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Seaweed cultivation can inhibit the occurrence of red tides. However, how seaweed aquaculture interactions with harmful algal blooms will be affected by the increasing occurrence and intensity of marine heatwaves (MHWs) is unknown. In this study, we run both monoculture and coculture systems to investigate the effects of a simulated heatwave on the competition of the economically important macroalga Gracilariopsis lemaneiformis against the harmful bloom diatom Skeletonema costatum. Coculture with G. lemaneiformis led to a growth decrease in S. costatum. Growth and photosynthetic activity (F v /F m ) of G. lemaneiformis was greatly reduced by the heatwave treatment, and did not recover even after one week. Growth and photosynthetic activity of S. costatum was also reduced by the heatwave in coculture, but returned to normal during the recovery period. S. costatum also responded to the stressful environment by forming aggregates. Metabolomic analysis suggests that the negative effects on S. costatum were related to an allelochemical release from G. lemaneiformis. These findings show that MHWs may enhance the competitive advantages of S. costatum against G. lemaneiformis, leading to more severe harmful algal blooms in future extreme weather scenarios., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Many studies investigate the plant uptake and metabolism of xenobiotics by hydroponic experiments, however, plants grown in different conditions (hydroponic vs. soil) may result in different behaviors. To explore the potential differences, a comparative study on the uptake, translocation and metabolism of the fungicide phenamacril in crops (wheat/rice) under hydroponic and soil cultivation conditions was conducted. During 7-14 days of exposure, the translocation factors (TFs) of phenamacril were greatly overestimated in hydroponic-wheat (3.6-5.2) than those in soil-wheat systems (1.1-2.0), with up to 3.3 times of difference between the two cultivation systems, implying it should be cautious to extrapolate the results obtained from hydroponic to field conditions. M-144 was formed in soil pore water (19.1-29.9 μg/L) in soil-wheat systems but not in the hydroponic solution in hydroponics; M-232 was only formed in wheat shoots (89.7-103.0 μg/kg) under soil cultivation conditions, however, it was detected in hydroponic solution (20.1-21.2 μg/L), wheat roots (146.8-166.0 μg/kg), and shoots (239.2-348.1 μg/kg) under hydroponic conditions. The root concentration factors (RCFs) and TFs of phenamacril in rice were up to 2.4 and 3.6 times higher than that in wheat for 28 days of the hydroponic exposure, respectively. These results highlighted that cultivation conditions and plant species could influence the fate of pesticides in crops, which should be considered to better assess the potential accumulation and transformation of pesticides in crops., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Understanding the complicate chemical components in atmospheric fine particulate matter (PM 2.5 ) helps policy makers for pollutants control track progress and identify disparities in overall health risks. However, till now, information on accurate component detection, source identification, and effect-oriented risk assessment is scarce, especially for the simultaneous analysis of a broad-spectrum of compounds. In this study, a high-throughput target method was employed to distinguish the occurrence and characteristics of 152 chemicals: phthalate esters (PAEs), organophosphate esters (OPEs), carboxylic acid esters (CAEs), nitrophenols (NPs), nitrogen heterocyclic compounds (NHCs), per- and poly-fluoroalkyl substances (PFASs), triclosan and its derivatives (TCSs), and organosulfates (OSs) in ambient PM 2.5 collected from Beijing, China. Detection frequencies of 77 targeted compounds were >50 %. Total concentrations of all compounds ranged from 33.1 to 745 ng/m 3 . The median concentration of ∑PAEs (108 ng/m 3 ) was the highest, followed by ∑CAEs (12.2 ng/m 3 ) and ∑NPs (10.1 ng/m 3 ). Organophosphate diesters (di-OPEs) and TCSs were reported for the first time in ambient PM 2.5 . The pollutants mainly originated from the local industrial production, release of building materials, and environmental degradation of parent compounds. Based on absorption, distribution, metabolism, excretion, and toxicity (ADMET)-oriented risk evaluations, we found that bis (2-ethylhexyl) phthalate, diisobutyl phthalate, dibutyl phthalate, and di (2-ethylhexyl) adipate have high health risks. Additionally, the high oxidative stress potential of 4-nitrocatechol and the strong blood-brain barrier penetration potential of triclosan cannot be ignored. Our study will facilitate the evaluations of specific health outcomes and mechanisms of pollutants, and suggestion of pollutants priority control to reduce human health hazards caused by atmospheric particles., Competing Interests: Declaration of competing interest The authors have no relevant financial or non-financial interests to disclose., (Copyright © 2023 Elsevier B.V. All rights reserved.)

The impact of heatwaves (HWs) on urban heat island (UHI) is a contentious topic with contradictory research findings. A comprehensive understanding of the response of urban and rural areas to HWs, considering the underlying cause of surface energy budget changes, remains elusive. This study attempts to address this gap by investigating a 2020 HW event in the Greater Sydney Area using the Advanced Weather Research and Forecasting (WRF) model with 250-m high resolution. Findings indicate that the HW intensifies the nighttime surface UHI by approximately 4 °C. An analysis of surface energy budgets reveals that urban areas store more heat during the HW due to receiving more solar radiation and less evapotranspiration compared to rural areas. The maximum heat storage flux in urban during the HW can be around 200 W/m 2 higher than that during post-HW. The stored heat is released at nightime, raising the air temperature in the urban areas. Forests and savannas have relatively lower storage heat fluxes due to high transpiration and albedo, and the maximum heat storage flux is only around 50 W/m 2 higher than that during post-HW. In contrast, a negative synergistic effect is detected between the 2-m UHI and HW. This may be because other meteorological conditions including wind have substantial impacts on the air temperature pattern. The strong hot and dry winds coming from the west resulted in a higher air temperature in the western urban district, and intra-city disparities are higher. Meanwhile, the western forest area also experiences higher temperatures due to the westward winds. In addition, changes in wind direction alter the temperature distribution in the northern rural region. The findings of the present study may provide some insights into urban heat mitigation during HW., Competing Interests: Declaration of competing interest Jing Kong reports equipment, drugs, or supplies was provided by National Computational Infrastructure., (Copyright © 2023 The Authors. Published by Elsevier B.V. All rights reserved.)

Plant species diversity (PSD) benefits soil organic carbon (SOC) accumulation, but mechanisms underlying the stimulative effects of PSD on SOC pools have not been well explored, especially in terms of how PSD impacts plant-derived C accumulation. Here, 45 plots covering a natural gradient of PSD ranging from 0.15 to 3.57 (Shannon's diversity index) were selected in a subtropical forest with calcareous soil to determine the pattern of and controls on the variation of plant-derived C as indexed by lignin phenols along with PSD. The absolute contents of lignin phenols ranged from 1.18 to 6.62 mg g -1 soil with an average of 2.48 ± 1.13 mg g -1 soil across the 45 plots. PSD significantly enhanced soil lignin accumulation via three mechanisms. First, PSD benefited lignin accumulation by stimulating plant detritus inputs. Second, PSD directly and indirectly increased reactive minerals, so that enhanced mineral protection of lignin. Third, decrease in microbial C limitation due to increased soil C availability resulted in lowered peroxidase activity and subsequently lignin degradation, which in turn benefited lignin accumulation. Our study provides mechanisms underlying SOC accumulation in response to increased PSD, which may be integrated into Earth system models in order to better predict SOC dynamics under PSD alteration., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

The Prussian blue (PB) blending membranes are promising candidates for the removal of trace radionuclide Cs + . Constructing a membrane with high flux and selectivity are challenging in its practical application. Here, a novel polyvinylidene fluoride (PVDF)-PB-graphene oxide (GO) modified membrane was fabricated via phase inversion for trace radionuclide cesium ( 137 Cs) removal from water. Attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) were used to analyze chemical composition and morphology of the membrane, and the properties in terms of water flux and Cs + removal were studied under different PB dosage, pH and co-existing ions conditions. It was observed that the addition of GO improved the dispersion of PB, and the PVDF-PB-GO membrane presented the highest Cs + removal efficiency (99.6 %) and water flux (1638.2 LMH/bar) at pH = 7 with 0.1 wt% GO and 5 wt% PB. In addition, Langmuir and pseudo-second-order kinetics models fitted well for Cs + adsorption by the PVDF-PB-GO membrane, illustrating that the Cs + was removed via chemical adsorption dominated by Fe(CN) 6 4- defect sites of PB and the oxygen groups of GO. Furthermore, the membrane showed a significant selectivity and reusability towards trace radioactive cesium, even in the presence of excess co-existing ions and in real water, which strongly verified that the modified membrane had application potential., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Cadmium (Cd) could reduce abnormal cell morphology and membrane permeability, however, there are few studies on the detoxification of Cd-reduced cell membrane toxicity. In the present study, we firstly studied the effects of zinc chloride (ZnCl 2 ), n-acetyl-L-cysteine (NAC), and calcium/calmodulin dependent protein kinase II inhibitor (KN93) on cell membrane permeability, respectively; then, we studied the inhibitory effects of ZnCl 2 , NAC, and KN93 on Cd 2+ -induced abnormal cell membrane permeability by scanning electrochemical microscopy (SECM) scanning imaging, transverse scanning curve and DPV technology. Our results showed that 10 μmol·L -1 ZnCl 2 , 0.5 mmol·L -1 NAC and 5 μmol·L -1 KN93 could significantly improve the activity of MCF-7 cells, while did not destroy the cell morphology and membrane permeability. 0.5 mmol·L -1 NAC and 5 μmol·L -1 KN93 could significantly inhibit the effects of Cd 2+ on the morphology and membrane permeability of MCF-7 cells (p < 0.01). 10 μmol·L -1 ZnCl 2 could significantly inhibit the effect of Cd on the membrane permeability of MCF-7 cells, however, it cannot completely eliminate the morphological changes of MCF-7 cells caused by Cd 2+ . The results of cell activity experiment showed that 10 μmol·L -1 ZnCl 2 , 0.5 mmol·L -1 NAC and 5 μmol·L -1 KN93 could inhibit the effect of Cd 2+ on the activity of MCF-7 cells. By comparing the inhibitory effects of ZnCl 2 , NAC and KN93 on Cd 2+ - induced cytotoxicity, 5 μmol·L -1 KN93 had the robust effect on the maintenance of MCF-7 cell morphology and cell membrane integrity. Our research provided evidence on Zn supplement, NAC as antioxidant drugs, and KN93 as special inhibitor for the detoxification of Cd 2+ -reduced abnormal cell morphology and membrane permeability., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Triclosan (TCS) is a typical environmental pollutant, which seriously threatens the health of humans and organisms. A novel strategy of biochar/Ag 3 PO 4 /polyaniline (PANI) composite photocatalyst was synthesized by a facile chemical precipitation method to efficiently degrade TCS. XRD, Raman, ESR, etc. were used to reveal the effective associations among physiochemistry, photochemistry and photocatalytic properties of the composite. It was proved the synergistic effects of biochar (T-Bio) and PANI resulted in the decrease of Ag 3 PO 4 particle size, the enhancement of adsorption, the improvement of light utilization, the increase of photogenerated carrier separation and the promotion of reactive species. The photocatalytic mechanism showed h + was the main active species, O 2 and OH played minor roles. Under the irradiation of visible light, the optimal photocatalyst (1.0% T-Bio/AP/1.0% PANI) displayed excellent photocatalytic activity with the removal rate of 85.21% for TCS within 10 min, and the apparent rate constant K' was 2.38 times of Ag - and OH played minor roles. Under the irradiation of visible light, the optimal photocatalyst (1.0% T-Bio/AP/1.0% PANI) displayed excellent photocatalytic activity with the removal rate of 85.21% for TCS within 10 min, and the apparent rate constant K' was 2.38 times of Ag 3 PO 4 . 11 main intermediates for TCS degradation were identified, and their toxicity was significantly reduced. The possible degradation pathways were proposed. This work is the first systematic study on the degradation behavior of TCS by Ag 3 PO 4 -based photocatalyst, and it provides a new approach to fabricate photocatalysts with synergistic effects and amazing photocatalytic activity by biochar., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Ocean acidification (OA) represents a threat to marine organisms and ecosystems. However, OA rarely exists in isolation but occurs concomitantly with other stressors such as ultraviolet radiation (UVR), whose effects have been neglected in oceanographical observations. Here, we perform a quantitative meta-analysis based on 373 published experimental assessments from 26 studies to examine the combined effects of OA and UVR on marine primary producers. The results reveal predominantly additive stressor interactions (69-84% depending on the UV waveband), with synergistic and antagonistic interactions being rare but significantly different between micro- and macro-algae. In microalgae, variations in interaction type frequencies are related to cell volume, with antagonistic interactions accounting for a higher proportion in larger sized species. Despite additive interactions being most frequent, the small proportion of antagonistic interactions appears to have a stronger power, leading to neutral effects of OA in combination with UVR. High levels of UVR at near in situ conditions in combination with OA showed additive inhibition of calcification, but not when UVR was low. The results also reveal that the magnitude of responses is strongly dependent on experimental duration, with the negative effects of OA on calcification and pigmentation being buffered and amplified by increasing durations, respectively. Tropical primary producers were more vulnerable to OA or UVR alone compared to conspecifics from other climatic regions. Our analysis highlights that further multi-stressor long-term adaptation experiments with marine organisms of different cell volumes (especially microalgae) from different climatic regions are needed to fully disclose future impacts of OA and UVR., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Anemia is a highly prevalent disease among older populations, with multiple adverse health outcomes, and particles exposure is a potential risk factor for anemia. However, evidence on associations of exposure to particles with small size with anemia-related blood cell parameters levels in the elderly is limited, and the underlying mechanisms are unclear. Based on a panel study in Beijing, we found that in 135 elderly participants, mass concentrations of particle with an aerodynamic diameter ≤ 2.5 μm (PM 2.5 ), black/elemental carbon (BC/EC, particle size range: 0-2.5 μm), and number concentrations of ultrafine particles (UFPs, particle size range: 5.6-93.1 nm) and accumulated mode particles (Acc, size range: 93.1-560 nm) were significantly associated with levels of red blood cell count (RBC), hemoglobin (HGB), hematocrit (HCT), mean corpuscular hemoglobin (MCH), mean corpuscular hemoglobin concentration (MCHC). The mean ± SD for PM 2.5 , UFPs, Acc, BC, OC, and EC were 69.7 ± 61.1 μg/m 3 , 12.5 ± 4.3 × 10 3 /cm 3 , 1.6 ± 1.2 × 10 3 /cm 3 , 3.0 ± 2.0 μg/m 3 , 8.7 ± 6.7 μg/m 3 , and 2.1 ± 1.6 μg/m 3 , respectively. Cotinine (higher than 50 ng/mL) is used as an indicator of smoking exposure. The association between MCHC difference and per interquartile range (IQR) increase in average UFPs concentration 14 d before clinical visits was -0.7% (95% CI: -1.1% to -0.3%). Significant associations of UFPs and Acc exposure with MCHC and MCH levels remain robust after adjustment for other pollutants. Furthermore, 25.2% (95% CI: 7.4% to 64.8%) and 29.8% (95% CI: 5.3% to 214.4%) of the difference in MCHC associated with average UFPs and Acc concentrations 14 d before clinical visits were mediated by the level of tumor necrosis factor α (TNF α), a biomarker of systemic inflammation. Our findings for the first time provide the evidence that short-term UFPs and Acc exposure contributed to the damage of anemia-related blood cell in the elderly, and systemic inflammation was a potential internal mediator., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Antibiotic resistance genes (ARGs) have been regarded as emerging environmental contaminants. The profile of resistome (collection of all ARGs) in drinking water and its fate during drinking water treatment remain unclear. This study applied metagenomic assembly combined with network analysis to decipher the profile, mobility, host, and pathogenicity of resistomes in two full-scale drinking water treatment plants (DWTPs), each applying conventional treatment and advanced treatment of ozonation followed by biological activated carbon filtration. In source waters and effluents of each treatment process collected from both DWTPs, 215 ARGs belonging to 20 types were detected with total concentration ranging from 6.30 ± 1.83 to 5.20 ± 0.26 × 10 4  copies/mL. Both the conventional and advanced DWTPs were revealed to effectively reduce the concentration of total ARGs, with the average removal efficiency of 3.61-log 10 and 2.21-log 10 , respectively. Multiple statistical analyses (including network analysis) indicated drinking water resistome correlated tightly with mobile gene elements (MGEs) and bacterial community, with the latter acting as the premier driver of resistome alteration in DWTPs. Further analysis of ARG-carrying contigs (ACCs) assembled from drinking water metagenomes (i) tracked down potential bacterial hosts of ARGs (e.g., Proteobacteria phylum as the major pool of resistome), (ii) provided co-localization information of ARGs and MGEs (e.g., MacB-E7196 plasmid1), and (iii) identified ARG-carrying human pathogens (e.g., Enterococcus faecium and Ralstonia pickettii). This work firstly determined the concentration, mobility incidence, and pathogenicity incidence of DWTP resistomes, based on which the actual health risk regarding antibiotic resistance could be quantitatively assessed in further study, providing a useful direction for decision-making concerning the risk control of ARGs in DWTPs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Acid mine drainage (AMD) poses a potential threat to human health worldwide, due to its high content of inorganic contaminants including heavy metals. Nevertheless, AMD is commonly used for irrigation of paddy soils. To determine the extent to which AMD affects contaminant levels in such practices, the effect of continuous AMD flooding on pH, redox potential Eh and the migration of Cu and Cd in contaminated paddy soil was studied in column experiments. By means of simulated AMD, dynamic changes of Cu and Cd concentrations in pore water were measured and the controlling factors pH, Eh and presence of Fe, dissolved organic carbon and sulfate were determined over a period of 60 days. Minerals in the soil were assessed by means of an Eh-pH diagram and solid-phase mineral detection. During continuous flooding with AMD-simulated water the soil pH increased, while Eh decreased over time. After 60 days the soil pH stabilized. Cu and Cd concentrations in the pore water negatively correlated with pH and with sulfate concentrations. Five-step sequential extraction illustrated that the fraction of exchangeable Cu increased significantly during AMD flooding. The overall content of Cu increased from initially 0.29 mg/g to 0.41 mg/g, while the content of Cd decreased from 9.2 mg/g to approximately 7.2 mg/g. Mobility factors were calculated and these conformed that Cd mobility significantly increased in contaminated soils during continuous AMD flooding. Our findings indicate that the release of Cu and Cd under AMD flooding can increase potential environmental risks, even though they lead to formation of metal sulfide deposits under anaerobic conditions. The presented data improves our understanding of the impact of overlying water conditions on the mobility of toxic metals in contaminated paddy soils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Metal sulfides, which are important indicators of sulfur cycling, are usually divided into two categories according to sulfur chemical valence: (1) monosulfides (S 2- ) and (2) disulfides (S 2 2- ). The two sulfur species are separated and quantified by a sequential-extraction method. Specifically, monosulfides are extracted as acid-volatile sulfide (AVS) using 6 M HCl prior to the extraction of disulfides using acidic CrCl 2 , which is defined as chromium-reducible sulfur (CRS). However, the conventional AVS procedure does not result in the quantitative extraction of S 2- from the acid-insoluble metal monosulfide, copper sulfide (CuS). Consequently, residual sulfur in CuS (CuS-S) may be extracted as CRS resulting in the inaccurate separation of these two sulfur species. In this study, we used stannous chloride (SnCl 2 ) to improve CuS-S recovery in the AVS procedure and permit the separate extraction of sulfur from CuS and pyrite (FeS 2 ), the most abundant disulfide in nature. Our results show that the addition of SnCl 2 increased the recovery of CuS-S as AVS from less than 36% to as high as 92% in the absence of pyrite and Fe 3+ and 89% in the presence of pyrite and Fe 3+ . In addition, based on the observed correlation between the concentration of SnCl 2 and the dissolution of FeS 2 , we identified the appropriate concentration of SnCl 2 needed to avoid the dissolution of FeS 2 in the AVS procedure. SnCl 2 also minimized the oxidation of CuS-S by Fe 3+ released from ferric minerals during the extraction of AVS. Based on the results of a series of sequential-extraction experiments, we show that an amendment of SnCl 2 in the AVS procedure followed by CRS permits the quantitative separation of CuS-S and FeS 2 -S while also preventing interference by Fe 3+ . Our method will find application in research concerned with the fate of metals and the biogeochemistry of sulfur in the environment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Organosulfates (OSs) are well-known water-soluble constituents of atmospheric aerosol particles. They are formed from multiphase reactions between volatile organic compounds (VOCs) and their photooxidation products, and acidic sulfate originating from biogenic and anthropogenic sources in the atmosphere. Although the analytical procedures used to measure OSs, including sampling, pre-treatment, and instrumental detection, have advanced substantially in the last decade, there is still a need for accurate and standardized analysis procedures for the identification, quantification, and comparison of OSs in different regions. Additionally, there has no study focused on the health effects of OSs. This review outlines the analytical methods developed for OS detection during the last decade, highlighting both improvements and drawbacks. It also considers the future development of analytical methods for OS detection, and proposes the establishment of OSs screening method from the perspective of health effects to solve the problem of unknown health related OSs identification., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Arsenic-rich schwertmannite may cause arsenic (As) release during phase transition. In this study, microbial sulfidogenesis on As(V)-loaded schwertmannite (As-Sch) and associated As mobility at different SO 4 2- concentrations were investigated under anaerobic conditions by Desulfosporosinus meridiei (D. meridiei). For biotic treatments, the more SO 4 2- was added, the more Fe 3+ was reduced to Fe 2+ , and the more As(V) was released during the reductive dissolution of As-Sch. The reduction of As(V) to As(III) by D. meridiei resulted in a higher concentration, toxicity, solubility and mobility of As than the corresponding abiotic treatments. However, compared with the abiotic treatments, a variety of new minerals (such as mackinawite, vivianite, sulfur, As 2 S 3 , and parasymplesite) were generated in the biotic treatments, and the As concentration in aqueous solution was less than 1 μM at the end of the incubation period regardless of the presence of SO 4 2- . The results of continuous extraction of different species of As from secondary minerals showed that the effect of microorganisms decreased As content of amorphous iron oxide-bound phase, while increasing that bound on the surface of iron oxide surface-bound phase, thus increasing As fluidity. Our findings indicated that under anaerobic conditions, D. meridiei sulfidogenesis can trigger significant As mobilization in the early stage and remove As from the aqueous solutions when new minerals are formed at a later stage., Competing Interests: Declaration of competing interest None., (Copyright © 2020 Elsevier B.V. All rights reserved.)

After normal alkali treatment process, the industrial Cr(VI) containing wastewater still contains a ppm level of Cr(VI) ions which should be further purified before discharging. In this study, the Cr(VI)-containing wastewater has been efficiently treated by the porous paper sludge-based activated carbon (psAC) with an excellent specific surface area and rich oxygen functional groups. The batch experimental results showed that under acidic conditions, pH has little effect on the Cr(VI) removal. The kinetic and isotherms studies showed that the Elovich and Freundlich model could describe the adsorption process well and the maximum adsorption capacity of psAC was 54.04 mg/g. The thermodynamic studies indicated that the reaction process was endothermic and spontaneous. Adsorption enthalpy was 17.37 kJ/mol, showing that the chemisorption process was a hydrogen bonding-controlled that has been also verified by some analytical techniques. Lastly, this study also provided an idea for reutilization of waster Cr(VI)-contained psAC in furfural hydrogenation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Urban overheating is the most documented phenomenon of climate change, causing severe energy problems. The study aims to evaluate the mitigation potential of irrigation as a response to the urban overheating and heatwaves in large cities, using simulation-based techniques. Mesoscale simulations are conducted for a 32.5 km × 22.5 km metropolitan region of Sydney, Australia, and it is modelled based on the moderate resolution imaging spectroradiometer (MODIS) 500 m resolution land surface dataset. To better represent the Sydney metropolitan area, the New South Wales Land Zoning dataset is used to remap the land surface. The weather research forecast model (WRF) combined with the urban canopy model (UCM) is used as the simulation tool. The results show that a daily irrigation scheme results in a maximum daily temperature drop of approximately 1.3 °C and an average daily air temperature decrease close to 0.5 °C. It is also found that the cooling effect due to the additional irrigation is strongly correlated to the ambient temperature, urban fraction, and the soil moisture state before irrigation. The irrigation induced cooling effect tends to be higher in the urban areas where the soil is drier before irrigation, or in a larger portion of the area that is covered with vegetation, or where the ambient temperature is higher., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Jarosite is an iron-hydroxysulfate mineral commonly found in acid mine drainage (AMD). Given its strong adsorption capacity and its ability to co-precipitation with heavy metals, jarosite is considered a potent scavenger of contaminants in AMD-impacted environments. Sulfate-reducing bacteria (SRB) play an important role in the reductive dissolution of jarosite; however, the mechanism involved has yet to be elucidated. In this study, an indigenous SRB community enriched from the Dabaoshan mine area (Guangdong, China) was employed to explore the mechanism of the microbial reduction of jarosite. Different cultures, with or without dissolved sulfate and the physical separation of jarosite from bacteria by dialysis bags, were examined. Results indicate that the reduction of jarosite by SRB occurred via an indirect mechanism. In systems with dissolved sulfate, lactate was incompletely oxidized to acetate coupled with the reduction of SO 4 2- to S 2- , which subsequently reduced the Fe 3+ in jarosite, forming secondary minerals including vivianite, mackinawite and pyrite. In systems without dissolved sulfate, jarosite dissolution occurred prior to reduction, and similar secondary minerals formed as well. Extracellular polymeric substances secreted by SRB appeared to facilitate the release of sulfate from jarosite. Structural sulfate in the solid phase of jarosite may not be available for SRB respiration. Although direct contact between SRB and jarosite is not necessary for mineral reduction, wrapping jarosite into dialysis bags suppressed the reduction to a certain extent. Microbial community composition differed in direct contact treatments and physical separation treatments. Physical separation of the SRB community from jarosite mineral supported the growth of Citrobacter, while Desulfosporosinus dominated in direct contact treatments., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Inhalable environmental pollutants induce pulmonary malfunction, which alters thoracoabdominal respiratory conditions. Traditional methods of recording pressure differences or existing machine vision analyses for detecting respiratory abnormalities are not suitable for synchronous thoracic and abdominal respiratory detections. The present study provides a new method that combines a model of thoracoabdominal localization and distribution based on respiratory physiological characteristics and a machine vision analysis on respiratory conditions in mice exposed to aqueous aerosol containing cadmium with classical symptoms. Thoracoabdominal respirations of mice were similar to male humans based on thoracic and abdominal composite respiration and the primarily presented abdominal respiration. Under environmental inhalable cadmium doses (1, 3, 5 mM CdCl 2 in solution respectively atomized to be 112.41, 337.23, 562.05 μg/g Cd/Aerosol), the pathological thoracoabdominal respirations of mice showed that abdominal respiration contributed more to respiratory compensation and presented greater adaptive adjustments and more obvious fluctuations during lung injury than thoracic respiration, which suggests that toxic aerosol from a high-risk work environment quickly induces discernible respiratory clinical manifestations in occupational groups, as a warning for health, and abdominal obesity is unfavorable for male respiratory compensation. The respiratory abnormality shown in machine vision analysis was verified in pulmonary structural changes and hypoxia stress. Conclusively, the present method may be used to test the effects of aerosols on respiratory state and provides new prospects for toxicity determinations and risk evaluations of aerosols in the respiratory system in vivo., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Diatoms and other phytoplankton groups are exposed to abrupt changes in pCO 2 , in waters in upwelling areas, near CO 2 seeps, or during their blooms; or to more gradual pCO 2 rise through anthropogenic CO 2 emissions. Gradual CO 2 rises have, however, rarely been included in ocean acidification (OA) studies. We therefore compared how small (Thalassiosira pseudonana) and larger (Thalassiosira weissflogii) diatom cell isolates respond to gradual pCO 2 rises from 180 to 1000 μatm in steps of ~40 μatm with 5-10 generations at each step, and whether their responses to gradual pCO 2 rise differ when compared to an abrupt pCO 2 rise imposed from ambient 400 directly to 1000 μatm. Cell volume increased in T. pseudonana but decreased in T. weissflogii with an increase from low to moderate CO 2 levels, and then remained steady under yet higher CO 2 levels. Growth rates were stimulated, but Chl a, particulate organic carbon (POC) and cellular biogenic silica (BSi) decreased from low to moderate CO 2 levels, and then remained steady with further CO 2 rise in both species. Decreased saturation light intensity (I k ) and light use efficiency (α) with CO 2 rise in T. pseudonana indicate that the smaller diatom becomes more susceptible to photoinhibition. Decreased BSi/POC (Si/C) in T. weissflogii indicates the biogeochemical cycles of both silicon and carbon may be more affected by elevated pCO 2 in the larger diatom. The different CO 2 modulation methods resulted in different responses of some key physiological parameters. Increasing pCO 2 from 180 to 400 μatm decreased cellular POC and BSi contents, implying that ocean acidification to date has already altered diatom contributions to carbon and silicon biogeochemical processes., (Copyright © 2019 Elsevier B.V. All rights reserved.)

With the increasing applications in various industrial areas, toxicity of ionic liquids (ILs) has gained much attention in recent years. In this work, 1-octyl-3-methylimidazolium nitrate ([C 8 mim]NO 3 ), 1-octyl-3-methylimidazolium chloride ([C 8 mim]Cl), N-octyl-3-metylpyridinium chloride ([C 8 mpy]Cl) and N-octyl-3-metylpyridinium bromide ([C 8 mpy]Br) were used to investigate the impacts of different types of cations and anions on their toxicity to a marine diatom Phaeodactylum tricornutum. Results showed that the four ILs had poor degradability under the culture conditions used in this study, and significantly inhibited the growth of this diatom with 96-h EC 50 values of 24.0, 33.6, 16.1 and 14.4mgL -1 for [C 8 mim]NO 3 , [C 8 mim]Cl, [C 8 mpy]Cl and [C 8 mpy]Br, respectively. The data indicated that types of cations and anions would affect the toxicity of ILs to this diatom. Additionally, photosynthesis of this diatom was inhibited because significant decrease of chlorophyll a content and damage of PSII reaction centers were observed when it was exposed to the four ILs. Remarkable physiological and biochemical responses occurred in the cells of this diatom to alleviate the damaging effects of the four ILs. For example, content of soluble protein and activities of superoxide dismutase (SOD) and catalase (CAT) in the cells of this diatom increased significantly to form a protective mechanism against the toxicity of ILs, although they decreased in the cultures with high concentrations of ILs (≥20mgL -1 ). Thus, these results would not only provide strong evidences for evaluating the ecological risks and toxicity of ILs to marine ecosystem, but also help for understanding their toxic mechanisms to marine diatoms., (Copyright © 2018. Published by Elsevier B.V.)

In this study, eggs from free-range and barn chickens in farms around a fluorochemical facility were collected to assess the distribution profiles of perfluoroalkyl acids (PFAAs), including isomers of perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), and perfluorohexane sulfonate (PFHxS), in egg yolk and albumen. The results revealed that the concentrations of PFAAs in yolks were significantly higher than those in albumen. All 17 PFAAs examined could be detected in yolks, showing decreasing concentrations with increasing distance from the fluorochemical facility. The three predominant compounds in yolks were perfluorobutanoic acid (PFBA, mean concentration 81.4 ng/g ww), PFOS (28.0 ng/g ww), and PFOA (4.83 ng/g ww), and this result is consistent with the product structure of the facility. Moreover, n-PFOA, n-PFOS, and n-PFHxS were the dominant contaminants in yolk, with mean concentrations of 4.75, 25.7, and 4.29 ng/g ww, respectively. In albumen, PFBA was still the predominant PFAA congener (mean concentration = 3.93 ng/g ww), followed by PFOA. Docking analysis indicated that the PFAAs presented higher binding abilities with the low density lipoprotein, high density lipoprotein, and vitellin proteins in yolk than that with ovalbumin albumen proteins, which might be the main factor influencing the possible difference in distributions of PFAAs in yolk and albumen., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Increases of atmospheric CO 2 concentrations due to human activity and associated effects on aquatic ecosystems are recognized as an environmental issue at a global scale. Growing attention is being paid to CO 2 enrichment effects under multiple stresses or fluctuating environmental conditions in order to extrapolate from laboratory-scale experiments to natural systems. We carried out a mesocosm experiment in coastal water with an assemblage of three model phytoplankton species and their associated bacteria under the influence of elevated CO 2 concentrations. Net community production and the metabolic characteristics of the phytoplankton and bacteria were monitored to elucidate how these organisms responded to CO 2 enrichment during the course of the algal bloom. We found that CO 2 enrichment (1000μatm) significantly enhanced gross primary production and the ratio of photosynthesis to chlorophyll a by approximately 38% and 39%, respectively, during the early stationary phase of the algal bloom. Although there were few effects on bulk bacterial production, a significant decrease of bulk bacterial respiration (up to 31%) at elevated CO 2 resulted in an increase of bacterial growth efficiency. The implication is that an elevation of CO 2 concentrations leads to a reduction of bacterial carbon demand and enhances carbon transfer efficiency through the microbial loop, with a greater proportion of fixed carbon being allocated to bacterial biomass and less being lost as CO 2 . The contemporaneous responses of phytoplankton and bacterial metabolism to CO 2 enrichment increased net community production by about 45%, an increase that would have profound implications for the carbon cycle in coastal marine ecosystems., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Based on the statistics data, this paper estimated the quantity of biomass resource, and then the distribution of emissions from its combu3stion and gasification was analyzed in Tibet in 2015. The main conclusions are as follows: (1) biomass energy is rich in Tibet and its geographical distribution and quantity mainly depends on the relationship between ecological zones and the climate conditions. Crop straw is mainly distributed in Xigazê, Lasha, Qamdo and Shannan with the total quantity of 3.29×10 6 t/year; while animal dung is mainly distributed in Nagqu, Qamdo and Xigazê with the total quantity of 1.69×10 7 t/year. For the acquirable quantity of crop straw and animal dung is 7.27×10 6 t/year, mainly distributed in Nagqu, Qamdo and Xigazê. (2) The energy production potential of crop straw and animal dung in Tibet for combustion (thermal efficiency: 22.5%), HLG (system efficiency: 28.75% based on our investigation) and VLG (system efficiency: 38.75%) is 2.56×10 10 J/year, 3.28×10 10 J/year and 4.42×10 10 J/year, respectively. (3) Compared to the household combustion, the reduction of SO 2 is 72% with HLG and 97% with VLG, and the NOx reduction is 79% with HLG, 96% with VLG and 72% with gasification-combustion case., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Recently, some researchers have pointed out that the threats of ionic liquids (ILs) to aquatic environment cannot be ignored. Thus, this study investigated the potential toxicity of 1-dodecyl-3-methylimidazolium tetrafluoroborate ([C 12 mim]BF 4 ) on a marine diatom Phaeodactylum tricornutum at population, biochemical and physiological levels using 96h growth tests with a batch-culture system. Results showed that [C 12 mim]BF 4 was very stable in aquatic environment during 96h of exposure. The growth of P. tricornutum was significantly inhibited by [C 12 mim]BF 4 with 24, 48, 72 and 96h EC 50 values of 0.63, 0.61, 0.68 and 0.72mgL -1 , respectively. Although there were no significant differences between the controls and treatments with 0.1 and 0.5mgL -1 [C 12 mim]BF 4 , the effective quantum yields (Φ PSII ) of the diatom in 1, 2.5, 5 and 10mgL -1 [C 12 mim]BF 4 treatments were 61.48, 17.04, 2.96 and 0.74% of that in the controls at 96h of exposure, respectively. Chl a content of the diatom was decreased by 34.86, 47.79, 49.81, 59.21, 79.82 and 86.98% compared with that of the controls at 96h of exposure in 0.1, 0.5, 1, 2.5, 5 and 10mgL -1 [C 12 mim]BF 4 treatments, respectively. Relative to the controls, soluble sugar content, reactive oxygen species (ROS) level, malondialdehyde (MDA) content, superoxide dismutase (SOD) and peroxidase (POD) activities of the diatom increased with increasing [C 12 mim]BF 4 concentrations at 96h of exposure, and reached their maxima (1.46μg10 6 cell -1 , 7.48FU10 7 cell -1 , 3.35nmol10 8 cell -1 , 33.41 and 7.23Umg -1 proteins, respectively) in 5mgL -1 [C 12 mim]BF 4 treatments. While the maximum soluble protein content (1.56μg10 6 cell -1 ) of the diatom was obtained in 0.5mgL -1 [C 12 mim]BF 4 treatments, and then decreased with increasing [C 12 mim]BF 4 concentrations from 0.5 to 10mgL -1 . These findings provide strong evidence for the potential toxicity of ILs to marine diatoms., (Copyright © 2017 Elsevier B.V. All rights reserved.)

It is very important to have a good understanding of the biological effects of nanoparticles (NPs) on marine diatoms. In this study, the physiological and biochemical responses of a marine diatom Phaeodactylum tricornutum to titanium dioxide NPs (nano-TiO 2 ) and cerium oxide NPs (nano-CeO 2 ) were compared and evaluated using 96h growth tests in a batch-culture system. At 96h of exposure, the growth inhibition rate (IR, %) of P. tricornutum increased from 5.46 to 27.31% with increasing nano-TiO 2 concentrations from 2.5 to 40mgL -1 . The maximum IR of 49.59% occurred in 40mgL -1 nano-TiO 2 treatments at 48h of exposure. Growth of the diatom was increased in low nano-CeO 2 treatments (≤5mgL -1 ), but was inhibited in high nano-CeO 2 treatments (≥10mgL -1 ). Large aggregates of NPs were attached to the cells of P. tricornutum in 20 and 40mgL -1 nano-TiO 2 and nano-CeO 2 treatments. In addition, the effective quantum yields (Φ PSII ) of P. tricornutum in 40mgL -1 nano-TiO 2 and nano-CeO 2 treatments were 83.33 and 71.13% of that in the controls at 96h of exposure, respectively. Compared with that of the controls at 96h of exposure, chlorophyll a content, soluble sugar content, malondialdehyde (MDA) content, SOD and POD activities of P. tricornutum in 40mgL -1 nano-TiO 2 and nano-CeO 2 treatments increased by 57.56, 142.97, 373.25, 698.76, 204.85% and 21.43, 89.41, 194.97, 340.05, 502.86%, while soluble protein content decreased by 70.38 and 28.64%, respectively. These findings will be helpful to understand the effect mechanisms of NPs on marine organisms., (Copyright © 2016 Elsevier B.V. All rights reserved.)