtze Block suggest they constitute separate terranes. • Final cratonization of the Yangtze Block likely relates to the assembly of the Nuna supercontinent. Precambrian igneous and metamorphic rocks of the Phan Si Pan Complex, North Vietnam, constitute the southern extension of the Yangtze Block, and provide a valuable record of the early evolution of the continental crust. We present results of U-Pb zircon geochronology and geochemistry for Precambrian granites in this complex to constrain their emplacement age and genesis. Granites from three plutonic bodies yielded ages of 2848 ± 15 Ma, 2768 ± 19 Ma and 1869 ± 30 Ma, which represent newly-recognized late Archean to Paleoproterozoic potassic granite plutonism in the southern Yangtze Block. The average ε Hf(t) values range from −6.2 to 0.1 for the 2.85 to 2.77 Ga granitic rocks and −13.1 to −9.2 for the ca. 1.86 Ga granitic rocks, with two-stage model ages of 3.64 to 3.20 Ga and 3.31 to 3.07 Ga, respectively, suggesting derivation from partial melting of Paleoarchean and Mesoarchean crust. The late Archean potassic granites exhibit high K 2 O, and high Sr/Y and (La/Yb) N ratios with negligible Eu anomalies, indicating derivation from melting of the thickened lower crust, which is inferred to have occurred in an active margin setting. The late Paleoproterozoic alkali feldspar granites are characterized by high FeO T /(FeO T + MgO)(0.96–0.99) and 10000 * Ga/Al (2.75–2.94) ratios, showing an affinity of A-type granite. These A-type granites exhibit flat chondrite-normalized HREE patterns and strong negative Eu anomalies, and low Sr/Y and (La/Yb) N ratios, corresponding to melting at a shallow depth, probably in a post-collisional extension setting. Comparison of the rock units and events recorded by the Phan Si Pan Complex with other Archean to Paleoproterozoic complexes (Houhe, Dongchuan, Yudongzi, Douling, Zhongxiang and Kongling complexes) in the Yangtze Block indicate spatially distinct histories of crustal growth, and thus may reflect independent terranes. The ca. 1.86 Ga post-collisional magmatism, which succeeds a 2.0–1.9 Ga metamorphic event, is distributed throughout the Yangtze Block, including the Phan Si Pan Complex, suggesting assembly of the disparate terranes and final cratonization of the Yangtze Block overlaps with, and may be related to, assembly of the Nuna supercontinent. [ABSTRACT FROM AUTHOR]