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Scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) were used to analyze the surface micromorphology and components of the iron oxide sulfide powders respectively. Differential scanning calorimetry (DSC) and thermogravimetry (TG) were used to investigate the self-heating properties. It was observed that temperature had a significant effect on the microscopic morphology and composition of the sulfide products. The product powders were homogeneously distributed in small particles and the composition of the products were converted from non-stationary FeS to FeS 2 with the sulfidation temperature increased. The apparent activation energy at a sulfidation temperature of 300 °C was 66.5 % of that at a sulfidation temperature of 150 °C. The apparent activation energies were 114.65 kJ/mol, 95.41 kJ/mol, 89.5 kJ/mol and 76.27 kJ/mol respectively at 150 °C, 200 °C, 250 °C and 300 °C during the self-heating reaction phase. There was only one main weight loss phase for the 100 °C, 150 °C and 200 °C products, while the 250 °C and 300 °C products had an additional weight loss phase before the main weight loss phase. The apparent activation energies of the main weight loss phase of the five temperature products were 318.1–333.7 kJ/mol, 266.2–293.2 kJ/mol, 212.7–234.0 kJ/mol, 174.7–193.1 kJ/mol and 168.7–188.7 kJ/mol, respectively. The apparent activation energies of the first weight loss phase of the 250 °C and 300 °C products were 217.4–243.2 kJ/mol and 198.2–214.6 kJ/mol respectively. The mechanism function for the thermal oxidation of elemental sulfur in the first weight loss phase was determined to follow the spherical contraction phase boundary reaction model, i.e. g(α)= [1-(1-α)1/3]m. In the main weight loss phase, the mechanism function for the thermal oxidation of iron sulfate followed the random nucleation followed by subsequent growth model, i.e. g(α)= [ln(1-α)]m. [ABSTRACT FROM AUTHOR]

• Corrosion coupons bent different angles can simulate the column material under different stress conditions. • The corrosion degree of the coupon with 20° bend is higher than other coupons. • In the study time range, the corrosion rate first decreased, then increased and finally decreased. • In a certain temperature range, the temperature can promote the corrosion rate of 316 L stainless-steel. Stress corrosion is the main factor that results in corrosion and fractures of rectifying columns in the process industries. Stress corrosion of rectifying columns can result in significant economic losses to chemical industries, while also having a major impact on the quality of products produced, particularly polysilicon. This gives rise to the need for research involving stress corrosion of rectifying columns. Corrosion coupons, including those with welds and bends, were used to simulate various stress conditions of stainless steel. For the experiments, a 1.5 wt.% hydrochloric acid and 2.5 wt.% sodium chloride solution was prepared to simulate realistic working conditions for the steel. The experimental methods include static coupon experiment, electrochemical experiment, scanning electron microscope and X-ray diffraction. The corrosion products of the coupons consisted mostly of grey-green materials with loose surface layers and small amounts of black matter. The corrosion products were confirmed to be FeCl 2 and Fe 2 O 3 , and the corrosion degree of the bent 20° coupon was found to be greater than that of other types of coupons. Under low temperature conditions, the corrosion rate of the coupons initially decreased over time before increasing and then decreasing again. At high temperatures, the corrosion rate began to decrease earlier than at low temperatures. The bending tendency of the 20° hanging piece was the greatest and that of the 30° hanging piece was the smallest. Higher temperatures promoted stress corrosion, with increases in temperature resulting in more significant corrosion effects. The results reported herein provide a theoretical basis and technical guidance for important anticorrosion and safety designs for distillation columns to be used in the semiconductor polysilicon rectification process. [ABSTRACT FROM AUTHOR]

• An accident on corrosion of a polycrystalline distillation column was investigated. • The main corrosion forms are pitting corrosion and stress corrosion caused by Cl−. • Corrosion rate of 316 L stainless steel is negatively correlated with the pH. • Corrosion rate of 316 L stainless steel is positively correlated with temperature. • Transformation from pitting corrosion to stress corrosion occurs at high temperature. Distillation column is a fundamental device for the production of the semiconductor polysilicon. Therefore, investigating corrosion leakage protection of the distillation column is of great significance because of the undetectable yet very significant consequences of corrosion leakage to the column. In this work, corrosion investigation of a polycrystalline silicon rectification tower is presented. The composition and crack morphology of the distillation column (316 L austenitic stainless steel) were detected and analysed using component and hardness analysers. The effects of pH and temperature on the corrosion rate were studied by conducting electrochemical experiments. According to the macroscopic test results, the surface of the tower was covered with a large number of pits and cracks of different depths. Furthermore, based on the metallographic analysis, SEM analysis, and energy spectrum analysis results, it was determined that the crack morphology was mostly intergranular and transgranular. Combined with the test data and process environment, it has been determined that the main forms of corrosion for rectification towers are pitting corrosion and stress corrosion caused by chloride ions. According to the results of electrochemical experiments, the corrosion rate of 316 L stainless steel is negatively correlated with pH value for a pH range of 4–6 at constant temperatures. However, the corrosion rate is positively correlated with temperature for the range of 60 °C–90 °C at constant pH values. From the analysis of the corrosion morphology, the corrosion failure mode of 316 L stainless steel is largely attributed to pitting corrosion when the column is operated at low temperatures (60 °C and 70 °C). However, at high temperatures (90 °C), a transformation from pitting corrosion to stress corrosion occurs along the crystalline form. To ensure the stable operation of the polysilicon rectification tower, this paper proposes corrosion protection measures based on the results of the analysis as described. [ABSTRACT FROM AUTHOR]

The flame resistance characteristics of wire mesh and its influence factor on syngas explosion were researched by experiment. Relationships between flame propagation and pressure rise at the flame resistance system two ends were clarified under different flame resistance results. And the effect of syngas concentration on explosion parameters was obtained and flame resistance mechanism was also revealed. Results indicate that the existence of wire mesh could indirectly affect pressure rise by affecting the flame propagation, and flame propagation and pressure rise presented a clear corresponding relationship. The wire mesh could play a better inhibiting role and reduce the explosion intensity, affecting by syngas concentration. As the flame resistance failed (c =30%), △ P max was effectively decreased from 0.81 MPa to 0.52 MPa above wire mesh and from 0.58 MPa to 0.39 MPa below wire mesh. And the reduction extent was more significant under flame resistance success (80.25% and 68.97%). With reduction of syngas concentration and increase of mesh layer, explosion parameters were evidently decreased. Especially the temperature above wire mesh did not present an increase trend and reach the ignition point of syngas under flame resistance success. The inhibition mechanism was mainly attributed to the combination of endothermic and wall effects. [ABSTRACT FROM AUTHOR]