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Cacao crops in Colombia play a fundamental role in its economy. Cacao bean exports have a rising tendency due to increased area and production. However, cadmium (Cd) in cacao beans has affected market in Colombia. The aim of this study is to assess Cd distribution hotspots for cacao beans, Cd in beans and soil relationships, geological ages and soil chemical parameters, overall Cd dynamics, soil-to-plant translocation, and EU regulation impacts on Cd presence in Colombian cacao production. A hot and cold spot analysis combined with a cluster and outlier analysis was used to build the geographic Cd distribution in cacao beans in Colombia. Cadmium in the subsurface and the relationship with Cd in the soil surface of cacao farms were analysed using the geoaccumulation index (I geo ). The bioconcentration factor (BCF) and soil chemical features in cacao beans were quantified. Positive correlations were observed within all the studied variables except for Mn and Fe. The highest correlation was observed within Ca, pH, and Cd in soil. The Valanginian-Albian and Albian-Maastrichtian geological ages are directly related to Cd in beans, Zn, P, soil Cd, and Fe. Regions with the highest cacao productivity and export registered an average Cd concentration in beans of 2.39_ ± _2.82 mg kg -1 . Two municipalities in Santander were 'partially contaminated' according to I geo . The BCF was not directly proportional to soil and bean Cd level and did not fully coincide with hot spots. This evidence reinforces the idea that even areas with apparently low Cd levels may register a latent problem associated with genetic/ontogenetic, climatic, or management factors. This first distribution map of Cd in cacao beans constitutes a tool to implement actions to minimize risks and face challenges posed by the imposed regulations that may limit raw cacao bean exports in Colombia., Competing Interests: Declaration of competing interest The authors declare that they have no competing financial or personal interests that might influence this study., (Copyright © 2024 Elsevier B.V. All rights reserved.)

China faces a big challenge of environmental deterioration amid its rapid economic development. To comprehensively identify the contamination characteristics of heavy metals in Chinese soils on a national scale, data set of the first national soil pollution survey was employed to evaluate the pollution levels using several pollution indicators (pollution index, geoaccumulation index and enrichment factor) and to quantify their exposure risks posed to human health with the risk assessment model recommended by the US Environmental Protection Agency. The results showed that, due to the drastically increased industrial operations and fast urban expansion, Chinese soils were contaminated by heavy metals in varying degrees. As a whole, the exposure risk levels of soil metals in China were tolerable or close to acceptable. Comparatively speaking, children and adult females were the relatively vulnerable populations for the non-carcinogenic and carcinogenic risks, respectively. Cadmium and mercury have been identified as the priority control metals due to their higher concentrations in soils or higher health risks posed to the public, as well as, arsenic, lead, chromium and nickel. Spatial distribution pattern analysis implied that the soil metal pollutions in southern provinces of China were relatively higher than that in other provinces, which would be related to the higher geochemical background in southwest regions and the increasing human activities in southeast areas. Meanwhile, it should be noticed that Beijing, the capital of China, also has been labeled as the priority control province for its higher mercury concentration. These results will provide basic information for the improvement of soil environment management and heavy metal pollution prevention and control in China. [ABSTRACT FROM AUTHOR]

Total nine tree species of common tropical trees were assessed for their air pollution tolerance, dust capturing capacity and possibility to act as metal bio-monitors in commercial, industrial and control sites. Two seasons sampling was done respectively in monsoon and post-monsoon, to study their seasonal variations. According to Air Pollution Tolerance Index (APTI) values Mangifera indica , Azadirachta indica and Ficus religiosa were the most tolerant species while Ficus bengalensis and Alstonia scholaris were intermediately tolerant towards air pollution. Single factor ANOVA of biochemical parameters between the sampling sites, revealed that APTI of plants did not vary significantly in both the seasons. Site-wise variation was significant both at commercial and industrial sites. The same trend of result was also found in Anticipated Performance Index (API) which also includes other social benefits. So, these species can be recommended for the green belt development in urban commercial and industrial areas. Ficus bengalensis , Ficus religiosa and Mangifera indica were also having the best dust capturing capacity as Scanning Electron Microscope image revealed that they have rough and large surface area of leaf with short petiole and large canopy structure. According to the Geoaccumulation index (Igeo) and Enrichment Factor (EF) of soil in the sampling sites were found to be contaminated with copper and cadmium. Psidium guajava , Mangifera indica , Alstonia scholaris and Ficus religiosa were found to be good phytoextractors of copper. They did not accumulate cadmium. So, these plants can be recommended as copper bioindicators. However, the metals accumulation efficiencies were high for Mangifera indica and Ficus religiosa. Unlabelled Image • M. indica , A. indica and F. religiosa were most tolerant while F. bengalensis and A. scholaris were intermediately tolerant towards air pollution. • F. bengalensis , F. religiosa and M. indica have the best dust capturing capacity. • Geoaccumulation Index (Igeo) and Enrichment Factor (EF) of soil indicates that the sampling sites were contaminated with Cu and Cd. • P. guajava , M. indica , A. scholaris and F. religiosa were found to be good phytoextractors of Cu. So, they can be recommended as Cu bioindicators. • Metal Accumulation Index suggests that the metals accumulation efficiencies were high for M. indica and F. religiosa. [ABSTRACT FROM AUTHOR]

• Total levels of eight potentially toxic elements in global coal industry-associated soils are reviewed. • Serious contamination of soils occurs in Southeast Asia, South Europe, and North Africa. • Compared with other elements, more Cd and Hg accumulate in coal industry-associated soils. • As is the top candidate for priority control to protect human health around coal industrial areas. Coal production and utilization are recognized as two principal sources of potentially toxic elements in the environment. Here the published literature (2008–2018) was searched to collect data on As, Ni, Cd, Cu, Cr, Hg, Pb and Zn concentrations in soils near different types of coal industrial areas such as coal mines, thermal power plants, coal chemical plants, coal mining cities and coal waster piles. The contamination levels of soils and associated health risks were assessed using global reference materials and multiple contamination indices. The results revealed that average concentrations of potentially toxic elements varied widely, yet most of them exceeded global averages in background soils and upper continental crust concentrations. Spatial distribution analysis suggested the concentrations of potentially toxic elements varied according to coalification and combustion conditions. Higher concentrations were found in Southeast Asia, South Europe, and North Africa compared with other regions. Assessment of the geoaccumulation index revealed that contamination levels of Cd and Hg were higher than those of other elements. In particular, Ni, Cd, Zn, and Hg were most likely to accumulate in soils near coal mining areas, while Cd and Hg tended to accumulate near coal chemical plants. Regarding non-carcinogenic risks, oral ingestion was the major pathway of exposure to potentially toxic elements in coal industry-associated soils, followed by dermal contact and inhalation. Tolerable non-carcinogenic risk of potentially toxic elements and relatively high carcinogenic risks of As were observed. Children were most vulnerable to non-carcinogenic risks, while the carcinogenic risks estimated for adult and children populations were similar. Accordingly, As should be designated as top candidates for priority control to protect human health in the vicinity of coal industry-associated areas. This study provides timely information for developing control and management strategies to reduce soil contamination by potentially toxic elements in different types of coal industrial areas. [ABSTRACT FROM AUTHOR]

• Systematically analyze the heavy metal pollution in the sediments of Taihu Lake in the past 20 years. • The Cd accumulation index indicated moderate–heavy pollution and Cd was the main contributor of potential ecological risks. • Pb is the main contributor to the total toxicity of the sediments in Taihu Lake. • Industrial source accounts for 64.9% of the heavy metals in the sediments of Taihu Lake. Heavy metal concentrations in Taihu Lake sediment from studies performed between 2000 and 2018 were analyzed and Monte Carlo uncertainty analysis of heavy metal geo-accumulation, potential ecological risk and toxicity data for Taihu Lake sediment was performed to allow heavy metal pollution of Taihu Lake sediment to be described clearly, objectively, and comprehensively. Five main conclusions were drawn. (1) Most attention should be paid to As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn pollution. (2) The geo-accumulation indices showed that Cd is the most important pollutant and that the probabilities of Taihu Lake sediment being moderately polluted, moderately–heavily polluted, and heavily polluted were found to be 53.6%, 34.9%, and 18.7%, respectively. (3) Cd is the main contributor to potential ecological risks and had cumulative low risk, moderate risk, and considerable risk probabilities of 63.0%, 27.0%, and 10.0%, respectively. (4) Toxicity unit evaluation results indicated that Pb is the main contributor of toxicity in Taihu Lake sediment and had cumulative low toxicity, moderate toxicity, and high toxicity probabilities of 53.0%, 36.8%, and 5.6%, respectively. (5) Positive matrix factorization model results indicated that industrial sources are the main suppliers of heavy metals to Taihu Lake sediment, contributing 64.9% of the heavy metals. The summarized results and conclusions will improve local government awareness of heavy metal pollution in Taihu Lake and will aid in the development of appropriate pollution control measures. The results will also provide reference data for future studies of heavy metal pollution in sediment from Taihu Lake and other lakes. [ABSTRACT FROM AUTHOR]