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Hydrogen titanate nanotubes (H2Ti3O7) were synthesized by hydrothermal process using 10 M NaOH and TiO2 anatase powder. The material synthesized was characterized by powdered X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) to ensure the structural and morphological details of the above said nanotubes. This nanosized material behaved as a cation exchanger and it was employed to separate carrier-free 137mBa from 137Cs in column chromatographic technique using 1.0 M HNO3 as eluting agent.

The chemical investigation of E113 is likely to become soon feasible. The determination of chemical properties of carrier-free amounts of the lighter homologues of element 113, especially indium and thallium, allows designing experimental set-ups and selecting experimental conditions suitable for performing these studies. Here, we present investigations of the interaction of indium species with quartz and gold surfaces. Deposition temperatures as well as enthalpies of adsorption were determined for indiumTdep=739±20 °C (−ΔHads(In)=227±10 kJ mol−1) and for indium hydroxideTdep=250±20 °C (−ΔHads(InOH)= 124±10 kJ mol−1) respectively, on quartz. In case of adsorption of indium on a gold surface only a lower limit of the deposition temperature was establishedTdep>980 °C (−ΔHads(In)≥315±10 kJ mol−1). Investigations of macroscopic amounts of indium in thermosublimation experiments at similar experimental conditions were instrumental to establish a tentative speciation of the observed indium species.

A device for on-line electromigration studies of radio-elements in free electrolytes has been tested by measuring the absolute individual ion mobilities of no-carrier-added single charged anions [99mTc]TcO4 - and [18F]F- and differently charged cations [137Cs]Cs+, [57Co]Co2+ and [241Am]Am3+ in inert aqueous electrolytes at 298.1 K. The observed ion mobilities were found to be influenced by electroosmosis in the migration tube. A relation to correct this effect is proposed. In addition, it was shown that the effect of electroosmosis may be suppressed by chemical treatment of the surface of the migration tube.

The potential associated with the electrochemical deposition of radionuclides in metallic form from solutions of extremely small concentration is strongly influenced by the choice of the electrode material. In a macroscopic model, the interaction between the microcomponent and the electrode material is described by the partial molar adsorption enthalpy and -entropy. By combination with the thermodynamic description of the electrode process, a potential is calculated that characterizes the process at 50% deposition. Model calculations for Ni-, Cu-, Pd-, Ag-, Pt-, and Au-electrodes and the microcomponents Hg, Tl, Pb, Bi, and Po confirm the decisive influence of the electrode material on the deposition potential. The present study prepares an application of the same model to the superheavy elements 112-116.

Heavy ion activation of natural Sb2O3 with 78 MeV 16O6+ results in the formation of carrier-free praseodymium isotopes, 133,135Pr, and their corresponding decay products 133,135Ce, in the matrix. Also irradiation with ~ 90 MeV 19F7+ beam leads to the production of carrier-free neodymium isotopes, 135-138Nd, which decay out to 135-138Ce via 135-138Pr. Another way for the production of carrier-free 135Ce radionuclide is to irradiate CsNO3 target with 7Li3+ beam of energy 44 MeV. The shorter lived radionuclides of cerium decay out and a radiochemical procedure has been developed for the separation of carrier-free radionuclides from the bulk target matrix antimony and caesium through liquid-liquid extraction (LLX) using Aliquat 336 (tricaprylmethylammonium chloride), and di-(2-ethylhexyl)phosphoric acid (HDEHP) as extractants.