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Liquid crystal monomers (LCMs) have been recognized as contaminants of emerging concerns. E-waste recycling sites and liquid crystal displays (LCDs) manufacturers are supposed to be critical sources. However, information regarding LCM contaminations in soils surrounding these sites are currently unavailable. In this study, soil samples were collected from two distinct areas in South China: e-waste recycling area (n = 36) and LCD manufacturer (n = 41), and 60 target LCMs (including 13 biphenyl and analogs (BAs), 10 cyanobiphenyl and analogs (CBAs), and 37 fluorinated biphenyl and analogs (FBAs)) were determined. The concentrations of LCMs in the soils from near the e-waste recycling area (0.32-18 ng/g, average: 4.2 ng/g) were higher than those surrounding the LCD manufacturer (ND - 7.2 ng/g, average: 1.5 ng/g). The compositional profiles of LCMs in soil samples from these two typical point sources were considerably different. The concentrations of FBAs exponentially decreased with distance from the e-waste recycling park, by >90 % within 2 km. The levels of BAs exhibited a similar exponential decrease with distance from the LCD manufacturer. The inventories of LCMs were estimated to be 21.0 kg in the e-waste recycling area and 10.8 kg in the LCD manufacturer area. Remarkably, the inventory of LCMs in soils from e-waste recycling area was one order of magnitude larger than that of hexabromocyclododecanes (HBCDs) in the same region, and 0.2 to 20 times the annual global emissions of LCMs from discarded LCD panels. More studies are required to elucidate the environmental occurrence, behavior, and fate of LCMs in multimedia environment surrounding typical point sources., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

With the strict regulation of brominated flame retardants, organophosphate esters (OPEs) have been extensively used as replacements. Increasing concerns on OPEs have aroused due to their extensive distribution in the environment and humans, as well as their potential toxicities. Recent studies have demonstrated that some organophosphate di-esters are even more toxic than their respective tri-esters. This review summarized the current state of knowledge on the analytical methodologies (including sample collection and preparation, instrumental analysis, and the feasibility of each potential human matrix), as well as the occurrences of OPEs and/or their metabolites (m-OPEs) in various human matrices. Organophosphate esters are readily metabolized in human thus only limited studies reported their occurrences in blood and breast milk, whereas abundant studies are available regarding the occurrences of m-OPEs rather than OPEs in urine. Since none of the matrix is suitable all the time, appropriate matrix should be selected depending on the aims of biomonitoring studies, e.g., high throughput screening or body burden estimation. Biomonitoring with non-invasive matrices such as hair and/or nail is useful to screen specific populations that might be under high exposure risks while urine is more suitable to provide valuable information on body burden. In terms of urinary monitoring, specific biomarkers have been identified for some OPE compounds, including tri(2-butoxyethyl) phosphate, tri(1,3-dichloro-2-propyl) phosphate, tri(2-chloroethyl) phosphate and tri(1-chloro-2-propyl) phosphate. Further studies are required to identify suitable urinary biomarkers for other OPE compounds, especially the emerging ones., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the present work., (Copyright © 2022 Elsevier B.V. All rights reserved.)