1. Multistep synthesis of non-spherical SnO2@SnO2 yolk-shell cuboctahedra with nanoparticle-assembled porous structure for toluene detection.
- Author
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Bing, Yifei, Liu, Chang, Qiao, Liang, Zeng, Yi, Yu, Shansheng, Liang, Zhongzhu, Liu, Junping, Luo, Jingze, and Zheng, Weitao
- Subjects
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STANNIC oxide , *CHEMICAL synthesis , *NANOPARTICLES , *POROUS materials , *TOLUENE , *CHEMICAL detectors , *SURFACES (Technology) - Abstract
A new type of nonspherical yolk-shell structures in the case of SnO 2 has been successfully prepared by a simple anneal-etching strategy without employing any additional templates or capping agents. The morphological and structural characterization reveals that SnO 2 yolk-shell particles have a hierarchical architecture with penetrable multi-walled surfaces and cuboctahedral shape, where the secondary building blocks are numerous nanoparticles. The synthetic step-dependent evolution process of SnO 2 yolk-shell cuboctahedra is investigated and the possible formation mechanism is also discussed. To demonstrate the merit of unique structure for the fast mass transfer, sensor based on SnO 2 products has been fabricated and the results exhibit excellent sensing performances for toluene detection. It is found that our SnO 2 yolk-shell structures have a response of 28.6–20 ppm toluene at the optimal working temperature of 250 °C, and the response time and recovery time are within 1.8 and 4.1 s, respectively. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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