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Your search keyword '"Zyk, N. V."' showing total 10 results
Start Over Author "Zyk, N. V." Journal russian journal of general chemistry
10 results on '"Zyk, N. V."'

10. Formation of CuI(CH3CN)4ClO4 in the reactions of copper(II) perchlorate with acetonitrile in the presence of sulfur-containing organic compounds.

Author

Beloglazkina, E. K., Shimorsky, A. V., Mazhuga, A. G., Shilova, O. V., Tafeenko, V. A., and Zyk, N. V.

Subjects
COPPER, PERCHLORATES, PERCHLORIC acid, LIGANDS (Chemistry), SULFOXIDES, ORGANOSULFUR compounds
Abstract

Cu(ClO4)2·6H2O was shown to react with 2,2′-[propane-1,3-diylbis(thio-2-phenylnemethylidene]-bis(3-pyridylamine) ( I) or (5Z)-2-ethoxycarbonylmethyl-(2-pyridylmethylidene)-3,5-dihydro-4 H-imidazol-4-one ( II) in the presence of CH3CN with the reduction of copper(II) to copper(I) and the formation of the tetrahedral complex CuI(CH3CN)4ClO4 ( III). In the course of the reaction the organic ligands I and II were oxidized to the corresponding sulfoxides. [ABSTRACT FROM AUTHOR]

Published
2009
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