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Geochemical environment can influence human health causing chronic medical problems related to long-term, low-level exposures to toxic agents such are trace elements. Humans can be directly exposed to toxic substances by inhalation of air dust or indirectly through food chain or by consumption of local water for drinking, cooking, personal hygiene and recreational purposes. Chronic medical problems related to geochemical characteristics of the environment can also be caused by chronic deficit of chemical elements essential for humans. In this paper we will present several applications of the GIS and statistical methods for relating the geographical distribution of diseases with geochemical characteristics of the environment. In addition, we are presenting methods applied for distinguishing natural distribution of elements from anthropogenic contribution, which is important information for establishing protective measures necessary for decreasing the health risk (the paper is published in Croatian).