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Injecting ozone by means of a venturi device causes an increase in the mass transfer coefficient with respect to gas dissolution through a microdiffuser. Moreover, it was observed that significant turbidity levels are not formed (1 NTU) when using a microdiffuser, probably due to the relatively high stirring which avoids formation of intermolecular hydrogen bonds. On the contrary, employing a venturi injector led to the production of high turbidity levels in water (up to 20 NTU). This indicates that formation of supramolecular structures causing this turbidity requires the presence of certain facilitating species which are formed through ozone decomposition mechanisms. The maximum ozone transfer takes place when operating at pH

Paracetamol aqueous solutions, when ozonized, acquired a strong red coloration depending on the applied ozone dose and the initial pH of the aqueous solution. Then, this color loses intensity and turns to yellow. Color formation is favored when operating at initial pH0 = 12.0 and ozone flow-rate 4.2 mg/min. A mechanism describing color formation was proposed, being the main pathway involved an initial paracetamol hydroxylation to yield 3-hydroxyacetaminophen followed by the formation of 2-amino-5-hydroxyacetofenone. Then, these compounds are degraded to colored oxidation by-products. A model describing color evolution was also proposed, considering first-order kinetics for both color formation and degradation. The corresponding kinetic constant values were determined to be kf = 0.01 (1/min) and kd = 0.03 pH −0.055 (1/min), respectively. A relationship between aromaticity loss and color changes during the reaction has been estimated considering the parameter α=kA/kf, being α = 1.62 pH + 3.5 and the first-order rate constant for aromaticity loss given by kA = 0.0162 pH + 0.035 (1/min).

Three organic fertilizers (EDTA (Ethylenedinitrilotetraacetic acid), EDDS (Ethylenediamine-N, N'-disuccinic acid) and DTPA (Diethylene triamine pentaacetic acid)) were tested as Fe-complexes in photo-Fenton process at natural pH for micropollutants (MPs) abatement and simultaneous E.coli inactivation. Less stable Fe-complexes show high iron precipitation, stopping MPs degradation. On the contrary, stable Fe-complexes imply low kinetic rates for MPs removal. To solve these inconveniences, three mixtures of organic fertilizers were also tested, trying to improve the kinetic rates of micropollutants oxidation and overcome iron precipitation. Three different pollutants (propranolol (PROP), acetamiprid (ACMP) and sulfamethoxazole (SMX)) were used as the target compounds. As the iron release is, in part, linked to the hardness of water, two water matrices from two different secondary wastewaters (Membrane Bioreactor (MBR) and Conventional Activated Sludge (CAS)) were tested. The best performance in micropollutant degradation and E.coli inactivation was achieved with the combination of EDDS + EDTA, accomplishing a good equilibrium between iron precipitation and rate of MPs removal. For instance, total removal of propranolol was achieved at 45 min in MBR, while it was only 85.7% in CAS, being an improvement of the process comparing with that obtained using single organic fertilizers. At the end of the treatment, 2.1 log-inactivation for E.coli was reached in CAS. The differences observed between both wastewaters were related to CAS' higher DOC, turbidity, and hardness. Finally, from the physicochemical characterization conducted, including Biochemical Oxygen Demand at 5 days and phytotoxicity, it is possible to highlight the suitability of these treated effluents for its reuse in irrigation, as long as in CAS matrix the final values of E. coli are within the legal limit., The authors wish to thank the Ministry of Economy and Competitiveness of Spain (project CTQ2017-86466-R, MINECO/FEDER, UE), AGAUR-Generalitat de Catalunya (project 2017SGR-131) and Nuria López FPU research fellowship (FPU-16/02101) financed by Ministry of Science, Innovation and Universities of Spain.

Dichlorvos (DDVP) is an organophosphorus pesticide that has been classified as highly hazardous chemical by the World Health organization. In this study, the fate of the pesticide DDVP in natural water compartments was examined under simulated sunlight. Moreover, the effect of UV-254 irradiation on DDVP depletion was also studied. In deionized water, DDVP was photodegraded only in the presence of dissolved molecular oxygen. The photodegradation during the first 6 h of sunlight irradiation occurred with pseudo first-order kinetics, and the rate constants were 0.040 h−1 at pH 7 and 0.064 h−1 at pH 3. A reaction mechanism for the generation of reactive oxygen species (ROS) via DDVP photoabsorption was proposed. Humic acids (HA) played a double role as photosensitizer and inhibitor, observing an enhancement on DDVP photodegradation at low HA concentration (TOC = 2 mg L−1). The depletion of DDVP under 254 nm UV irradiation was ascribed to direct photodegradation and oxygen mediated photoinduced reactions. Direct photodegradation of DDVP decreased with 254 nm irradiation reduction, highlighting the importance of radical mediated mechanisms at low irradiation doses. Based on LC/MS data, the main photoproducts under simulated solar light and UV-C irradiation were identified and potential reaction pathways were postulated. The three main identified products were o-methyl 2,2-dichlorovinyl phosphate, dichloroacetaldehyde and dimethylphosphate. Moreover, the toxicity of samples was evaluated along the irradiation exposure time using Microtox® assays. This study brings new insights into the role of oxygen in the photodegradation of DDVP and the induced and inhibition mechanisms involved in the presence of the humic acids in natural waters. Fil: Bustos, Nahuel Jano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Unidad Ejecutora de Investigaciones en Producción Animal. Universidad de Buenos Aires. Facultad de Ciencias Veterinarias. Unidad Ejecutora de Investigaciones en Producción Animal; Argentina Fil: Cruz Alcalde, Alberto. Universidad de Barcelona; España Fil: Iriel, Analia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Unidad Ejecutora de Investigaciones en Producción Animal. Universidad de Buenos Aires. Facultad de Ciencias Veterinarias. Unidad Ejecutora de Investigaciones en Producción Animal; Argentina Fil: Fernandez Cirelli, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Unidad Ejecutora de Investigaciones en Producción Animal. Universidad de Buenos Aires. Facultad de Ciencias Veterinarias. Unidad Ejecutora de Investigaciones en Producción Animal; Argentina Fil: Sans, Carmen. Universidad de Barcelona; España