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[Display omitted] • This material is capable of withstanding highly acidic (3–8 M HNO 3), highly radioactive (∼200 kGy), and highly heated (∼200 °C) conditions. • It has good stability, being able to withstand prolonged exposure to high acid without any impact on its efficacy. • The material has great selectivity, and even when there are hundreds or thousands of times more interfering ions, it still has a particular selectivity to Eu(III). • This material is cost-effective, its synthesis is uncomplicated, the raw materials are readily available, and it can be reused - these are all advantages. Americium (Am), a radioactive element, is highly valued for its commercial uses. Its source is primarily derived from high-acid, high-radiation, and high-temperature high-level radioactive waste liquids, requiring materials that are capable of enduring the most intense conditions for its capture. For this challenging environment, we successfully created a composite material TODGA@SiO 2 that is capable of effectively separating Am3+. An exhaustive evaluation of the material was undertaken, focusing on essential parameters and the column behavior of the material to ascertain its suitability for engineering applications. The composite is highly resistant to acid (>3 M HNO 3), can withstand temperatures up to 200 °C, and is radiation resistant up to 200 kGy, making it a great choice. Highlighting its suitability for radioactive waste, the adsorbent exhibited outstanding stability even after being soaked in 3 M HNO 3 for 11 days. In terms of performance, this material had a rapid kinetics (1 min, >95 %), a considerable adsorption capacity (K d value close to 3 × 105 mL/g), and a high selectivity for Am3+. From a cost and environmental protection perspective, the adsorbent can be regenerated and reused at least five times, and the extractant structure adheres to the CHON (Carbon, Hydrogen, Oxygen, and Nitrogen) principle, so orderly disposal is simple. At the same time, the high column efficiency, with a recovery rate of Am3+ of more than 94 %, makes its industrial application highly practical. In comparison to existing adsorbents, the material reported in this work has shown greater efficacy, making it a suitable inorganic composite for Am3+ extraction from radioactive liquid waste. [ABSTRACT FROM AUTHOR]