1. Effect of sintering aids on the electrical properties of Ce0.9Nd0.1O2−δ
- Author
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Xia, Yanjie, Bai, Yijia, Wu, Xiaojie, Zhou, Defeng, Wang, Zhongchang, Liu, Xiaojuan, and Meng, Jian
- Subjects
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SINTERING , *ELECTRIC properties of metals , *CERIUM oxides , *ADDITION reactions , *SOLID solutions , *FLUORITE , *SCANNING electron microscopy , *ELECTROLYTES , *IMPEDANCE spectroscopy - Abstract
Abstract: The effect of small addition of different sintering aids (MoO3 and WO3) on the electrical properties of Ce0.9Nd0.1O2−δ has been investigated. The (Ce0.9Nd0.1)1−x M x O2−δ (x = 0.0; M = Mo, W, x = 0.01; Ce0.9Nd0.1O2−δ : NDC, (Ce0.9Nd0.1)0.99Mo0.01O2−δ : NDCMo; (Ce0.9Nd0.1)0.99W0.01O2−δ : NDCW) solid solutions were prepared and characterized. The X-ray diffraction patterns indicate that all the samples are single phases with a cubic fluorite structure. Moreover, from the field-emission scanning electron microscopy results, it is found (Ce0.9Nd0.1)0.99M0.01O2−δ (M = Mo, W) sintered at 1300 °C for 15 h have better sinterability than Ce0.9Nd0.1O2−δ . The total conductivity by electrochemical impedance spectroscopy are ranked as: NDCW > NDCMo > NDC measured at 700 °C, which is attributed to microstructures. It can be concluded that MoO3 and WO3 are both effective and WO3 seems to be more potential as sintering aids on the optimization of electrical properties for ceria-based electrolytes. [Copyright &y& Elsevier]
- Published
- 2012
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