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Although there is an important lack of commercial thermoelectric applications mainly due to their low efficiency, there exist some cases in which thermoelectric generators are the best option thanks to their well-known advantages, such as reliability, lack of maintenance and scalability. In this sense, the present paper develops a novel thermoelectric application in order to supply power to volcanic monitoring stations, making them completely autonomous. These stations become indispensable in any volcano since they are able to predict eruptions. Nevertheless, they present energy supply difficulties due to the absence of power grid, the remote access, and the climatology. As a solution, this work has designed a new integral system composed of thermoelectric generators with high efficiency heat exchangers, and its associated electronics, developed thanks to Internet of Things (IoT) technologies. Thus, the heat emitted from volcanic fumaroles is transformed directly into electricity with thermoelectric generators with passive heat exchangers based on phase change, leading to a continuous generation without moving parts that powers different sensors, the information of which is emitted via LoRa. The viability of the solution has been demonstrated both at the laboratory and at a real volcano, Teide (Canary Islands, Spain), where a compact prototype has been installed in an 82 °C fumarole. The results obtained during more than eight months of operation prove the robustness and durability of the developed generator, which has been in operation without maintenance and under several kinds of meteorological conditions, leading to an average generation of 0.49 W and a continuous emission over more than 14 km.

Fumaroles represent evidence of volcanic activity, emitting steam and volcanic gases at temperatures between 70 and 100 ∘ C . Due to the well-known advantages of thermoelectricity, such as reliability, reduced maintenance and scalability, the present paper studies the possibilities of thermoelectric generators, devices based on solid-state physics, to directly convert fumaroles heat into electricity due to the Seebeck effect. For this purpose, a thermoelectric generator composed of two bismuth-telluride thermoelectric modules and heat pipes as heat exchangers was installed, for the first time, at Teide volcano (Canary Islands, Spain), where fumaroles arise in the surface at 82 ∘ C . The installed thermoelectric generator has demonstrated the feasibility of the proposed solution, leading to a compact generator with no moving parts that produces a net generation between 0.32 and 0.33 W per module given a temperature difference between the heat reservoirs encompassed in the 69–86 ∘ C range. These results become interesting due to the possibilities of supplying power to the volcanic monitoring stations that measure the precursors of volcanic eruptions, making them completely autonomous. Nonetheless, in order to achieve this objective, corrosion prevention measures must be taken because the hydrogen sulfide contained in the fumaroles reacts with steam, forming sulfuric acid.