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Start Over Author "Ismailov S" Journal russian chemical bulletin
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2. Molecular and crystal structure of 2-(2-methyl-2-propenyl)-1,3-cyclopentanedione (C9H12O2)

Author

Chertanova, L. F., Ismailov, S. A., Khalilov, L. M., Miftakhov, M. S., Prishchepova, E. V., Shitikova, O. V., and Tolstikov, G. A.

Abstract

An x-ray crystal structure study of 2-(2-methyl-2-propenyl)-1,3-cyclopentane-dione (C9H12O2) has been carried out. It has been shown that in the solid this compound occurs exclusively in the enol form. The molecules are bound together by strong hydrogen bonds and form infinite chains along the b-axis. According to the spectroscopic data (1H and13C NMR), the same compound in solution has a mesomeric structure.

Published
1991
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