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Start Over Author "Bykov, M." Journal russian journal of coordination chemistry
4 results on '"Bykov, M."'

4. Synthesis, Crystal Structure, and Thermal Properties of Metal-Containing Ionic Liquids with Spiro Cations: (Spiro)2MCl4 (Spiro = 2,8-Dioxo-5-azoniaspiro[4.5]decane or 2-Oxo-5-azoniaspiro[4.4]nonane, M = Mn, Ni, Co).

Author

Zakharov, M. A., Vyatchanina, E. A., Ivanov, A. S., Bykov, M. A., Karpova, E. V., Paseshnichenko, K. A., and Aslanov, L. A.

Subjects
IONIC liquids, CRYSTAL structure, DIFFERENTIAL scanning calorimetry, CATIONS, THERMAL properties, PHASE transitions
Abstract

Metal-containing ionic liquids composed of the 2,8-dioxo-5-azoniaspiro[4.5]decane (MorphOx) and 2-oxo-5-azoniaspiro[4.4]nonane (PyrOx) spiro cations and tetrachlorometallate anions (M = Mn, Ni, Co) were synthesized and studied by X-ray diffraction (CIF file CCDC nos. 2033482 (Morph-Ox2CoCl4), 2033483 (PyrOx2CoCl4), 2033484 (PyrOx2MnCl4), and 2033485 (PyrOx2NiCl4)). The compounds PyrOx2MCl4 are isostructural. The phase transition temperatures of the compounds were determined by differential scanning calorimetry. [ABSTRACT FROM AUTHOR]

Published
2021
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