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For dissimilar metal welds, between austenitic stainless steels and ferritic steels, an austenitic stainless steel filler material with an adequate composition is normally used. To minimize the risk of hot cracking, the weld zone should preferably be constituted by an austenitic microstructure with a small amount of ferrite δ. During solidification, the microstructures depend on filler material and base material compositions. Useful indications of the weld zone microstructures can be drawn from such diagrams, for example the Schaeffler diagram, which defines the fields of existence of the phases as a function of composition expressed in terms of chromium equivalent (Creq%) and nickel equivalent (Nieq%). Recently alternative diagrams to Schaeffler diagram have been proposed. An amendment was introduced in one of these diagrams to better characterize the boundary area between martensitic-austenitic structure and fully austenitic structure. In this paper, by means of the experimental test results of austenitic stainless steel and ferritic steel joints, welded with laser beam process, some specimens were obtained with a weld zone composition near to the boundary between martensitic and austenitic zone in the Schaeffler diagram. The content of the elements was calculated by energy dispersive microanalysis (EDS). The microstructures were examined by optical microscopy and scanning electron microscopy (SEM) and by Vickers microhardness tests. For some microstructures, which were fully austenitic, the position of the corresponding points were located in the martensitic-austenitic zone below the line defined by the original Schaeffler diagram, while they were in accordance with the new definition of the boundary zone of the modified Schaeffler diagram. [ABSTRACT FROM AUTHOR]

EST Plant (Eni Slurry Technology) consists of about 300 pressure vessels in the following principal units and section: * EST unit (unit 90); * Hydrogen production plant (Unit 95); * SWS sulphur recovery and tail gas treatment (Unit 92 and 94). More than 100 "critical" equipments exist in the EST complex, divided in units and sections on the basis of their type of service. In detail, the considered critical items include: carbon steel and low alloy steels heavy wall pressure vessels for high temperature, high-pressure hydrogen service; carbon steel pressure vessels in sour (wet H^S service) and amine service. For fabrication of such "critical" items special base materials and filler metals were adopted according to specific material requirement, special welding processes and fabrication sequences (including advanced automatic systems for non destrucutive testing) were used. This paper shows an overview on some critical aspects and experience of fabrication of main "critical" equipments of EST Plant. [ABSTRACT FROM AUTHOR]

Modern superaustenitic stainless steels are quaternary alloys extensively used to resist severe aqueous corrosive service, with large contents of Cr, Ni, Mo and PREn index generally higher than 45. Fusion welding is the major joining method for fabricating components and vessels using these grades. In this paper, the behavior of these alloys and the consequence of their use infusion welded structures are illustrated. The typical microstructures of the base materials, the transformations followed during welding or heat treatment and their influence on the mechanical properties and corrosive resistance of the joints are presented. Fabrication practices, filler materials and the aspects common to the nickel alloys welding are discussed, as well. During the welded fabrication, the major difficult is to retain the fully austenitic microstructure with sufficient homogeneity throughout all the high temperature manufacturing operations, and to limit the tendency to the hot solidification cracking. The recent understanding of the segregation mechanisms during the solidification and the associated kinetic will allow a more effective control of the micro structural evolution, also by using high energy welding methods and newly formulated filler materials with non-austenitic primary solidification mode. [ABSTRACT FROM AUTHOR]

This paper has the target to summarize which are the fillers to be used in the pressure vessels cladding processes. We evaluate the most common requests in the customer's specifications and how to meet them while checking the results during construction. We gave great emphasis to the applications with austenitic stainless steels (series 300), without neglecting other applications such as Ni-based alloys. We evaluated the different processes to be used and the role of "b ferrite" which, besides being often a specific requirement of the customer, is also the key factor to control the cladding during the construction. We examined the various processes used in terms of thickness and dilution. The dilution is a key output, which depends on the process used and the parameters reported in the WPS. The accurate assessment of the dilution allows to choose the most suitable filler material and to avoid problems. The power source must be reliable and allow the repeatability of the process, as well as having a "duty cycle" adapted to production demands. It is important to underline that often being the surface to be plated several hundred square meters, the correct selection of the power sources reduce the cycle times and the delivery times. In fact, very often the cladding is on the production critical path. We presented some real cases, demonstrating how it is possible to meet the specification requirements with a careful analysis of a few experimental data. We dedicated a chapter to cladding repair defects subject. Cladding repairing defects need to be evaluated on a case by case basis, but in this presentation we propose some key guidelines that can be used to develop the repair specifications avoiding common problems. [ABSTRACT FROM AUTHOR]