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1. Reactions of 1,3-dehydroadamantane with polyfluorinated alcohols.

Author

Gladkikh, B. P., Mokhov, V. M., Butov, G. M., and Novakov, I. A.

Subjects
*FLUOROALKYL compounds, *ORGANOFLUORINE compounds, *ETHERS, *ALCOHOL
Abstract

A one-step synthesis of hard-to-reach adamantyl polyfluoroalkyl ethers in yields up to 95% comprises the reaction of strained 1,3-dehydroadamantane with polyfluorinated alcohols. In the competitive reactions of 1,3-dehydroadamantane with pentan-1-ol and its fluorinated analog, the latter compound is etherified predominantly (∼3:5). [ABSTRACT FROM AUTHOR]

Published
2023
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