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Graft modified flocculants have recently received increasing attention in the field of water treatment as they have the combinative advantages of synthetic and natural polymeric flocculants. In this work, surface-active monomer benzyl(methacryloyloxyethyl)dimethylammonium chloride (BMDAC) was selected to graft on dextran (DX) with high molecular weight (10.3 × 10 6  g/mol) produced through enzyme-catalyzed process in order to remove dissolved dyes from wastewater. The flocculant (DAB) was fabricated by ultrasound initiated polymerization technique, and the structure characterization of FTIR, 1 H/ 12 C NMR, XRD and XPS spectrum confirmed the successful grafting. Then the Congo red (CR) removal efficiency by DAB was optimized based on the flocculation conditions, including wastewater initial pH, flocculant dosage and initial dye concentration. The effect of suspended solids on the removal of dyes was evaluated in kaolin-CR simulated wastewater. The results indicated that the optimal removal efficiency of CR was 68.1% and 88.2% in single CR and kaolin-CR flocculation system, respectively. The improvement of removal efficiency was attributed to the fact that partial CR molecules were adsorbed onto kaolin particles before flocculation, and were synergistically flocculated accompanied by kaolin particles. Finally, the flocculation mechanism was discussed by a detailed investigation of the zeta potentials, FTIR and XPS spectra of flocs, which can provide important reference for optimizing the flocculation conditions and designing novel high-performance flocculants. [ABSTRACT FROM AUTHOR]

In this study, maleyl chitosan- graft -polyacrylamide (MHCS-g-PAM), a novel chitosan-based flocculant, was prepared through UV irradiation, and maleyl chitosan (MHCS) was designed and prepared with maleic anhydride and acrylamide (AM) through maleyl acylation reaction. The effects of monomer concentration, MHCS-to-AM ratio, illumination time, initiator concentration, pH on viscosity, and grafting efficiency were investigated to optimize the synthesis of these substances. MHCS-g-PAM was characterized through Fourier transform infrared spectroscopy, nuclear magnetic resonance hydrogen spectroscopy, scanning electron microscopy, and thermal gravimetric analysis. Flocculation mechanisms in alga-containing wastewater at various pH levels and dosages were examined in detail on the basis of zeta potential measurements. Zeta potential experiments indicated that the adsorption-bridging and charge neutralization mechanisms played an important role in algal removal. Flocculation tests on algal removal demonstrated that the flocculation performance of MHCS-g-PAM was more effective than that of cationic polyacrylamide, polyferric sulfate, and polymeric aluminium. The optimal Chl- a and COD removal rate obtained by MHCS-g-PAM was 98.6% and 94.9% at pH 7 and 4 mg·L − 1 , respectively. [ABSTRACT FROM AUTHOR]