Search

For dissimilar metal welds, between austenitic stainless steels and ferritic steels, an austenitic stainless steel filler material with an adequate composition is normally used. To minimize the risk of hot cracking, the weld zone should preferably be constituted by an austenitic microstructure with a small amount of ferrite δ. During solidification, the microstructures depend on filler material and base material compositions. Useful indications of the weld zone microstructures can be drawn from such diagrams, for example the Schaeffler diagram, which defines the fields of existence of the phases as a function of composition expressed in terms of chromium equivalent (Creq%) and nickel equivalent (Nieq%). Recently alternative diagrams to Schaeffler diagram have been proposed. An amendment was introduced in one of these diagrams to better characterize the boundary area between martensitic-austenitic structure and fully austenitic structure. In this paper, by means of the experimental test results of austenitic stainless steel and ferritic steel joints, welded with laser beam process, some specimens were obtained with a weld zone composition near to the boundary between martensitic and austenitic zone in the Schaeffler diagram. The content of the elements was calculated by energy dispersive microanalysis (EDS). The microstructures were examined by optical microscopy and scanning electron microscopy (SEM) and by Vickers microhardness tests. For some microstructures, which were fully austenitic, the position of the corresponding points were located in the martensitic-austenitic zone below the line defined by the original Schaeffler diagram, while they were in accordance with the new definition of the boundary zone of the modified Schaeffler diagram. [ABSTRACT FROM AUTHOR]

EST Plant (Eni Slurry Technology) consists of about 300 pressure vessels in the following principal units and section: * EST unit (unit 90); * Hydrogen production plant (Unit 95); * SWS sulphur recovery and tail gas treatment (Unit 92 and 94). More than 100 "critical" equipments exist in the EST complex, divided in units and sections on the basis of their type of service. In detail, the considered critical items include: carbon steel and low alloy steels heavy wall pressure vessels for high temperature, high-pressure hydrogen service; carbon steel pressure vessels in sour (wet H^S service) and amine service. For fabrication of such "critical" items special base materials and filler metals were adopted according to specific material requirement, special welding processes and fabrication sequences (including advanced automatic systems for non destrucutive testing) were used. This paper shows an overview on some critical aspects and experience of fabrication of main "critical" equipments of EST Plant. [ABSTRACT FROM AUTHOR]