Search

Several experimental methods are used to investigate the swelling capacity and transport properties of re-sealed macro-cracked Callovo–Oxfordian (COx) claystone, particularly in the absence of confining pressure. Six COx claystone samples from four different geological locations of the Bure basin (France) are tested, five of which are macro-cracked and one remains intact. Sample swelling occurs, during re-hydration with liquid water, leading to the measurement of an apparent swelling pressure. The latter is continuously recorded with a dedicated device. The asymptotic apparent swelling pressure of macro-cracked UT (transitional unit) COx is approximately 1 MPa, while it varies from 3 to 5 MPa for macro-cracked UA (clayey unit) COx. Quantitative X-ray diffraction (QXRD) analysis demonstrates that the amount of smectite, which is a swelling clay, is weakly correlated with apparent swelling pressure. Surprisingly, the interstratified illite/smectite with lower smectite content is highly correlated to apparent swelling pressure. Nitrogen isotherms data imply that the Gurvich total pore volume (VGurvich) and specific surface area (SSA) are highly linearly correlated with the low smectite content interstratified phase. This means that the distribution of smectite strongly affects the swelling capacity of COx. Moreover, nitrogen sorption is an easier and more effective technique than QXRD for assessing COx swelling capacity, since both VGurvich and SSA have been proven as effective indicators. For both UT and UA COx, self-sealing can cause significant reductions in water permeability (Kw). In particular, UA COx shows higher sealing efficiency and faster kinetics compared to UT COx. After sealing, the equivalent crack aperture (calculated from Poiseuille's law) decreases from tens of microns to less than 1 micron. According to the gas breakthrough tests, the gas breakthrough pressure (GBP) of re-sealed macro-cracked COx is of the same order of magnitude as the equivalent capillary pressure of residual crack. This indicates that the gas migration in the re-sealed cracked COx claystone mainly occurs through the residual crack and is 'a priori' controlled by capillary processes. Highlights: A dedicated device was designed to study the transport and swelling properties of a sealed COx claystone under low confinement. The apparent swelling pressure and water permeability were continuously recorded during the sealing test due to water injection in fractures. Water permeability of samples decreased by orders of magnitude to almost meet the intact material permeability. Gas breakthrough experiments performed on sealed samples evidenced gas flow through the residual cracks. [ABSTRACT FROM AUTHOR]

Wetting–drying cycles are likely to induce damage of claystone. To evaluate and to prevent micro-cracking impacts on Callovo-Oxfordian (COx) argillite, which is, in France, the potential host rock of structures containing nuclear wastes, 18 months of tests were carried out on different series of samples. These tests consisted of gas permeability and Young's modulus measurements. They were carried out on dry material, as a reference state, previously submitted to successive cycles of wetting–drying. The results show without any ambiguity that repeated hydric cycles lead to damage i.e. additional micro-cracking that induces an increase in gas permeability (possibly by 2–3 orders of magnitude compared with the intact one) and decrease in Young's modulus by 5–15%. This means that strong precautions have to be followed to keep stable the initial material water content prior to the tests and to study a material representative of its in-situ state. [ABSTRACT FROM AUTHOR]

A correction to this paper has been published: https://doi.org/10.1007/s00603-021-02419-w [ABSTRACT FROM AUTHOR]