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Methylmercury (MeHg) presents high toxicity to humans and can be accumulated to organisms via the food chains. In aquatic environments, MeHg is mainly formed by microorganism using the bioavailable inorganic mercury in sediment. In this study, a total of 120 surface sediments from 20 sites in the Kaohsiung Harbor were collected quarterly in the period from July 2016 to October 2017 and analyzed for total mercury (THg), bioavailable inorganic mercury (BIHg), MeHg, and several geochemical parameters. The concentrations of THg, BIHg, and MeHg in sediment were 455–5108, 7.0–1021, and 0.84–24.1 μg/kg dw, respectively. Results indicated that the percentage of MeHg to THg (MeHg ratio) in most sediment (85%) is <1.2%. Correlation analysis showed that MeHg in sediment was mainly controlled by BIHg (r = 0.759, p < 0.01), while the concentration of BIHg in sediment was mainly related to TOC (r = 0. 480, p < 0.01) and THg (r = 0.435, p < 0.01). The relationship between total bioavailable inorganic mercury (containing BIHg and the bioavailable inorganic mercury used in the synthesis of MeHg) and MeHg concentration in the sediments that collected from the estuary, harbor channel, and the entrance was established by a Michaelis-Menten model to predict the maximum value of MeHg. The efficiency of Hg methylation in the sediments of Kaohsiung Harbor is significantly affected by the total bioavailable inorganic mercury and the related environmental factors. In addition, changes in environmental conditions caused by local seasonality should also be an important factor to consider when assessing the efficiency of Hg methylation. Unlabelled Image • MeHg in sediment was mainly controlled by the concentration of BIHg. • BIHg in sediment mainly related to the particle size, TOC, and THg. • Estuary sediment had high MeHg and THg together with high TOC and reducing status. [ABSTRACT FROM AUTHOR]

Abstract Many rivers are facing human-induced system regime shifts that have great environmental, ecological and social implications, necessitating an increasing need to quantify the human influence on sediment properties and their impacts on the source-to-sink system of marginal seas. The Huanghe and Changjiang Rivers have experienced a dramatic reduction in sediment flux in recent decades, typifying the human influence on sediment properties of global large rivers. Sediment samples from the two rivers were analyzed to obtain grain size, magnetic and geochemical data. The results show a large difference in sediment properties between pre- and post-dam periods. We applied a discrepancy factor to re-examine the magnetic and geochemical tracers that were previously used in the two rivers. The discrepancy factors of most magnetic and geochemical tracers in the mud-sized sediments of the two rivers increased by an average of about 109% after dam construction. This suggests that human-induced changes in sediment properties have greatly improved the discriminatory ability between the sediments from the two rivers. The results also raise the uncertainty of using previous tracers to distinguish between sediments from the two rivers after damming. Furthermore, significant changes in sediment properties that happened in a relatively short time may provide future geological time markers for sedimentary records with a temporal resolution of 100–101 years. For marine environments, an approach for identifying sediment sources based on multiple independent optimum tracers is also proposed, with composite magnetic (SIRM vs. HIRM) and geochemical (Na 2 O vs. Zn) tracers being considered. The results of this work can advance our knowledge of how human activities alter river systems, and identify a sustainable development model under system regime shifts for areas of high-intensity human activity. Graphical abstract Unlabelled Image Highlights • Large differences in sediment properties exist between pre- and post-dam periods. • An approach of using multiple independent optimum tracers is proposed. • Human activities increased the differences between the sediments from the two rivers. • Amplified endmember differences may provide a future geological time marker. [ABSTRACT FROM AUTHOR]

Abstract Understanding the integrated effect of external factors (e.g., human activities) and internal factors (e.g., hydrodynamics, sediment properties) on metal(loid) distributions is necessary for relevant decision-makers to develop river basin management strategies. In attempts to understand the possible causes of the distribution of nine target metal(loid)s in riverbed sediments across Xijiang River basin in China, we grouped and portrayed the multiple metal(loid) distributions by calculating metal(loid)'s normalised-and-weighted average concentrations, and then canonical correlation analysis combined with a series of statistical operations, collectively called optimized CCA analysis, was applied to quantify the strength of relationship between multiple metal(loid) distribution and integrated effect of internal-external factors. Results showed that the target metal(loid)s can be divided into three groups according to their distribution patterns: Group A (including Zn, As, Cd, Sb and Pb), Group B (including Cr, Ni and Cu) and Group C (including Tl). Among them, metal(loid)s in Group A was significantly enriched in comparison with the reference values of Chinese sediments, and the wide-ranging accumulation of Cd and Sb in the whole study area needs paying great attention to. For those metals in natural states (e.g., metals in Group B), the affinity of sediment (e.g., Fe and Mn oxides) is responsible for their distributions. By contrast, when metal(loid)s (e.g., metal(loid)s in Group A and Group C) had obvious anthropogenic sources, the interferences of anthropogenic inputs (e.g., non-ferrous metal enterprises' waste-discharging activities) and the specific sedimentary characteristics (e.g. karst topography and low-energy hydrodynamic depositional conditions) in study area can weaken the correlation between the binding affinity of sediment and the contents of metal(loid)s. The optimized CCA analysis can be an alternative and advantageous statistical operation for determining the main types of causes of multiple metal(loid) distribution in the case of observations with relatively low case-per-variable ratios. Graphical abstract Unlabelled Image Highlights • Metal(loid) distributions in sediments are controlled by external-internal factors. • A procedure was developed based on optimized canonical correlation analysis. • This procedure was applied to study sediment metal(loid)s in Xijiang River basin. • Relationship between metal distributions and related factors could be quantified. • The contributions of related factors can reflect the extent of human interference. [ABSTRACT FROM AUTHOR]

Rare earth elements (REEs) disperse from indigenous rocks to the environment, thus making sediments one of the major sinks and sources of metal pollution. The emerging use of REEs and the subsequent opening of new mining areas may contribute to their release into surrounding ecosystems. For this reason, this study was performed in a natural area with geological material abundant in ferrocarbonatites and light REE. The aim of this work was to assess the natural REE availability and (eco)toxicity in freshwater sediments. Sediments showed high REE concentrations in samples with fine grain size fractions, and low in organic-rich sediments. The enrichment in LREE was mostly from rocks and the obtained enrichment factors (EF) confirmed that the sediments are not anthropogenically polluted. To assess REE availability and ecotoxicity, four toxicity tests were performed. REEs measured as the dissolved concentration in the test media were very low compared to the potentially available total REE in sediments and showed positive or negative correlations with fine or coarse grain sizes, respectively, and positive correlations with the content in Mg, Fe and Al. In tests performed in media supplemented with salts, the availability of REEs decreased considerably. Only some toxic effects could be linked to the REE contents in the ostracodtox and luminotox tests. However, measurement of toxicity could be influenced by the sediment properties and lead to a potential overestimation of ecotoxicity if only REE are regarded. Our study reveals that the physicochemical properties of sediments are a key factor controlling both REE availability and toxicity, whereas the determination of REE effects from toxicity tests using liquid media with salt addition will decrease REE availability and could mask toxic effects. Our findings provide new knowledge about REE behaviour in sediments and are a starting point for understanding potential REE pollution around prospective mining areas. [ABSTRACT FROM AUTHOR]

Of the blue carbon sinks, mangroves have one of the highest organic matter (OM) storage capacities in their soil due to low mineralization processes resulting from waterlogging. However, mangroves are disappearing worldwide because of demographic increases. In addition to the loss of CO 2 fixation, mangrove clearing can strongly affect soil characteristics and C storage. The objectives of the present study were to quantify the evolution of soil quality, carbon stocks and carbon fluxes after mangrove clearing. Sediment cores to assess physico-chemical properties were collected and in situ CO 2 fluxes were measured at the soil-air interface in a mangrove of Northern Vietnam. We compared a Kandelia candel mangrove forest with a nearby zone that had been cleared two years before the study. Significant decrease of clay content and an increase in bulk density for the upper 35 cm in the cleared zone were observed. Soil organic carbon (OC) content in the upper 35 cm decreased by > 65% two years after clearing. The quantity and the quality of the carbon changed, with lower carbon to nitrogen ratios, indicating a more decomposed OM, a higher content of dissolved organic carbon, and a higher content of inorganic carbon (three times higher). This highlights the efficiency of mineralization processes following clearing. Due to the rapid decrease in the soil carbon content, CO 2 fluxes at sediment interface were > 50% lower in the cleared zone. Taking into account carbonate precipitation after OC mineralization, the mangrove soil lost ~ 10 MgOC ha − 1 yr − 1 mostly as CO 2 to the atmosphere and possibly as dissolved forms towards adjacent ecosystems. The impacts on the carbon cycle of mangrove clearing as shown by the switch from a C sink to a C source highlight the importance of maintaining these ecosystems, particularly in a context of climate change. [ABSTRACT FROM AUTHOR]

Rivers are regarded as sinks and pathways of plastic pollutants from terrestrial environments to various other aquatic systems such as lakes and oceans. Although extensive research has been conducted in recent years on microplastic pollution in river sediments, knowledge on the relationships between potential influential factors such as catchment characteristics and sediment properties, and microplastics occurrence in river sediments, is still considered an under-researched area. This study evaluated the influence of land use, population, and sediment particle size on the presence of microplastics abundance and types. Based on a Bayesian Network modelling approach to characterise the correlations between influencing factors and microplastics occurrence, it was evident that microplastics type had a positive correlation with different land use types and population. Catchment characteristics were found to play a more important role in influencing microplastics type than microplastics concentration. A statistically significant positive relationship was observed between microplastics concentration and clay particles which suggested that the occurrence of microplastics in sediments can be impacted by the presence of clay particles. Unlabelled Image • Role of catchment and sediment characteristics in microplastics in river sediments • Bayesian Networks modelling to evaluate microplastics occurrence in river sediments • Land use, population exert greater impact on microplastics type not concentration • Clay particles influence microplastics concentration in river sediments [ABSTRACT FROM AUTHOR]